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公开(公告)号：US08936089B2
公开(公告)日：2015-01-20
申请号：US13335409
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein.
摘要翻译： 从地下（油）页岩层中提取干酪根类产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。
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公开(公告)号：US20120175116A1
公开(公告)日：2012-07-12
申请号：US13335673
申请日：2011-12-22
IPC分类号： A47B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein. These organic acids are valuable as hydrocarbon products for creating commercial products and a portion of these organic acids can also be used in the process for extracting the kerogen-based product from the subsurface shale formation.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。 这些有机酸作为用于产生商业产品的烃产品是有价值的，并且这些有机酸的一部分也可用于从地下页岩层中提取干酪根基产物的方法。
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公开(公告)号：US08839860B2
公开(公告)日：2014-09-23
申请号：US13335525
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： The invention relates to methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. In one embodiment, the mobile kerogen-based product is treated such that at least a portion of the organic acids form a separate phase from the mobile kerogen-based product to isolate the acids. The organic acids may further be extracted from the mobile kerogen-based product using an organic extraction fluid.
摘要翻译： 本发明涉及从地下（油）页岩层中提取含有油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 在一个实施方案中，处理基于活性干酪根的产物，使得至少一部分有机酸与来自可移动的基于油母质的产物形成分离相以分离酸。 有机酸可以使用有机萃取液从可移动的基于油母质的产品中进一步提取。
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公开(公告)号：US20120175115A1
公开(公告)日：2012-07-12
申请号：US13335607
申请日：2011-12-22
IPC分类号： A47B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. The isolated organic acids are upgraded by a reaction process that make the products suitable as refinery feedstocks, fuel or lubricant blendstocks, reaction intermediates, chemical feedstocks, or chemical intermediate blendstocks.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 分离的有机酸通过反应过程升级，使得产物适合作为炼油原料，燃料或润滑剂共混物，反应中间体，化学原料或化学中间体共混物。
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公开(公告)号：US09133398B2
公开(公告)日：2015-09-15
申请号：US13335673
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Methods for extracting a kerogen-based product from subsurface (oil) shale formations rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein. These organic acids are valuable as hydrocarbon products for creating commercial products and a portion of these organic acids can also be used in the process for extracting the kerogen-based product from the subsurface shale formation.
摘要翻译： 从地下（油）页岩层中提取含有油母质的产品的方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。 这些有机酸作为用于产生商业产品的烃产品是有价值的，并且这些有机酸的一部分也可用于从地下页岩层中提取干酪根基产物的方法。
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公开(公告)号：US08997869B2
公开(公告)日：2015-04-07
申请号：US13335607
申请日：2011-12-22
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. The isolated organic acids are upgraded by a reaction process that make the products suitable as refinery feedstocks, fuel or lubricant blendstocks, reaction intermediates, chemical feedstocks, or chemical intermediate blendstocks.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 分离的有机酸通过反应过程升级，使得产物适合作为炼油原料，燃料或润滑剂共混物，反应中间体，化学原料或化学中间体共混物。
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公开(公告)号：US20120175114A1
公开(公告)日：2012-07-12
申请号：US13335525
申请日：2011-12-22
IPC分类号： E21B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and processed to isolate the organic acids contained therein. An exemplary method for isolating the acids includes treating the mobile kerogen-based product such that at least a portion of the organic acids form a separate phase from the mobile kerogen-based product. The organic acids may further be extracted from the mobile kerogen-based product using an organic extraction fluid.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 包括有机酸的基于移动干酪根的产品从地下页岩地层中取出并进行处理以分离其中所含的有机酸。 用于分离酸的示例性方法包括处理可移动的基于油母质的产品，使得至少一部分有机酸与可移动的基于油母质的产品形成分离的相。 有机酸可以使用有机萃取液从可移动的基于油母质的产品中进一步提取。
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公开(公告)号：US20120160486A1
公开(公告)日：2012-06-28
申请号：US13335409
申请日：2011-12-22
IPC分类号： E21B43/00
CPC分类号： C10G1/04 , C10G9/00 , C10G27/06 , C10G27/12 , C10G49/00 , C10G2300/4081 , C10G2400/10 , E21B43/24 , Y02P30/44
摘要： Disclosed herein are methods for extracting a kerogen-based product from subsurface (oil) shale formations. These methods rely on chemically modifying the shale-bound kerogen using a chemical oxidant so as to render it mobile. The oxidant is provided to a formation fluid in contact with the kerogen in the subsurface shale. An alkaline material is also provided to the formation fluid to mobilize organic acids which are produced during oxidation of the kerogen. A mobile kerogen-based product which includes the organic acids is withdrawn from the subsurface shale formation and further processed to isolate the organic acids contained therein.
