公开(公告)号：US6063726A

公开(公告)日：2000-05-16

申请号：US862174

申请日：1997-05-22

申请人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

发明人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

IPC分类号： C08F4/02 ,  C08F4/655 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/10 ,  C08F110/02 ,  C08F4/64

CPC分类号： C08F10/00 ,  C08F10/10 ,  C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  Y10S526/901 ,  Y10S526/943

摘要： The invention relates to a polymerization catalyst for alpha-olefins and a process for polymerizing alpha-olefins. The catalyst comprises a component having a transition metal compound supported on a carrier and an aluminoxane. The carrier may be pre-treated with an organometallic compound, a halogen-containing silicon compound or an aluminoxane. Alternatively, the above two catalyst components are subjected to preliminary polymerization of olefins. The catalyst of this invention enables the production of a spherical polymer having a good particle size distribution, an excellent bulk density and a narrow molecular weight distribution in a slurry polymerization method or a vapor-phase polymerization method, particulary the vapor-phase polymerization method. When applied to the copolymerization of at least two olefins, the catalyst has excellent polymerization activity such that an olefin copolymer having a narrow molecular weight distribution and a narrrow composition distribution is obtained.

摘要翻译： 本发明涉及α-烯烃的聚合催化剂和α-烯烃的聚合方法。 催化剂包含负载在载体上的过渡金属化合物和铝氧烷的组分。 载体可以用有机金属化合物，含卤素的硅化合物或铝氧烷进行预处理。 或者，将上述两种催化剂组分进行烯烃的预聚合。 本发明的催化剂能够制备在淤浆聚合法或气相聚合法中具有良好的粒度分布，优异的堆积密度和窄分子量分布的球形聚合物，特别是气相聚合法。 当应用于至少两种烯烃的共聚时，催化剂具有优异的聚合活性，从而获得具有窄分子量分布和叙述组成分布的烯烃共聚物。

公开(公告)号：US5206199A

公开(公告)日：1993-04-27

申请号：US860014

申请日：1992-03-30

申请人： Mamoru Kioka ,  Norio Kashiwa ,  Toshiyuki Tsutsui ,  Akinori Toyota

发明人： Mamoru Kioka ,  Norio Kashiwa ,  Toshiyuki Tsutsui ,  Akinori Toyota

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/943

摘要： An olefin is polymerized or copolymerized under the presence of an olefin-polymerizing catalyst prepared from (A) a transition-metal compound or (A') a transition-metal compound loaded on a fine-particle carrier, said transition metal being selected from group IVB in the periodic table; (B) an aluminoxane; and (C) an organoaluminum compound represented by the general formula [I] or [II]:R.sup.1.sub.m Al(OR.sup.2).sub.3-m [I]R.sup.3.sub.n Al(OSiR.sup.4.sub.3).sub.3-n [II]wherein R.sup.1, R.sup.2, and R.sup.3 are selected from hydrocarbon radicals, R.sup.4 is selected from the group consisting of hydrocarbon, alkoxy, and aryloxy radicals, and m and n are positive numbers of 0

摘要翻译： 在由（A）过渡金属化合物或（A'）负载在细颗粒载体上的过渡金属化合物制备的烯烃聚合催化剂存在下，烯烃聚合或共聚，所述过渡金属选自 IVB在周期表中; （B）铝氧烷; 和（C）由通式[I]或[II]表示的有机铝化合物：R1mA1（OR2）3-m [I] R3nAl（OSiR43）3-n [II]其中R1，R2和R3选自 烃基，R 4选自烃，烷氧基和芳氧基，m和n是0

公开(公告)号：US4704491A

公开(公告)日：1987-11-03

申请号：US843556

申请日：1986-03-25

申请人： Toshiyuki Tsutsui ,  Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa

发明人： Toshiyuki Tsutsui ,  Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa

IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F8/04 ,  C08F10/00 ,  C08F210/16

