摘要:
In the process of bisphenol-A systhesis a method for controlling the water content of the resultant cation-exchanger bed wherein an acid ion-exchanger resin in the form of a sulphonated styrene-divinylbenzene copolymer is washed with phenol and the resulted washing is contacted with a basic ion-exchanger resin. Water is removed from the washing by distillation, and the dewatered phenol is recycled to wash the cation-exchanger bed. The catalyst bed is then washed with a mixture of phenol acetone and water, and this washing is contacted with the basic ion-exchange resin and recycled to wash the cation exchanger bed so as to obtain the desired moisture content.
摘要:
An ion-exchanger catalyst in the form of an acid ion-exchanger resin used for the synthesis process of alkylated phenols and having substitutes containing 6-12 carbon atoms in a chain is treated with phenol alkylation having olefins in the presence of acid catalysts such as acid ion-exchange resins.
摘要:
A process for the production of bisphenol A from phenol and acetone, comprises introducing a substantially anhydrous reaction mixture of phenol, acetone, and recycled solution of bisphenol A and reaction by-products in phenol into a reaction zone containing a cation-exchange resin catalyst, such catalyst being a mixture of resin having a macroporous structure and resin having a microporous structure in a ratio of 0.05:1 to 0.5:1 by weight, the mol ratio of phenol to acetone being 5:1 to 30:1, and the concentration of bisphenol A being 12 to 20% by weight. The temperature of the reaction zone is maintained between 60 degrees and 95 degrees C. The resulting reacted reaction mixture is withdrawn from the reaction zone, the concentration of bisphenol A being 21 to 35% by weight and the amount of reaction by-products being 12 to 24% by weight. Such withdrawn reaction mixture is treated to recover bisphenol A product and to provide the recycled solution of bisphenol A and reaction by-products in phenol.
摘要:
The invention relates to a process for obtaining a high purity bisphenol from a post-reaction mixture resulting from the step of synthesis of phenol and acetone in the presence of a strong acid cation exhanger catalyst, by the way of crystallation and separation by distillation followed by recovery of bisphenol-A from the step of thermal catalytic decomposition of by product of the principal process technology in a multistage process.