公开(公告)号：US06333086B1

公开(公告)日：2001-12-25

申请号：US08535259

申请日：1996-01-29

申请人： Marja Ora ,  Esa Suokas ,  Mika Härkönen ,  Seppo Kuusela ,  Erkki Laiho

发明人： Marja Ora ,  Esa Suokas ,  Mika Härkönen ,  Seppo Kuusela ,  Erkki Laiho

IPC分类号： B29D2200

CPC分类号： B32B27/08 ,  B32B1/02 ,  B32B1/08 ,  B32B27/10 ,  B32B27/32 ,  B32B27/36 ,  B32B37/153 ,  B32B2307/7244 ,  B32B2317/12 ,  B32B2323/043 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2367/00 ,  B32B2439/60 ,  B32B2439/66 ,  B32B2439/70 ,  B32B2597/00 ,  Y10T428/1303 ,  Y10T428/1352 ,  Y10T428/31688 ,  Y10T428/31786

摘要： The present invention concerns a multilayered polymer film structure, which comprises at least one first layer (1) containing a thermoplastic polymer and at least one second layer (2), arranged adjacent to said first layer, containing a liquid crystalline polymer. According to the invention, the second layer (2) consists essentially of a compounded polymer blend formed by the liquid crystalline polymer and a thermoplastic polymer, the liquid crystalline polymer of the second layer forms a continuous phase, and the first and the second layers (1, 2) contain the same thermoplastic polymer. The oxygen transmission rate of the second layer is less than about 150 cm3/(m2·d·bar), determined according to the standard ASTM D 3985-81, and the water vapour transmission rate of the integral film structure is less than 10 g/(m2·24·h) at RH 80% 23° C., determined according to ASTM F 1249-90. The present structure can be used as a barrier layer in packages.

摘要翻译： 本发明涉及一种多层聚合物膜结构，其包括含有热塑性聚合物的至少一个第一层（1）和邻近所述第一层设置的包含液晶聚合物的至少一个第二层（2）。 根据本发明，第二层（2）基本上由由液晶聚合物和热塑性聚合物形成的复合聚合物共混物组成，第二层的液晶聚合物形成连续相，并且第一和第二层（ 1,2）含有相同的热塑性聚合物。 根据标准ASTM D 3985-81测定，第二层的氧气透过率小于约150cm 3 /（m2.d.bar），整体膜结构的水蒸汽透过率小于10g /(m2.24.h）在RH80％23℃下，根据ASTM F 1249-90测定。 本结构可用作封装中的阻挡层。

公开(公告)号：US09657147B2

公开(公告)日：2017-05-23

申请号：US14123065

申请日：2012-05-23

申请人： Jun Shan ,  Mika Härkönen ,  Jarmo Ropponen ,  Ali Harlin ,  Harri Heikkinen ,  Virpi Rämö ,  Thomas Gädda ,  Leena Nurmi ,  Pia Willberg-Keyriläinen

发明人： Jun Shan ,  Mika Härkönen ,  Jarmo Ropponen ,  Ali Harlin ,  Harri Heikkinen ,  Virpi Rämö ,  Thomas Gädda ,  Leena Nurmi ,  Pia Willberg-Keyriläinen

IPC分类号： C08G63/82 ,  C08J3/20 ,  C08G63/06 ,  C08G63/81 ,  C08G63/87

CPC分类号： C08J3/203 ,  C08G63/06 ,  C08G63/81 ,  C08G63/82 ,  C08G63/823 ,  C08G63/87 ,  Y10T428/2982

摘要： The present invention relates to a method for preparation a glycolide polyester by ring opening polymerization characterized in that glycolide monomer with optional co-monomer(s) of cyclic ester(s) is/are subjected to ring opening polymerization in the presence of a dispersion stabilizer and a catalyst, said catalyst being selected for precipitating glycolide homopolymer or copolymer from solvent, said solvent being selected so that the glycolide monomer and the optional co-monomer(s), the dispersion stabilizer and the catalyst are soluble therein but said glycolide homopolymer or copolymer is non-soluble. The present invention further relates to an in situ ring opening polymerizing process product, and to use of said glycolide polyester, and to further processing of said glycolide polyester.

公开(公告)号：US07182987B2

公开(公告)日：2007-02-27

申请号：US10344843

申请日：2001-08-15

申请人： Dirk Matthijs ,  Svein Jamtvedt ,  Mika Härkönen ,  Harry Øysaed

发明人： Dirk Matthijs ,  Svein Jamtvedt ,  Mika Härkönen ,  Harry Øysaed

IPC分类号： B32B1/08 ,  A61M5/00

CPC分类号： A61M5/3129 ,  B29C45/0001 ,  B29K2023/12 ,  B29K2091/00 ,  B29K2105/0094 ,  B29L2031/7544 ,  Y10T428/139

摘要： The invention provides a syringe barrel formed by injection moulding of a polypropylene composition, characterised in that said polypropylene composition contains a polyethylene wax. The invention further provides a syringe having a barrel formed by injection moulding of a polypropylene composition, characterised in that said polypropylene composition contains a polyethylene wax and a polypropylene composition suitable for such moulding.