CPC分类号： C08F210/16 ,  C08F10/00 ,  C08F8/04 ,  C08F4/65912 ,  C08F4/65925

摘要： A liquid ethylene-alpha-olefin random copolymer, characterized in that(a) it has an ethylene unit content of 10 to 85 mole % and an alpha-olefin unit content of 15 to 90 mole %,(b) it has a low molecular weight,(c) it has a narrow molecular weight distribution,(d) the dispersion of the ethylene units and alpha-olefin units in the polymer chain is in the advanced state, and(e) the directions of bonding of the alpha-olefin units in the polymer chain are nearly the same.The copolymer is prepared by copolymerizing ethylene and an alpha-olefin having 3 to 20 carbon atoms in the presence of a catalyst comprising a compound of a transition metal of Group IVb of the periodic table and an aluminoxane. The copolymer is very useful as a synthetic lubricant oil.

摘要翻译： 一种液体乙烯-α-烯烃无规共聚物，其特征在于（a）其乙烯单元含量为10至85摩尔％，α-烯烃单元含量为15至90摩尔％，（b）其具有低分子量 （c）它具有窄的分子量分布，（d）聚合物链中的乙烯单元和α-烯烃单元的分散体处于先进状态，和（e）α-烯烃的键合方向 聚合物链中的单元几乎相同。 该共聚物通过在包含元素周期表IVb族过渡金属的化合物和铝氧烷的催化剂存在下共聚乙烯和具有3-20个碳原子的α-烯烃来制备。 该共聚物作为合成润滑油是非常有用的。

公开(公告)号：US5171799A

公开(公告)日：1992-12-15

申请号：US682528

申请日：1991-04-09

申请人： Mamoru Kioka ,  Toshiyuki Tsutsui ,  Akinori Toyota

发明人： Mamoru Kioka ,  Toshiyuki Tsutsui ,  Akinori Toyota

IPC分类号： C08F4/602 ,  C08F10/00

CPC分类号： C08F10/00 ,  Y10S526/943

摘要： In accordance with the present invention, there are provided olefin polymerization catalyst components comprising an organoaluminum oxy-compound having less than 10% in terms of Al atom of Al component dissolving in benzene kept at 60.degree. C., and olefin polymerization catalyst containing said olefin polymerization catalyst components. The olefin polymerization catalysts have excellent polymerization activities, and are capable of giving olefin (co)polymers having a narrow molecular weight distribution and a narrow composition distribution.

公开(公告)号：US5122491A

公开(公告)日：1992-06-16

申请号：US290110

申请日：1988-12-16

申请人： Mamoru Kioka ,  Norio Kashiwa ,  Toshiyuki Tsutsui ,  Akinori Toyota

发明人： Mamoru Kioka ,  Norio Kashiwa ,  Toshiyuki Tsutsui ,  Akinori Toyota

IPC分类号： C08F4/62 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00

CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  Y10S526/904 ,  Y10S526/943

摘要： An olefin is polymerized or copolymerized under the presence of an olefin-polymerizing catalyst prepared from (A) a transition-metal compound or (A') a transition-metal compound loaded on a fine-particle carrier, said transition metal being selected from group IVB in the periodic table; (B) an aluminoxane; and (C) an organoaluminum compound represented by the general formula [I] or [II]:R.sup.1.sub.m Al(OR.sup.2).sub.3-m [I]R.sup.3.sub.n Al(OSiR.sup.4.sub.3).sub.3-n [II]wherein R.sup.1, R.sup.2, and R.sup.3 are selected from hydrocarbon radicals, R.sup.4 is selected from the group consisting of hydrocarbon, alkoxy, and aryloxy radicals, and m and n are positive numbers of 0

摘要翻译： PCT No.PCT / JP88 / 00384 Sec。 371日期：1988年12月16日 102（e）日期1988年12月16日PCT提交1988年4月19日PCT公布。 出版物WO88 / 08432 日本11月3日，1988年。烯烃在由（A）过渡金属化合物或（A'）负载在细粒载体上的过渡金属化合物制备的烯烃聚合催化剂存在下聚合或共聚合， 所述过渡金属选自周期表中的IVB族; （B）铝氧烷; 和（C）由通式[I]或[II]表示的有机铝化合物：R1mA1（OR2）3-m [I] R3nAl（OSiR43）3-n [II]其中R1，R2和R3选自 烃基，R 4选自烃，烷氧基和芳氧基，m和n是0

