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公开(公告)号：US08936089B2
公开(公告)日：2015-01-20
申请号：US13335409
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein.
摘要翻译： 从地下（油）页岩层中提取干酪根类产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。
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公开(公告)号：US20120175116A1
公开(公告)日：2012-07-12
申请号：US13335673
申请日：2011-12-22
IPC分类号： A47B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein. These organic acids are valuable as hydrocarbon products for creating commercial products and a portion of these organic acids can also be used in the process for extracting the kerogen-based product from the subsurface shale formation.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。 这些有机酸作为用于产生商业产品的烃产品是有价值的，并且这些有机酸的一部分也可用于从地下页岩层中提取干酪根基产物的方法。
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公开(公告)号：US08839860B2
公开(公告)日：2014-09-23
申请号：US13335525
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： The invention relates to methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. In one embodiment, the mobile kerogen-based product is treated such that at least a portion of the organic acids form a separate phase from the mobile kerogen-based product to isolate the acids. The organic acids may further be extracted from the mobile kerogen-based product using an organic extraction fluid.
摘要翻译： 本发明涉及从地下（油）页岩层中提取含有油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 在一个实施方案中，处理基于活性干酪根的产物，使得至少一部分有机酸与来自可移动的基于油母质的产物形成分离相以分离酸。 有机酸可以使用有机萃取液从可移动的基于油母质的产品中进一步提取。
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公开(公告)号：US20120175115A1
公开(公告)日：2012-07-12
申请号：US13335607
申请日：2011-12-22
IPC分类号： A47B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. The isolated organic acids are upgraded by a reaction process that make the products suitable as refinery feedstocks, fuel or lubricant blendstocks, reaction intermediates, chemical feedstocks, or chemical intermediate blendstocks.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 分离的有机酸通过反应过程升级，使得产物适合作为炼油原料，燃料或润滑剂共混物，反应中间体，化学原料或化学中间体共混物。
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公开(公告)号：US09133398B2
公开(公告)日：2015-09-15
申请号：US13335673
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Methods for extracting a kerogen-based product from subsurface (oil) shale formations rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein. These organic acids are valuable as hydrocarbon products for creating commercial products and a portion of these organic acids can also be used in the process for extracting the kerogen-based product from the subsurface shale formation.
摘要翻译： 从地下（油）页岩层中提取含有油母质的产品的方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。 这些有机酸作为用于产生商业产品的烃产品是有价值的，并且这些有机酸的一部分也可用于从地下页岩层中提取干酪根基产物的方法。
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公开(公告)号：US08997869B2
公开(公告)日：2015-04-07
申请号：US13335607
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. The isolated organic acids are upgraded by a reaction process that make the products suitable as refinery feedstocks, fuel or lubricant blendstocks, reaction intermediates, chemical feedstocks, or chemical intermediate blendstocks.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 分离的有机酸通过反应过程升级，使得产物适合作为炼油原料，燃料或润滑剂共混物，反应中间体，化学原料或化学中间体共混物。
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公开(公告)号：US20120175114A1
公开(公告)日：2012-07-12
申请号：US13335525
申请日：2011-12-22
IPC分类号： E21B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. An exemplary method for isolating the acids includes treating the mobile kerogen-based product such that at least a portion of the organic acids form a separate phase from the mobile kerogen-based product. The organic acids may further be extracted from the mobile kerogen-based product using an organic extraction fluid.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 用于分离酸的示例性方法包括处理可移动的基于油母质的产品，使得至少一部分有机酸与可移动的基于油母质的产品形成分离的相。 有机酸可以使用有机萃取液从可移动的基于油母质的产品中进一步提取。
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公开(公告)号：US20120160486A1
公开(公告)日：2012-06-28
申请号：US13335409
申请日：2011-12-22
IPC分类号： E21B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。
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公开(公告)号：US08992771B2
公开(公告)日：2015-03-31
申请号：US13481303
申请日：2012-05-25
IPC分类号： C10G1/04 , E21B43/16 , E21B43/22 , E21B43/34 , C10M101/02 , C10M105/04 , C10M177/00 , F17D1/16
CPC分类号： C10M101/02 , C10M105/04 , C10M177/00 , C10N2260/02 , E21B43/16 , E21B43/34 , F17D1/16 , Y10T137/0391
摘要： Disclosed herein are methods for isolating heavy saturated hydrocarbons from a subsurface shale formation comprising kerogen and an extractible organics component. These methods can be used to provide a bright stock product. The process comprises extracting an extractible organics component from subsurface shale formations comprising kerogen and the extractible organics component in an inorganic matrix and isolating a heavy hydrocarbon fraction comprising saturated beta-carotene. The methods utilize a hydrocarbon solvent to at least partially solubilize the extractible organics component. Among other factors, these processes are based on the discovery that the extractible organics is composed of a heavy hydrocarbon component containing saturated beta-carotene. The saturated beta-carotene product is a valuable commercial product. The presently disclosed processes are more environmentally benign, more economical, and more efficient in producing commercial products and in providing access to kerogen.
摘要翻译： 本文公开了从含有干酪根和可提取的有机物组分的地下页岩层中分离重饱和烃的方法。 这些方法可用于提供光亮的原料产品。 该方法包括从含有无机基质中的干酪根和可萃取的有机物组分的地下页岩层中提取可提取的有机物组分，并分离包含饱和β-胡萝卜素的重质烃馏分。 该方法利用烃溶剂至少部分增溶可萃取的有机物成分。 除其他因素之外，这些方法是基于以下发现：可萃取的有机物由含有饱和β-胡萝卜素的重质烃组分组成。 饱和β-胡萝卜素产品是有价值的商业产品。 目前公开的方法在生产商业产品和提供对油母质的接触方面更环保，更经济，更有效。
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公开(公告)号：US20130313160A1
公开(公告)日：2013-11-28
申请号：US13481303
申请日：2012-05-25
IPC分类号： E21B43/34 , F17D1/16 , C10M101/02
CPC分类号： C10M101/02 , C10M105/04 , C10M177/00 , C10N2260/02 , E21B43/16 , E21B43/34 , F17D1/16 , Y10T137/0391
摘要： Disclosed herein are methods for isolating heavy saturated hydrocarbons from a subsurface shale formation comprising kerogen and an extractible organics component. These methods can be used to provide a bright stock product. The process comprises extracting an extractible organics component from subsurface shale formations comprising kerogen and the extractible organics component in an inorganic matrix and isolating a heavy hydrocarbon fraction comprising saturated beta-carotene. The methods utilize a hydrocarbon solvent to at least partially solubilize the extractible organics component. Among other factors, these processes are based on the discovery that the extractible organics is composed of a heavy hydrocarbon component containing saturated beta-carotene. The saturated beta-carotene product is a valuable commercial product. The presently disclosed processes are more environmentally benign, more economical, and more efficient in producing commercial products and in providing access to kerogen.
摘要翻译： 本文公开了从含有干酪根和可提取的有机物组分的地下页岩层中分离重饱和烃的方法。 这些方法可用于提供光亮的原料产品。 该方法包括从含有无机基质中的干酪根和可萃取的有机物组分的地下页岩层中提取可提取的有机物组分，并分离包含饱和β-胡萝卜素的重质烃馏分。 该方法利用烃溶剂至少部分增溶可萃取的有机物成分。 除其他因素之外，这些方法是基于以下发现：可萃取的有机物由含有饱和β-胡萝卜素的重质烃组分组成。 饱和β-胡萝卜素产品是有价值的商业产品。 目前公开的方法在生产商业产品和提供对油母质的接触方面更环保，更经济，更有效。
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