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    Halftone gravure printing inks containing an azo dyestuff
    1.
    发明授权
    Halftone gravure printing inks containing an azo dyestuff 失效
    含有偶氮染料的半色调凹版印刷油墨

    公开(公告)号：US4776886A

    公开(公告)日：1988-10-11

    申请号：US893079

    申请日：1986-08-04

    申请人： Manfred Lorenz ,  Rainer Hamprecht ,  Artur Haus

    发明人： Manfred Lorenz ,  Rainer Hamprecht ,  Artur Haus

    IPC分类号： C09B29/08 ,  C09B29/44 ,  C09D11/02 ,  C09D11/00 ,  C09D11/16

    CPC分类号： C09D11/037 ,  C09B29/0809 ,  C09B29/3643 ,  Y10S534/02

    摘要： A halftone gravure printing ink(A) about 2 to about 20% by weight of colorant,(B) about 10 to about 40% by weight of resin and(C) about 80 to about 50% by weight of solventwherein said colorant comprises azo dyestuff of the formula ##STR1## in which A.sub.1, A.sub.2 and A.sub.3 denote hydrogen, halogen, --CN, --NO.sub.2, C.sub.1 -C.sub.6 -alkyl, cycloalkyl, C.sub.1 -C.sub.18 -alkoxy, optionally substituted phenoxy, optionally substituted C.sub.1 -C.sub.18 -alkylsulphonyl, optionally substituted phenylsulphonyl, optionally substituted sulphamoyl, optionally substituted carbamoyl, optionally substituted phenylazo, C.sub.1 -C.sub.18 -alkoxycarbonyl, --CF.sub.3, --SCN, C.sub.1 -C.sub.12 -alkylmercapto, C.sub.1 -C.sub.6 -alkylcarbonyl, optionally substituted phenylcarbonyl or --OH,A.sub.4 and A.sub.5 denote hydrogen, halogen, optionally substituted C.sub.1 -C.sub.6 -alkyl, optionally substituted C.sub.1 -C.sub.6 -alkoxy, --NH--CO--CH.sub.2 CH.sub.2 OA.sub.8, --NH--CO--A.sub.8, --NH--SO.sub.2 --A.sub.8, NH--CO--O--A.sub.9, --NH--CO--A--COOH, --NH--CO--CH.sub.2 OA.sub.8, ##STR2## A.sub.8 denotes C.sub.1 -C.sub.22 -alkyl, C.sub.2 -C.sub.22 -alkenyl, C.sub.3 -C.sub.7 -cycloalkyl, phenyl, naphthyl or phenyl-C.sub.1 -C.sub.4 -alkyl, it being possible for the aryl radicals mentioned to be substituted,A.sub.9 denotes C.sub.1 -C.sub.22 -alkyl, C.sub.2 -C.sub.22 -alkenyl, C.sub.3 -C.sub.7 -cycloalkyl or phenyl-C.sub.1 -C.sub.4 -alkyl,A.sub.10, A'.sub.10, and A.sub.11 denote hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.2 -C.sub.22 -alkenyl,A denotes ##STR3## A' and A" denote the remaining members of a carbocyclic 5-membered or 6-membered ring which is optionally substituted,A.sub.6 denotes aryl, or A.sub.7 andA.sub.7 denotes hydrogen or aliphatic radicals, it being also possible for the radicals A.sub.4 and A.sub.6 to be connected to form a ring, preferably a 6-membered ring, and for the radicals A.sub.6 and A.sub.7 to be cyclized by --(CH.sub.2)n-- groups (n=4 or 5) or --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 -- group.

    摘要翻译： 一种半色调凹版印刷油墨（A）约2至约20重量％的着色剂，（B）约10至约40重量％的树脂和（C）约80至约50重量％的溶剂，其中所述着色剂包括 其中A1，A2和A3表示氢，卤素，-CN，-NO2，C1-C6-烷基，环烷基，C1-C18-烷氧基，任选取代的苯氧基，任选取代的C 1 -C 18 - 烷基磺酰基，任选取代的苯基磺酰基，任选取代的氨磺酰基，任选取代的氨基甲酰基，任选取代的苯偶氮，C 1 -C 18烷氧基羰基，-CF 3，-SSCN，C 1 -C 12烷基巯基，C 1 -C 6烷基羰基，任选取代的苯基羰基或-OH， 并且A5表示氢，卤素，任选取代的C 1 -C 6 - 烷基，任选取代的C 1 -C 6 - 烷氧基，-NH-CO-CH 2 CH 2 OA 8，-NH-CO-A 8，-NH-SO 2 -A 8，NH-CO-O- A9，-NH-CO-A-COOH，-NH-CO-CH2OA8，图像+ TR图像A8表示C1-C22-烷基，C2-C22-烯基，C3-C7-环烷基，苯基，萘基或 苯基-C 1 -C 4 - 烷基， 所提及的芳基可以被取代，A9表示C1-C22-烷基，C2-C22-烯基，C3-C7-环烷基或苯基-C1-C4-烷基，A10，A'10和A11表示氢 ，C 1 -C 22 - 烷基或C 2 -C 22 - 烯基，A表示A'，A“表示任选被取代的碳环5元环或6元环的剩余成员，A 6表示芳基或A 7 并且A7表示氢或脂族基团，基团A4和A6也可以连接形成环，优选6-元环，并且基团A6和A7可以被 - （CH2）n- （n = 4或5）或 - （CH 2）2 -O-（CH 2）2 - 基。