公开(公告)号：US5091352A

公开(公告)日：1992-02-25

申请号：US407436

申请日：1989-09-14

申请人： Mamoru Kioka ,  Toshiyuki Tsutsui ,  Akinori Toyota

发明人： Mamoru Kioka ,  Toshiyuki Tsutsui ,  Akinori Toyota

IPC分类号： C08F4/64 ,  C08F10/00

CPC分类号： C08F10/00 ,  Y10S526/943

摘要： In accordance with the present invention, there are provided olefin polymerization catalyst components comprising an organoaluminum oxy-compound having less than 10% in terms of Al atom of Al component dissolving in benzene kept at 60.degree. C., and olefin polymerization catalyst containing said olefin polymerization catalyst components. The olefin polymerization catalysts have excellent polymerization activities, and are capable of giving olefin (co)polymers having a narrow molecular weight distribution and a narrow composition distribution.

摘要翻译： 根据本发明，提供了烯烃聚合催化剂组分，其包含以溶于保持在60℃的苯中的Al成分的Al原子计小于10％的有机铝氧化合物，以及含有所述烯烃的烯烃聚合催化剂 聚合催化剂组分。 烯烃聚合催化剂具有优异的聚合活性，并且能够得到具有窄分子量分布和窄组成分布的烯烃（共）聚合物。

公开(公告)号：US4990640A

公开(公告)日：1991-02-05

申请号：US407435

申请日：1989-09-14

申请人： Toshiyuki Tsutsui ,  Mamoru Kioka ,  Akinori Toyota

发明人： Toshiyuki Tsutsui ,  Mamoru Kioka ,  Akinori Toyota

IPC分类号： C07F5/06 ,  C08F10/00

CPC分类号： C07F5/068 ,  C08F10/00 ,  Y10S526/943

摘要： In accordance with the present invention, there are provided benzene-insoluble organoaluminum oxy-compounds having less than 10% in terms of Al atom of Al component dissolving in benzene kept at 60.degree. C. and less than 0.09 of a (D.sub.1260 /D.sub.1220) of an absorbance (D.sub.1260) at 1260 cm.sup.-1 to an absorbance (D.sub.1220) at 1220 cm.sup.-1, both obtained by infrared spectrophotometry, and also processes for preparing said benzene-insoluble organoaluminum oxy-compounds.

公开(公告)号：US5654248A

公开(公告)日：1997-08-05

申请号：US433545

申请日：1995-05-02

申请人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

发明人： Mamoru Kioka ,  Akinori Toyota ,  Norio Kashiwa ,  Toshiyuki Tsutsui

IPC分类号： C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/10 ,  C08F110/02 ,  B01J31/00 ,  B01J37/00

CPC分类号： C08F10/10 ,  C08F110/02 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925

摘要： A prepolymerized solid catalyst for gaseous phase or slurry polymerization of alpha olefins is disclosed. The catalyst comprises a porous carrier having a particle size of 20 to 200 microns onto which has been deposited an aluminoxane and a transition metal compound having at least one cycloalkadienyl group, the transition metal being from group 4 of the Periodic Table. The transition metal is present in an amount of 0.003 to 3 mmol/gm of carrier, and the aluminum to transition metal atomic ratio is from 15 to 1000. This catalyst is then prepolymerized with 0.2 to 30 gm of an alpha olefin per gram of catalyst to form the final prepolymerized solid catalyst having an intrinsic viscosity of 0.2 to 20 dl/gm as measured in decalin at 135 deg C.

