摘要:
A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.
摘要:
Provided are (1) a novel phenyl sulfonate compound, (2) a nonaqueous electrolytic solution comprising an electrolyte salt dissolved in a nonaqueous solvent and containing a phenyl sulfonate compound of the following general formula (II) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and (3) a lithium battery containing the nonaqueous electrolytic solution and excellent in low-temperature cycle property. (wherein X1 to X5 each independently represents a fluorine atom or a hydrogen atom, and from one to four of these are fluorine atoms; R2 represents a linear or branched alkyl group having from 1 to 6 carbon atoms, a linear or branched alkyl group having from 1 to 6 carbon atoms in which at least one hydrogen atom is substituted with a halogen atom, or an aryl group having from 6 to 9 carbon atoms).
摘要:
A nonaqueous electrolytic solution for lithium battery comprises an electrolyte salt dissolved in a nonaqueous solvent and contains a carboxylate compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution. (In the formula R1 and R2 each independently represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; R3 represents a hydrogen atom, a methyl group, or a group —CH2CO2CR1R2C≡CH (R1 and R2 have the same meaning as above) .) A lithium battery uses the nonaqueous electrolytic solution having excellent cycle property and storage property.
摘要翻译:用于锂电池的非水电解液包含溶解在非水溶剂中的电解质盐,并且含有由以下通式(I)表示的羧酸盐化合物,其量为非水电解液的0.01至10质量%。 (式中,R 1和R 2各自独立地表示氢原子或碳原子数1〜6的烷基,R 3表示氢原子,甲基或基团-CH 2 CO 2 CR 1 R 2C≡CH(R 1和R 2相同 如上所述)。锂电池使用具有优异的循环性能和储存性能的非水电解液。
摘要:
A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element selected from the group consisting of Ti, Zr and Hf and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.