公开(公告)号：US06417270B1

公开(公告)日：2002-07-09

申请号：US09757140

申请日：2001-01-09

申请人： Mark H. Wollum ,  Daniel F. Graves

发明人： Mark H. Wollum ,  Daniel F. Graves

IPC分类号： C08F25506

CPC分类号： C08F297/04

摘要： A process of preparing a diblock/triblock composition in a single reaction vessel includes reacting a first monomer, such as styrene, with a first portion of an anionic catalyst in a suitable solvent to form a first polymer block of the triblock. A second step includes adding a second monomer, such as butadiene (when the first monomer is styrene). This forms a second block of the triblock and a first block of the diblock. A further addition of the first monomer completes the diblock and triblock interpolymers. At least a portion of the diblock and/or triblock interpolymers are functionally terminated with a functional terminating agent, such as cyclohexene oxide or isopropanol, to provide the blocks with a functional group. The functional group and the proportion of the interpolymers functionally terminated are selected to provide desired adhesive properties for a particular application.

摘要翻译： 在单个反应容器中制备二嵌段/三嵌段组合物的方法包括使第一单体如苯乙烯与阴离子催化剂的第一部分在合适的溶剂中反应以形成三嵌段的第一聚合物嵌段。 第二步包括加入第二单体，如丁二烯（当第一单体是苯乙烯时）。 这形成了三次锁的第二块，并且形成了二块的第一块。 另外加入第一单体可完成二嵌段和三嵌段互聚物。 二嵌段和/或三嵌段互聚物的至少一部分用功能性终止剂如环己烯氧化物或异丙醇在功能上终止，以提供具有官能团的嵌段。 选择官能团和功能性终止的互聚物的比例以为特定应用提供期望的粘合剂性质。

公开(公告)号：US06362283B1

公开(公告)日：2002-03-26

申请号：US09676239

申请日：2000-09-29

申请人： Mark H. Wollum ,  Daniel F. Graves

发明人： Mark H. Wollum ,  Daniel F. Graves

IPC分类号： C08F25506

CPC分类号： C08F297/04 ,  C08L53/02 ,  C08L2666/04

摘要： A process for interpolymerizing a vinyl aromatic hydrocarbon polymer and a block polymer is disclosed. The process includes the following steps: (a) forming a block polymer precursor of at least one polymeric block containing conjugated diene monomer contributed units in the presence of an anionic initiator and in an inert diluent, the block polymer precursor having living ends; and (b) thereafter adding to the block polymer precursor a charge of a vinyl aromatic hydrocarbon monomer and an additional charge of an anionic initiator to simultaneously form (1) a block polymer having a terminal block formed from the charge of vinyl aromatic hydrocarbon monomer attached to the block polymer precursor and (2) a poly(vinyl aromatic hydrocarbon) polymer interpolymerized with the block polymer. The practice of this process produces a vinyl aromatic hydrocarbon block terminated block polymer, such as SBS, interpolymerized with a polymer formed from vinyl aromatic hydrocarbon monomer, such as polystyrene. The resultant interpolymer has a high Gardner Impact Strength and good processability.

摘要翻译： 公开了一种使乙烯基芳族烃聚合物和嵌段聚合物共聚的方法。 该方法包括以下步骤：（a）在阴离子引发剂存在下，在惰性稀释剂中形成含有共轭二烯单体的至少一个聚合物嵌段的嵌段聚合物前体，所述嵌段聚合物前体具有活性末端; 和（b）然后向嵌段聚合物前体中加入乙烯基芳族烃单体和另外的阴离子引发剂的电荷，以同时形成（1）具有由连接的乙烯基芳族烃单体的电荷形成的末端嵌段的嵌段聚合物 嵌段聚合物前体和（2）与嵌段聚合物共聚的聚（乙烯基芳族烃）聚合物。 该方法的实践产生与由乙烯基芳族烃单体如聚苯乙烯形成的聚合物共聚的乙烯基芳族烃嵌段封端的聚合物，例如SBS。 所得到的互聚物具有较高的加德纳冲击强度和良好的加工性能。

公开(公告)号：US06359075B1

公开(公告)日：2002-03-19

申请号：US09757141

申请日：2001-01-09

申请人： Mark H. Wollum ,  Daniel F. Graves

发明人： Mark H. Wollum ,  Daniel F. Graves

IPC分类号： C08F29702

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L2666/02 ,  C09J153/02

摘要： A process of preparing a diblock/triblock composition in a single reaction vessel includes reacting a first monomer, such as styrene, with a first portion of an anionic catalyst in a suitable solvent to form a first polymer block of the triblock. A second step includes adding a second portion of the catalyst and a second monomer, such as butadiene (when the first monomer is styrene). A portion of the resulting living diblock polymer is then terminated by addition of a chain transfer agent, which forms a second anionic catalyst in the process. Further sequential additions of the second and first monomers copolymerize with both the remaining living diblock and with the second anionic catalyst to complete the triblock polymer and form a second portion of diblock polymer.