    Dyed compositions containing insecticides
    2.
    发明授权
    Dyed compositions containing insecticides 失效
    含有杀虫剂的染色组合物

    公开(公告)号：US06706761B1

    公开(公告)日：2004-03-16

    申请号：US10031870

    申请日：2001-11-13

    申请人： Mike-Dirk Bublitz ,  Dietmar Kisters ,  Rainer Hamprecht

    发明人： Mike-Dirk Bublitz ,  Dietmar Kisters ,  Rainer Hamprecht

    IPC分类号： A01N5300

    CPC分类号： A01N25/18

    摘要： The invention relates to insecticide-comprising polymer-based compositions which, in order to recognize the point in time when the insecticide is exhausted, comprise at least one dye which, after the insecticide has evaporated, turns a different colour.

    摘要翻译： 本发明涉及含有杀虫剂的聚合物基组合物，为了识别杀虫剂耗尽的时间点，它包含至少一种染料，其在杀虫剂蒸发后变成不同的颜色。

    Azo dyestuffs containing phenolic coupling group
    4.
    发明授权
    Azo dyestuffs containing phenolic coupling group 失效
    含有苯偶姻染料的偶氮染料

    公开(公告)号：US4259237A

    公开(公告)日：1981-03-31

    申请号：US974018

    申请日：1978-12-28

    申请人： Rainer Hamprecht

    发明人： Rainer Hamprecht

    IPC分类号： C09B29/00 ,  C09B29/01 ,  C09B29/26 ,  C09B43/42 ,  C07C107/06 ,  C09B29/12

    CPC分类号： C09B29/0003 ,  C09B29/0059 ,  C09B29/0081 ,  C09B29/26 ,  C09B43/42

    摘要： Azo dyestuffs of the formula ##STR1## wherein R.sub.1 represents hydrogen or in some cases alkyl, aralkyl, aryl or cycloalkyl,R.sub.2 represents hydrogen or in some cases alkyl, alkenyl or aralkyl,R.sub.3 represents, inter alia, hydrogen, alkyl, halogen or cyano andD represents the radical of a diazo component,are suitable for dyeing synthetic textile materials, in particular those made of polyethylene terephthalate. The scarlet-colored to blue dyeings obtained, in particular, with the preferred dyestuffs of the formula I, wherein D represents a o,o'-dicyanobenzene radical, are distinguished by good general fastness properties, good depth of color and a particularly clear color shade.

    摘要翻译： 式（I）的偶氮染料其中R 1表示氢或在某些情况下为烷基，芳烷基，芳基或环烷基，R 2表示氢或在某些情况下为烷基，烯基或芳烷基，R 3特别表示氢，烷基， 卤素或氰基，D表示重氮组分的基团，适用于染色合成纺织材料，特别是由聚对苯二甲酸乙二醇酯制成的材料。 获得的猩红色至蓝色染色剂，特别是优选的式I染料，其中D代表ao，o'-二氰基苯基，具有良好的通用牢度特性，良好的颜色深度和特别清晰的色度 。

    Dyeing red with 2,6-dicyano-2'-sulfonamido-4'-amino-azo-benzenes
    7.
    发明授权
    Dyeing red with 2,6-dicyano-2'-sulfonamido-4'-amino-azo-benzenes 失效
    用2,6-二氰基-2'-亚磺酰氨基-4'-氨基偶氮苯染色红色

    公开(公告)号：US4452609A

    公开(公告)日：1984-06-05

    申请号：US449310

    申请日：1982-12-13

    申请人： Rainer Hamprecht

    发明人： Rainer Hamprecht

    IPC分类号： C09B29/01 ,  C09B29/08 ,  C09B29/085 ,  D06P1/16 ,  C07C161/06 ,  D06P1/02

    CPC分类号： C09B29/0003 ,  C09B29/08 ,  Y10S534/02 ,  Y10S8/922

    摘要： Azo compounds of the formula ##STR1## wherein R.sub.1 is alkyl, alkenyl, aralkyl, aryl or hetaryl,R.sub.2 is hydrogen or alkyl,R.sub.3 is hydrogen, alkyl, halogen, OR.sub.1 etc.R.sub.4 is hydrogen, alkyl, aralkyl, aryl or cycloalkyl,R.sub.5 is hydrogen, alkyl, alkenyl or aralkyl,Y is cyano, halogen, trifluoromethyl, nitro or SO.sub.2 R.sub.1,Y.sub.1 is halogen or preferably cyano,X.sub.1 is hydrogen or a substituent with a Hammet .sigma. para value of -0.3 to +0.3,X.sub.2 is hydrogen, halogen etc.,are useful for dyeing polyester fibre materials in clear red to violet shades with good general fastness properties.

