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1.发明授权Cell casing with a hermetic mechanical seal and a hermetically sealed sodium-sulfur cell 失效具有机械密封的密封和密封的硫酸钠细胞的细胞壳
公开(公告)号：US3946751A
公开(公告)日：1976-03-30
申请号：US550464
申请日：1975-02-18
CPC分类号： H01M10/3909
摘要： A cell casing and a hermetically sealed sodium-sulfur cell are disclosed wherein the cell casing includes a hermetic mechanical seal joining two opposed outer metallic casing portions to a ceramic ring supporting an inner casing of a solid sodium ion-conductive material. A hermetically sealed sodium-sulfur cell has the above type of casing with a sodium negative electrode in the inner casing and a positive electrode of sulfur in conductive material in an outer casing portion surrounding the inner casing.
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公开(公告)号：US4291108A
公开(公告)日：1981-09-22
申请号：US180601
申请日：1980-08-25
CPC分类号： H01M10/3918 , C04B35/113 , C04B35/64
摘要： A sintered .beta.-alumina cylindrical tube of uniform shape is produced by placing the unsintered tube within a sagger, passing the sagger on friction-reducing balls through a horizontal firing tube and continuously alternately rotating the tube-containing sagger through the firing tube so that all portions of the tube therewithin experience on the average the same gravitational effect.
摘要翻译： 通过将未烧结管放置在一个s ger中，通过一个水平的发射管使阻塞的摩擦减小球通过射流管连续地交替地旋转通过射出管的管状的s so，使得所有的 其中管的部分平均具有相同的引力效应。
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公开(公告)号：US3976554A
公开(公告)日：1976-08-24
申请号：US645549
申请日：1975-12-31
IPC分类号： C04B35/113 , C25D13/02 , C25D1/14 , C25D1/20
CPC分类号： C25D13/02 , C04B35/113
摘要： A method of forming a beta-alumina article includes electrophoretically depositing such material on a mandrel, exposing the deposited material promptly to a continuous flow of warm air thereby drying the deposited material, and sintering the dried material. Alternately, the deposited material is stored in a chamber purged continuously with an inert gas until the material is dried in a flow of warm dry air. Such articles are useful as solid electrolytes in sodium-sulfur and sodium halogen batteries.
摘要翻译： 形成β-氧化铝制品的方法包括将这种材料电泳沉积在心轴上，将沉积的材料迅速地暴露于连续的暖空气流中，从而干燥沉积的材料，并烧结干燥的材料。 或者，将沉积的材料储存在用惰性气体连续吹扫的室中，直到材料在温暖的干燥空气流中干燥。 这些物品可用作钠硫和钠卤素电池中的固体电解质。
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公开(公告)号：US4302519A
公开(公告)日：1981-11-24
申请号：US180600
申请日：1980-08-25
CPC分类号： H01M10/3918 , C04B35/113 , C04B35/64
摘要： A sintered .beta.-alumina cylindrical tube of uniform shape is produced by placing the unsintered tube within a sagger, passing the sagger on friction-reducing balls through a horizontal firing tube and rotating the tube-containing sagger through the firing tube.
摘要翻译： 通过将未烧结管放置在一个s ger中，通过一个水平的发射管将阻流通过减摩球，并通过射出管旋转含管的s。，产生均匀形状的烧结的β-氧化铝圆柱形管。
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公开(公告)号：US3960596A
公开(公告)日：1976-06-01
申请号：US447850
申请日：1974-03-04
CPC分类号： H01M10/3909
摘要： A battery casing and a sealed sodium-sulfur battery are disclosed wherein the battery casing includes separate seals of low temperature melting glass joining a portion of an inner casing of a solid sodium ion-conductive material to the interior surface of a ceramic ring, and joining two opposed outer metallic casings to the ceramic ring. A sealed sodium-sulfur battery has the above type of casing with a sodium anode in one casing and a cathode of sulfur in conductive material in the other casing.
摘要翻译： 公开了电池壳体和密封钠硫电池，其中电池壳体包括将固体钠离子传导材料的内壳的一部分与陶瓷环的内表面接合的低温熔融玻璃的分开的密封，以及接合 两个相对的外部金属外壳到陶瓷环。 密封的钠硫电池具有上述类型的壳体，在一个壳体中具有钠阳极，在另一个壳体中具有导电材料中的硫的阴极。
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公开(公告)号：US4132820A
公开(公告)日：1979-01-02
申请号：US804941
申请日：1977-06-09
申请人： Stephan P. Mitoff
发明人： Stephan P. Mitoff
CPC分类号： C04B35/113 , C03C8/02 , H01M10/3909 , H01M2/08 , Y10T428/215 , Y10T428/24322
摘要： A composite body has a beta-alumina substrate with at least one aperture therethrough, and a glass coating covering and adhering to the entire external surface of the substrate. The glass coating has sodium resistance, low alkali ion-conductance, and a coefficient of thermal expansion of 7.3 to 6.1 .times. 10.sup.-6 inches/inch/.degree. C.
