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公开(公告)号：US07476714B2
公开(公告)日：2009-01-13
申请号：US11132836
申请日：2005-05-19
申请人： Martial Jean-Jacques Pabon , Romain Severac , Emmanuel Abel Jean-Mark Puchois , Matthieu Perdon
发明人： Martial Jean-Jacques Pabon , Romain Severac , Emmanuel Abel Jean-Mark Puchois , Matthieu Perdon
IPC分类号： C08G77/388
CPC分类号： C03C17/30 , C03C2217/75 , C03C2217/76 , C04B41/4961 , C04B2111/203 , C04B2111/27 , C08G77/392 , C08L83/08 , C09D183/08 , D06M15/65 , D06M15/657 , D06M2200/11 , D06M2200/12 , Y10T428/31663 , C04B41/00 , C08L2666/02
摘要： A composition useful to provide oil repellency, water repellency, and stain resistance to substrates comprising a polymer prepared by contacting a polyfluoroalkyl sulfonyl halide with a compound of Formula II, III or IV (E-(O)q)3Si—O—(Si(R2)2—O)m—[Si(R3—NHR4)(R2)O]n—Si—((O)q-E)3 Formula II HR4N—R3—Si(R2)2—O—[Si(R2)2—O]m—[Si(R3—NHR4)(R2)O]n—Si(R2)2—R3—NHR4 Formula III HR4N—R3—Si(R2)2—O—[Si(R2)2—O]m—Si—((O)q-E)3 Formula IV wherein each R2 is independently a C1 to C8 alkyl, each R3 is independently a divalent group containing carbon, oxygen, and optionally at least one of nitrogen oxygen and sulfur, each R4 is independently H or C1 to C8 alkyl, each E is independently a C1 to C8 branched or linear alkyl, each q is independently zero or 1, m is a positive integer, and n is independently zero or a positive integer, such that n/(m+n) is zero or a positive fraction having a value up to about 0.7, and the polymer viscosity is less than or equal to 10000 mPa·s under a shear rate of 0.1 s−1 at a temperature of 20° C.
摘要翻译： 用于提供拒油性，拒水性和对基材的耐污性的组合物，其包含通过使多氟烷基磺酰卤与式II，III或IV的化合物接触而制备的聚合物，其中式“=”在线式 （E（O）q）3 Si-O-（Si（R 2）2 -O）m- [Si（R 3 -NHR 4）（R 2）O] n -Si - （（O ）qE）3公式II <？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> HR4N-R3-Si（R2）2-O- [Si（R2）2-O] m- [Si（R3-NHR4）（R2）O] n-Si（R2）2-R3-NHR4 in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> HR4N-R3-Si（R2） 2-O- [Si（R2）2-O] m-Si - （（O）qE）3式IV <？在线公式描述=“在线公式”end =“tail”？> R2独立地为C1至C8烷基，每个R3独立地为含有碳，氧和任选的氮氧和硫中的至少一个的二价基团，每个R 4独立地为 H或C1至C8烷基，每个E独立地为C1至C8支链或直链烷基，每个q独立地为0或1，m为正整数，n为独立为零或正整数，使得n /（m + n）为零或具有高达约0.7的值的正级分，并且在20℃的温度下，在0.1s -1的剪切速率下聚合物粘度小于或等于10000mPa.s。
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公开(公告)号：US20100168318A1
公开(公告)日：2010-07-01
申请号：US12531757
申请日：2008-03-14
IPC分类号： C08L27/12 , C08F214/18
CPC分类号： C08F214/18 , C08F214/20 , C08F220/24 , C08F220/38
摘要： It has been discovered by in present invention that, compared with a fluorosurfactant having only one betaine group per molecule, a fluorosurfactant having a plurality of betaine groups per molecule is superior in its ability to undergo electrostatic interaction with other components of a fire fighting composition thereby improving the performance of the fire fighting composition. Previously known fluorosurfactants comprise only one betaine group per molecule. In contrast, the present invention provides for a fluorobetaine copolymer containing a plurality of betaine groups.