    摘要翻译： 其中R 1是烷基，烯基，芳烷基，芳基或杂芳基，R 2是氢或烷基，R 3是氢，烷基，卤素，OR 1等。R 4是氢，烷基，芳烷基，芳基或环烷基， R 5是氢，烷基，烯基或芳烷基，Y是氰基，卤素，三氟甲基，硝基或SO 2 R 1，Y 1是卤素或优选地是氰基，X 1是氢或取代基，其中Hammet sigma对值为-0.3至+0.3，X2是 氢，卤素等，可用于以明显的红色至紫色色调染色聚酯纤维材料，具有良好的一般牢度特性。

    Halo-substituted amino-and substituted-sulphonamido-containing azo dyestuffs
    8.
    发明授权
    Halo-substituted amino-and substituted-sulphonamido-containing azo dyestuffs 失效
    卤代氨基和取代磺酰氨基偶氮染料

    公开(公告)号：US4424156A

    公开(公告)日：1984-01-03

    申请号：US185660

    申请日：1980-09-10

    申请人： Rainer Hamprecht ,  Klaus Leverenz

    发明人： Rainer Hamprecht ,  Klaus Leverenz

    IPC分类号： C09B29/08 ,  C09B29/036 ,  C09B29/039 ,  C09B29/085 ,  C09B29/09

    CPC分类号： C09B29/0833 ,  Y10S534/02

    摘要： An azo dyestuff suited for dyeing polyester, of the formula ##STR1## in which Hal is F, Cl, Br or I, R.sub.1 is a C.sub.1 -C.sub.10 -aliphatic hydrocarbyl or a C.sub.5 -C.sub.8 -cycloalkyl radical optionally substituted by OH, halogen, alkoxy, aryloxy or acyloxy, R.sub.2 is an optionally substituted aliphatic hydrocarbyl, aryl or hetaryl radical, R.sub.1 and R.sub.2 being free from --SO.sub.3 H and/or --COOH radicals, Z.sub.1 to Z.sub.4 each independently is hydrogen, alkyl, cycloalkyl, aralkyl, halogen, --CN, --NO.sub.2, --CF.sub.3, --SO.sub.2 Q, --SO.sub.2 NVW, --COW, --CONVW, --CO.sub.2 W, --OQ, --NVW, --NWCOW, --NWSO.sub.2 Q or --NHCO.sub.2 Q, or Z.sub.2 may also be arylazo, and Z.sub.3 may also be ##STR2## and Z.sub.3 and Z.sub.4 together can be ##STR3## Q is alkyl, aralykl or aryl, U is alkyl, V is H, alkyl or aralkyl, and W is V or aryl.

    摘要翻译： 适用于染色聚酯的偶氮染料，其中Hal为F，Cl，Br或I的式为“IMAGE”，R1为任选被OH，卤素取代的C 1 -C 10 - 脂族烃基或C 5 -C 8环烷基， 烷氧基，芳氧基或酰氧基，R2是任选取代的脂族烃基，芳基或杂芳基，R1和R2不含-SO3H和/或-COOH基团，Z1至Z4各自独立地为氢，烷基，环烷基，芳烷基，卤素， -CN，-NO 2，-CF 3，-SO 2 Q，-SO 2 N V W，-COW，-CONVW，-CO 2 W，-OQ，-NVW，-NWCOW，-NWSO 2 Q或-NHCO 2 Q，或Z 2也可以是芳基偶氮，Z 3也可以 并且Z 3和Z 4可以一起作为Q是烷基，芳烷基或芳基，U是烷基，V是H，烷基或芳烷基，W是V或芳基。

    Disperse azo dyestuffs
    9.
    发明授权
    Disperse azo dyestuffs 失效
    分散偶氮染料

    公开(公告)号：US07682408B2

    公开(公告)日：2010-03-23

    申请号：US12281003

    申请日：2007-03-02

    申请人： Andreas Endres ,  Rainer Hamprecht ,  Hartwig Jordan ,  Anthony Lawrence ,  Nigel Hall

    发明人： Andreas Endres ,  Rainer Hamprecht ,  Hartwig Jordan ,  Anthony Lawrence ,  Nigel Hall

    IPC分类号： C09B29/08 ,  C08B11/155

    CPC分类号： C09B29/0003

    摘要： The present invention relates to a dyestuff of the formula (I) wherein each of G1 and G2, independently is hydrogen, (C1-C4)-alkyl, trifluoromethyl, halogen, nitro, cyano or —SO2—T, wherein T is halogen, (C1-C4)-alkyl, (C1-C4)-alkoxy, aryl or aryloxy; K is a coupling component; and n is 1 or 2. The invention also relates to a process for its preparation and their use and for ink jet printing containing the ink.

    摘要翻译： 本发明涉及式（I）的染料，其中G1和G2各自独立地为氢，（C1-C4） - 烷基，三氟甲基，卤素，硝基，氰基或-SO2-T，其中T为卤素， （C 1 -C 4） - 烷基，（C 1 -C 4） - 烷氧基，芳基或芳氧基; K是耦合元件; 并且n为1或2.本发明还涉及其制备方法及其用途和用于含有油墨的喷墨印刷。