CHEMICAL ANNEALING METHOD FOR FABRICATION OF ORGANIC THIN FILMS FOR OPTOELECTRONIC DEVICES
    1.
    发明申请
    CHEMICAL ANNEALING METHOD FOR FABRICATION OF ORGANIC THIN FILMS FOR OPTOELECTRONIC DEVICES 审中-公开
    用于制造光电器件有机薄膜的化学退火方法

    公开(公告)号:US20120177813A1

    公开(公告)日:2012-07-12

    申请号:US13274875

    申请日:2011-10-17

    IPC分类号: B05D3/10 B05D5/12 C23C16/44

    摘要: There is disclosed a method of coordinating ligands, such as nitrogen-containing ligands to metal centers of metal-containing macrocyclic compounds, such as Magnesium Tetraphenyl Porphyrin (MgTPP) or Zinc Tetraphenyl Porphyrin (ZnTPP). The disclosed method comprises (a) forming an organic film comprising the disclosed metal-containing, macrocyclic compound; and (b) exposing the organic film to a vapor comprising at least one ligand for a time sufficient to coordinate the ligand to metal centers in the metal-containing, macrocyclic compound. There is also disclosed a method for preparing an organic photovoltaic device, such as a solar cell, comprising an ordered crystalline organic film made by the disclosed chemical annealing process.

    摘要翻译: 公开了配位体如含金属的大环化合物如四苯基卟啉镁(MgTPP)或锌四苯基卟啉(ZnTPP)的金属中心的配体配位体的方法。 所公开的方法包括(a)形成包含所公开的含金属的大环化合物的有机膜; 和(b)将有机膜暴露于包含至少一种配体的蒸气足够长的时间以使该配体与含金属的大环化合物中的金属中心配位。 还公开了一种制备有机光伏器件的方法,例如太阳能电池,其包括通过公开的化学退火工艺制成的有序结晶有机膜。