摘要翻译： 本文公开了从地下（油）页岩层中提取基于油母质的产品的方法。 这些方法依靠使用化学氧化剂对页岩结合的干酪根进行化学修饰，以使其移动。 将氧化剂提供给与地下页岩中的干酪根接触的地层流体。 还向地层流体提供碱性物质以移动在干酪根氧化期间产生的有机酸。 包括有机酸的基于移动干酪根的产品从地下页岩地层中排出并进一步处理以分离其中所含的有机酸。
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公开(公告)号：US07789164B2
公开(公告)日：2010-09-07
申请号：US12361473
申请日：2009-01-28
申请人： Mark Dean Looney , Robert Steven Lestz , Kirk Hollis , Craig Taylor , Scott Kinkead , Marcus Wigand
发明人： Mark Dean Looney , Robert Steven Lestz , Kirk Hollis , Craig Taylor , Scott Kinkead , Marcus Wigand
IPC分类号： E21B43/17 , E21B43/22 , E21B43/24 , E21B43/263
CPC分类号： E21B43/241 , C09K8/594 , E21B43/247 , Y02P20/544
摘要： The present invention is directed to methods for extracting a kerogen-based product from subsurface (oil) shale formations, wherein such methods rely on fracturing and/or rubblizing portions of said formations so as to enhance their fluid permeability, and wherein such methods further rely on chemically modifying the shale-bound kerogen so as to render it mobile. The present invention is also directed at systems for implementing at least some of the foregoing methods. Additionally, the present invention is also directed to methods of fracturing and/or rubblizing subsurface shale formations and to methods of chemically modifying kerogen in situ so as to render it mobile.
摘要翻译： 本发明涉及从地下（油）页岩层中提取含有油母质的产品的方法，其中这种方法依赖于将所述地层的部分压裂和/或碎化以增强其流体渗透性，并且其中这些方法进一步依赖 化学改性页岩结合的干酪根，以使其可移动。 本发明还涉及用于实现上述方法中的至少一些的系统。 此外，本发明还涉及压裂和/或摩擦地下页岩层的方法以及原位化学改性干酪根以便使其移动的方法。
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公开(公告)号：US20090126934A1
公开(公告)日：2009-05-21
申请号：US12361473
申请日：2009-01-28
申请人： Mark Dean Looney , Robert Steven Lestz , Kirk Hollis , Craig Taylor , Scott Kinead , Marcus Wigand
发明人： Mark Dean Looney , Robert Steven Lestz , Kirk Hollis , Craig Taylor , Scott Kinead , Marcus Wigand
CPC分类号： E21B43/241 , C09K8/594 , E21B43/247 , Y02P20/544
摘要： The present invention is directed to methods for extracting a kerogen-based product from subsurface (oil) shale formations, wherein such methods rely on fracturing and/or rubblizing portions of said formations so as to enhance their fluid permeability, and wherein such methods further rely on chemically modifying the shale-bound kerogen so as to render it mobile. The present invention is also directed at systems for implementing at least some of the foregoing methods. Additionally, the present invention is also directed to methods of fracturing and/or rubblizing subsurface shale formations and to methods of chemically modifying kerogen in situ so as to render it mobile.
摘要翻译： 本发明涉及从地下（油）页岩层中提取含有油母质的产品的方法，其中这种方法依赖于将所述地层的部分压裂和/或碎化以增强其流体渗透性，并且其中这些方法进一步依赖 化学改性页岩结合的干酪根，以使其可移动。 本发明还涉及用于实现上述方法中的至少一些的系统。 此外，本发明还涉及压裂和/或摩擦地下页岩层的方法以及原位化学改性干酪根以便使其移动的方法。
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