摘要翻译： 在单个反应容器中制备二嵌段/三嵌段组合物的方法包括使第一单体如苯乙烯与阴离子催化剂的第一部分在合适的溶剂中反应以形成三嵌段的第一聚合物嵌段。 第二步包括加入第二部分催化剂和第二单体，如丁二烯（当第一单体是苯乙烯时）。 然后通过加入在该方法中形成第二阴离子催化剂的链转移剂终止一部分所得的活性二嵌段聚合物。 第二和第一单体的进一步顺序添加与剩余的活性二嵌段和第二阴离子催化剂共聚以完成三嵌段聚合物并形成二嵌段聚合物的第二部分。

公开(公告)号：US06492439B2

公开(公告)日：2002-12-10

申请号：US09750570

申请日：2000-12-28

申请人： Mark H. Wollum ,  Daniel F. Graves

发明人： Mark H. Wollum ,  Daniel F. Graves

IPC分类号： C08L9500

CPC分类号： C08L95/00 ,  C08L9/00 ,  C08L9/06 ,  C08L53/02 ,  C08L61/06 ,  C08L2666/08 ,  C08L53/00

摘要： A rubber-modified asphalt composition is provided. The asphalt composition includes asphalt, a rubber including at least high vinyl poly(conjugated diene), and at least one phenolic curing resin. The high vinyl poly(conjugated diene) has a vinyl content of at least 35%. The use of phenolic curing agents results in improvements to the softening point of the present asphalt composition while also improving toughness and tenacity.

摘要翻译： 提供橡胶改性沥青组合物。 沥青组合物包括沥青，包括至少高乙烯基聚（共轭二烯）的橡胶和至少一种酚类固化树脂。 高乙烯基聚（共轭二烯）的乙烯基含量至少为35％。 使用酚类固化剂导致改善本沥青组合物的软化点，同时还提高韧性和韧性。

公开(公告)号：US06486236B2

公开(公告)日：2002-11-26

申请号：US09750599

申请日：2000-12-28

申请人： Mark H. Wollum ,  Daniel F. Graves

发明人： Mark H. Wollum ,  Daniel F. Graves

IPC分类号： C08L9500

CPC分类号： C08K5/3415 ,  C08L9/06 ,  C08L95/00 ,  C08L2666/08

摘要： A rubber-modified asphalt composition is provided. The rubber includes at least a polydiene and may further include vinyl-substituted aromatic hydrocarbon monomer contributed units. The rubber is cured by a bismaleimide. The present composition demonstrates improvements in the softening point of the asphalt composition.

摘要翻译： 提供橡胶改性沥青组合物。 橡胶包括至少一个聚二烯，并且还可以包括乙烯基取代的芳族烃单体贡献单元。 橡胶用双马来酰亚胺固化。 本发明的组合物显示了沥青组合物的软化点的改进。

公开(公告)号：US6162874A

公开(公告)日：2000-12-19

申请号：US935773

申请日：1997-09-23

申请人： Mark H. Wollum ,  Daniel F. Graves

发明人： Mark H. Wollum ,  Daniel F. Graves

IPC分类号： C08F287/00 ,  C08F285/00 ,  C08F297/04 ,  C08L53/02 ,  C08F255/06

CPC分类号： C08F297/04 ,  C08L53/02 ,  C08L2666/04

摘要： A process for interpolymerizing a vinyl aromatic hydrocarbon polymer and a block polymer is disclosed. The process includes the following steps: (a) forming a block polymer precursor of at least one polymeric block containing conjugated diene monomer contributed units in the presence of an anionic initiator and in an inert diluent, the block polymer precursor having living ends; and (b) thereafter adding to the block polymer precursor a charge of a vinyl aromatic hydrocarbon monomer and an additional charge of an anionic initiator to simultaneously form (1) a block polymer having a terminal block formed from the charge of vinyl aromatic hydrocarbon monomer attached to the block polymer precursor and (2) a poly(vinyl aromatic hydrocarbon) polymer interpolymedzed with the block polymer. The practice of this process produces a vinyl aromatic hydrocarbon block terminated block polymer, such as SBS, interpolymerized with a polymer formed from vinyl aromatic hydrocarbon monomer, such as polystyrene. The resultant interpolymer has a high Gardner Impact strength and good processibility.

摘要翻译： 公开了一种使乙烯基芳族烃聚合物和嵌段聚合物共聚的方法。 该方法包括以下步骤：（a）在阴离子引发剂存在下，在惰性稀释剂中形成含有共轭二烯单体的至少一个聚合物嵌段的嵌段聚合物前体，所述嵌段聚合物前体具有活性末端; 和（b）然后向嵌段聚合物前体中加入乙烯基芳族烃单体和另外的阴离子引发剂的电荷，以同时形成（1）具有由连接的乙烯基芳族烃单体的电荷形成的末端嵌段的嵌段聚合物 嵌段聚合物前体和（2）用嵌段聚合物共混的聚（乙烯基芳族烃）聚合物。 该方法的实践产生与由乙烯基芳族烃单体如聚苯乙烯形成的聚合物共聚的乙烯基芳族烃嵌段封端的聚合物，例如SBS。 所得互聚物具有较高的加德纳冲击强度和良好的加工性能。