摘要翻译： 本发明提供了一种通过聚丙烯组合物的注射成型形成的注射器筒，其特征在于，所述聚丙烯组合物含有聚乙烯蜡。 本发明还提供一种注射器，其具有由聚丙烯组合物的注模成型形成的筒体，其特征在于，所述聚丙烯组合物含有聚乙烯蜡和适于这种成型的聚丙烯组合物。

公开(公告)号：US06437063B1

公开(公告)日：2002-08-20

申请号：US09530689

申请日：2000-06-23

申请人： Amir Karbasi ,  Pauli Leskinen ,  Pirjo J{umlaut over (aa)}skeläinen ,  Bo Malm ,  Päivi Pitkänen ,  Mika Härkönen ,  John Haugen

发明人： Amir Karbasi ,  Pauli Leskinen ,  Pirjo J{umlaut over (aa)}skeläinen ,  Bo Malm ,  Päivi Pitkänen ,  Mika Härkönen ,  John Haugen

IPC分类号： C08F3200

CPC分类号： C08F10/06 ,  C08F4/65916 ,  C08F4/65927 ,  C08F110/06 ,  C08L23/0823 ,  C08L23/0838 ,  C08L23/10 ,  C08L2207/02 ,  C08L2314/06 ,  Y02P20/52 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/6492 ,  C08F4/6465 ,  C08F4/65912 ,  C08L2666/04 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/07 ,  C08F2500/12

摘要： The present invention concerns a process for producing a propylene polymer nucleated with a polymeric nucleating agent containing vinyl compound units. The method comprises modifying a catalyst by polymerizing a vinyl compound in the presence of said catalyst in a medium, which does not essentially dissolve the polymerized vinyl compound, and by continuing the polymerization of the vinyl compound until the concentration of unreacted vinyl compounds is less than about 0.5 wt-%. The thus obtained modified catalyst composition is used for polymerizing propylene optionally together with comonomers to produce in the presence of said modified catalyst composition. Modification of the catalyst according to the present invention will reduce production costs and provide highly reliable catalyst activity.

摘要翻译： 本发明涉及用含有乙烯基化合物单元的聚合物成核剂成核的丙烯聚合物的制备方法。 所述方法包括通过在所述催化剂存在下在介质中聚合乙烯基化合物来改性催化剂，该介质基本上不溶解聚合的乙烯基化合物，并且继续乙烯基化合物的聚合直到未反应的乙烯基化合物的浓度小于 约0.5wt％。 由此获得的改性催化剂组合物用于任选与共聚单体一起聚合丙烯，以在所述改性催化剂组合物存在下制备。 根据本发明的催化剂的改性将降低生产成本并提供高度可靠的催化剂活性。

公开(公告)号：US06221974B1

公开(公告)日：2001-04-24

申请号：US09171434

申请日：1998-12-21

申请人： Mika Härkönen ,  Bo Malm ,  Anders Nymark

发明人： Mika Härkönen ,  Bo Malm ,  Anders Nymark

IPC分类号： C08F29706

CPC分类号： F16L9/133 ,  F16L57/02

摘要： The invention relates to a process for the preparation of a creep-resistant polypropylene by means of the following steps: (a) copolymerizing propylene and ethylene into a random copolymer at 40 to 110° C. using: a catalyst system of the above-mentioned type; a portion of ethylene or C4-C10-&agr;-olefin leading to 1.0 to 10.0% by weight of ethylene repeating units in said random copolymer; and no or a minimal amount of hydrogen leading to a MFR10 value of between 0.01 and 5.0 g/10 min for said random copolymer, if this step is performed first, or to a MFR2 value for said polypropylene of between 0.05 and 0.40 g/10 min, if this step is performed after step (b); the proportion of random copolymer of this step being from 20 to 80% by weight of said polypropylene, (b) polymerizing propylene at 40 to 110° C. using: a catalyst system of the above-mentioned type; no or a minimal portion of ethylene leading to 0.0 to 1.0% by weight of ethylene repeating units in the polymer resulting from this step; and an amount of hydrogen leading to a MFR2 value of between 30 and 300 g/10 min for said polymer, if this step is performed first, or to a MFR2 value for said polypropylene of between 0.05 and 0.40 g/10 min, if this step is performed after step (a); the proportion of polymer of this step being from 80 to 20% by weight of said polypropylene.

摘要翻译： 本发明涉及一种通过以下步骤制备耐蠕变聚丙烯的方法：（a）在40-110℃下将丙烯和乙烯共聚到无规共聚物中，使用上述的催化剂体系 类型; 一部分乙烯或C4-C10-α-烯烃，导致所述无规共聚物中的乙烯重复单元的重量比为1.0-10.0％ 并且对于所述无规共聚物，如果首先进行该步骤，或者对于所述聚丙烯的MFR 2值为0.05-0.40g / 10min，则没有或最小量的氢导致MFR10值在0.01-5.0g / 10min之间 min，如果在步骤（b）之后执行该步骤; 该步骤的无规共聚物的比例为所述聚丙烯的20至80重量％，（b）在40至110℃下聚合丙烯，使用上述类型的催化剂体系; 乙烯的无或最小部分导致由该步骤得到的聚合物中的乙烯重复单元为0.0-1.0重量％ 如果该步骤首先进行，则导致所述聚合物的MFR 2值为30-300g / 10分钟的氢气量，或者对于所述聚丙烯的MFR 2值为0.05-0.40g / 10min，如果这样 在步骤（a）之后执行步骤; 该步骤的聚合物的比例为所述聚丙烯的80至20重量％。