摘要翻译： 复合体具有穿过其中的至少一个孔的β-氧化铝基底和覆盖并附着到基底的整个外表面的玻璃涂层。 玻璃涂层具有耐钠性，低碱离子电导率和7.3至6.1×10 -6英寸/英寸/℃的热膨胀系数。
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公开(公告)号：US4833039A
公开(公告)日：1989-05-23
申请号：US125091
申请日：1987-11-25
CPC分类号： H05K3/4061 , C04B41/52 , C04B41/89 , H05K3/246 , H05K3/247 , H05K1/0306 , H05K1/092 , H05K2201/0116 , H05K2201/0347 , H05K2201/035 , H05K2203/1147 , H05K2203/128 , Y10T428/12007 , Y10T428/12056 , Y10T428/12118
摘要： A process for producing an hermetic feedthrough in a ceramic substrate by providing a sheet of liquid phase sinterable ceramic composition having a feedthrough hole, filling the feedthrough hole with refractory metal metallization material, firing the resulting structure to produce a sintered substrate and adherent metallization wherein the metallization is comprised of continuous phases of refractory metal and glass, contacting the refractory metal with electrically conductive intrusion metal and heating the resulting structure to a temperature at which the glassy phase is fluid, the refractory metal is solid, and the intrusion metal is liquid whereby the liquid metal preferentially wets the refractory metal, migrates into the metallization displacing glass and, upon subsequent solidification, partially or wholly occupies the volume space originally containing the continuous glass phase.
摘要翻译： 一种通过提供一种具有馈通孔的液相可烧结陶瓷组合物制成密封馈通的方法，用耐火金属金属化材料填充馈通孔，烧制所得结构以产生烧结基底和粘附金属化，其中， 金属化由耐火金属和玻璃的连续相组成，使难熔金属与导电侵入金属接触，并将所得结构加热至玻璃相为流体的温度，难熔金属为固体，侵入金属为液体，由此 液体金属优先润湿难熔金属，迁移到金属化位移玻璃中，并且在随后的固化时，部分或全部占据原始包含连续玻璃相的体积空间。
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公开(公告)号：US4269909A
公开(公告)日：1981-05-26
申请号：US113280
申请日：1980-01-18
申请人： Randall N. King , Stephan P. Mitoff
发明人： Randall N. King , Stephan P. Mitoff
CPC分类号： H01M10/3909 , Y10T29/4911
摘要： A sodium-sulfur cell is disclosed herein along with a method of constructing its sulfur electrode. The cell includes means containing a supply of sodium, an elongated housing joined at one end with sodium containing means, a beta-alumina electrolyte tube located within and extending from the joined end of the housing so as to define a compartment within the housing around the tube. A mixture including sulfur and an electrically conductive filler is disposed within the compartment and forms the cells sulfur electrode. In constructing this electrode, sufficient space is initially provided within the cell compartment around the beta-alumina electrolyte tube to allow for expansion of the sulfur when the latter converts from its solidified state during initial storage to its molten state during operation of the cell, thereby minimizing the possibility of damage to the electrolyte tube as a result of this expansion.
摘要翻译： 本文公开了硫 - 硫电池以及构成其硫电极的方法。 电池包括含有钠的装置，在一端与含钠装置连接的细长壳体，位于壳体的连接端内并从壳体的连接端延伸的β-氧化铝电解质管，以便在壳体内围绕 管。 包含硫和导电填料的混合物设置在隔室内并形成电池硫电极。 在构建该电极时，初始在β氧化铝电解质管周围的电池室内提供足够的空间，以允许当电池在初始储存期间从其固化状态转变为其在电池运行期间的熔融状态时膨胀硫，由此 最小化由于这种膨胀而导致电解质管损坏的可能性。
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公开(公告)号：US4220691A
公开(公告)日：1980-09-02
申请号：US945624
申请日：1978-09-25
申请人： Walter L. Roth , Stephan P. Mitoff
发明人： Walter L. Roth , Stephan P. Mitoff
IPC分类号： H01M10/39
CPC分类号： H01M10/3909
摘要： In a sodium sulfur cell including a beta-alumina separator between the sodium and sulfur compartments, high surface area gettering means, e.g., beta-alumina or beta"-alumina, for potassium and alkali earth metal ion impurities in the sodium to protect the separator. The gettering means is disposed in the sodium container in the form of particles or a continous porous shell or porous solid plug adjacent to the separator.
摘要翻译： 在包含钠和硫隔室之间的β氧化铝分离器的钠硫电池中，高表面积吸气手段，例如β-氧化铝或β“ - 氧化铝，用于钾和碱土金属离子杂质在钠中保护 分隔器。 吸气装置以与颗粒相邻的颗粒或连续多孔壳或多孔固体塞的形式设置在钠容器中。
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公开(公告)号：US4189530A
公开(公告)日：1980-02-19
申请号：US945620
申请日：1978-09-25
申请人： Stephan P. Mitoff
发明人： Stephan P. Mitoff
CPC分类号： H01M10/3909 , Y10T29/4911
摘要： Molten sodium is filled into a reservoir insert container including a closed ended tubular portion and the sodium is solidified and the container sealed. Then an open port is provided for the insert container. The container is placed into the sodium compartment of a sodium-sulfur cell so that the tubular portion extends into the electrolytic separator tube of the cell and is spaced apart therefrom forming an annular chamber. To activate the cell, the sodium is melted and flows through the open port into the annular chamber.
摘要翻译： 将熔融钠填充到包括封闭端部管状部分的储存器插入容器中，并将钠固化并将容器密封。 然后为插入容器提供开口。 将容器放入钠 - 硫电池的钠隔室中，使得管状部分延伸到电池的电解分离器管中，并与其隔开形成环形室。 为了激活电池，钠被熔化并流过开口进入环形室。
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