摘要翻译： 公开了一种用于α-烯烃的气相或淤浆聚合的预聚合固体催化剂。 催化剂包括粒径为20-200微米的多孔载体，其上沉积有铝氧烷和具有至少一个环二烯基的过渡金属化合物，过渡金属来自元素周期表第4族。 过渡金属的存在量为0.003至3mmol / gm的载体，铝与过渡金属的原子比为15至1000.然后将该催化剂与每克催化剂0.2至30gm的α-烯烃预聚合 以形成在135℃萘烷中测得的特性粘度为0.2-20dl / gm的最终预聚固体催化剂

公开(公告)号：US5247031A

公开(公告)日：1993-09-21

申请号：US606628

申请日：1990-10-31

申请人： Mamoru Kioka ,  Masao Nakano ,  Akinori Toyota

发明人： Mamoru Kioka ,  Masao Nakano ,  Akinori Toyota

IPC分类号： C08F10/00

CPC分类号： C08F10/00 ,  Y10S526/904

摘要： A catalyst component (X") obtained by treating an olefin polymerization catalyst (X) formed from (A) a solid titanium catalyst component comprising magnesium, titanium, halogen and an electron donor as essential ingredients, (B) an organoaluminum compound catalyst component, and as required, (C) an electron donor with an alpha-olefin by preliminarily polymerizing the alpha-olefin in an amount of 0.1 to 500 g per gram of the solid titanium catalyst component (A) in the presence of said catalyst (X), and contacting the treated catalyst (X') with at least 0.1 mole, per gram-atom of titanium in the treated catalyst (X'), of oxygen. A process for producing the olefin polymerization catalyst component. A catalyst (Y) for olefin polymerization formed from [I] the above catalyst component (X"), [II] an organoaluminum compound catalyst component and as required [III] an electron donor. Also provided is a process for polymerizing olefins in the presence of the olefin polymerization catalyst (Y).

摘要翻译： 通过处理由（A）包含镁，钛，卤素和电子给体的固体钛催化剂组分形成的烯烃聚合催化剂（X）获得的催化剂组分（X“）作为必要成分，（B）有机铝化合物催化剂组分 和（C）通过在所述催化剂（X）存在下，每克固体钛催化剂组分（A）预先聚合0.1至500g的α-烯烃的聚合方法，（C）具有α-烯烃的电子给体 ），并且使经处理的催化剂（X'）与经处理的催化剂（X'）中的每克原子钛至少0.1摩尔的氧接触。 一种生产烯烃聚合催化剂组分的方法。 由[I]上述催化剂组分（X“），[II]有机铝化合物催化剂组分和所需的[III]电子给体形成的用于烯烃聚合的催化剂（Y）。 还提供了在烯烃聚合催化剂（Y）存在下使烯烃聚合的方法。

公开(公告)号：US5075396A

公开(公告)日：1991-12-24

申请号：US331221

申请日：1989-03-31

申请人： Norio Kashiwa ,  Akinori Toyota ,  Mamoru Kioka

发明人： Norio Kashiwa ,  Akinori Toyota ,  Mamoru Kioka

IPC分类号： C08F4/00 ,  C08F4/46 ,  C08F4/60 ,  C08F4/64 ,  C08F4/658 ,  C08F10/00

CPC分类号： C08F10/00

摘要： A process for producing a polymer or copolymer of an olefin which comprises polymerizing or copolymerizing at least one olefin with or without a diolefin in the presence of a catalyst composed of (A) a magnesium-containing solid titanium catalyst component containing magnesium, titanium, a halogen and an electron donor as essential ingredients and (B) an organoaluminum compound catalyst component; characterized in that(1) said catalyst further comprises (C) an organic silicon compound catalyst component having an Si--O--C or Si--N--C bond, and(2) said electron donor in the catalyst component (A) is a cyclic mono- or poly-ester such as diethyl furane-3,4-dicarboxylate, di-n-butyl 3,4-dihydro-2H-pyrane-5,6-dicarboxylate, di-isobutyl pyrrole-2,3-dicarboxylic, di-n-butyl thiophene-2,3-dicarboxylate, n-octyl pyrrolidine-2,3-dicarboxylate, and so on.