摘要翻译： 在本发明中已经发现，与每分子仅具有一个甜菜碱基团的含氟表面活性剂相比，每分子具有多个甜菜碱基团的含氟表面活性剂的耐受性与其它消防组合物的其它组分的静电相互作用相比是优异的 提高消防组合的表现。 以前已知的含氟表面活性剂每分子仅包含一个甜菜碱基团。 相反，本发明提供含有多个甜菜碱基团的氟代甜菜碱共聚物。
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公开(公告)号：US20090017321A1
公开(公告)日：2009-01-15
申请号：US11827006
申请日：2007-07-10
CPC分类号： C09D133/18 , C08F220/06 , C08F220/24 , C08F220/34 , D21H17/11 , D21H17/36 , D21H17/37 , D21H21/14 , D21H21/16 , Y10T428/31895 , Y10T442/2279 , Y10T442/2287
摘要： A method of imparting oil repellency to flexible, fibrous, nonwoven substrates comprising contacting the substrate with a composition prepared from polymerization of monomers in the following percentages by weight: (a) from about 60% to about 90% of a monomer of Formula 1 or a mixture thereof: Rf-Q-CO—CR═CH2 Formula 1 wherein: Rf is a straight- or branched-chain perfluoroalkyl group of 2 to about 20 carbon atoms, R is H or CH3, Q is —(CnH2n)pSO2NR1(CnH2nO)y—, wherein the —(CnH2n) is bonded to Rf, and R1 is H or C1-C20 alkyl; (b) from about 10% to about 25% of a monomer of Formula 2 or a mixture thereof: CH2═C(R)COZ(CH2)q(CHR)rNR2R3 Formula 2 wherein R2 and R3 are each independently C1-C4 alkyl, hydroxyethyl, or benzyl or R2 and R3 together with the nitrogen atom form a morpholine, pyrrolidine, or piperidine ring, and Z is —O— or —NR4— wherein R4 is H or C1-C4 alkyl; and (c) from about 1% to about 15% of a monomer of Formula 3 or a mixture thereof: CH2═CR(R5)e—COOH Formula 3 wherein R5 is CO(CH2)5, CO—O—(CH2)2, C6H4CHR, or CONRR6, and R6 is C6H4OCH2, (CH2)d, or C(CH3)2CH2.
摘要翻译： 包括使柔性纤维状非织造基材赋予拒油性的方法，包括使底物与按单体聚合制备的组合物接触，重量百分比如下：（a）约60％至约90％的式1单体或 其混合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> Rf-Q-CO-CR-CH2 Formula 1 <？in-line-formula description =“In-line 式中：R f为2-约20个碳原子的直链或支链全氟烷基，R为H或CH 3，Q为 - （C n H 2n）p SO 2 NR 1（C n H 2n O）y - ，其中 - （C n H 2n）键合到R f，并且R 1是H或C 1 -C 20烷基; （b）约10％至约25％的式2的单体或其混合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> CH2-C（R） COZ（CH2）q（CHR）rNR2R3式2 <？在线公式描述=“在线公式”end =“tail”？>其中R2和R3各自独立地为C1-C4烷基，羟乙基或苄基或 R2和R3与氮原子一起形成吗啉，吡咯烷或哌啶环，Z是-O-或-NR4-，其中R4是H或C1-C4烷基; （c）约1％至约15％的式3的单体或其混合物：<？in-line-formula description =“In-line formula”end =“lead”？> CH2-CR（R5 ）其中R5是CO（CH2）5，CO-O-（CH2）2，C6H4CHR或CONRR6，其中R5是CO- ，R6为C6H4OCH2，（CH2）d或C（CH3）2CH2。
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公开(公告)号：US08071489B2
公开(公告)日：2011-12-06
申请号：US11827006
申请日：2007-07-10
IPC分类号： B32B27/04
CPC分类号： C09D133/18 , C08F220/06 , C08F220/24 , C08F220/34 , D21H17/11 , D21H17/36 , D21H17/37 , D21H21/14 , D21H21/16 , Y10T428/31895 , Y10T442/2279 , Y10T442/2287
摘要： A method of imparting oil repellency to flexible, fibrous, nonwoven substrates comprising contacting the substrate with an amphoteric fluorochemical copolymer composition prepared from polymerization of monomers in the following percentages by weight: (a) from about 60% to about 90% of a fluorinated (meth)acrylate monomer of Formula 1 which is Rf-Q-CO—CR═CH2, (b) from about 10% to about 25% of an amine substituted (meth)acrylate or (meth)acylamide monomer of Formula 2 which is CH2═C(R)COZ(CH2)q(CHR)rNR2R3, and (c) from about 1% to about 15% of a substituted (meth)acrylic acid monomer of Formula 3 which is CH2=CR(R5)e—COOH.
摘要翻译： 将柔性纤维状非织造基材赋予斥油性的方法，包括使基材与由单体聚合制备的两性含氟共聚物组合物接触，所述两性含氟共聚物组合物的重量百分比如下：（a）约60％至约90％的氟化（ 甲基）丙烯酸酯单体，其为Rf-Q-CO-CR = CH 2，（b）约10％至约25％的胺取代的（甲基）丙烯酸酯或式（2）的（甲基） （C）COZ（CH2）q（CHR）rNR2R3和（c）约1％至约15％的CH 2 = CR（R 5）e -COOH的式3的取代的（甲基）丙烯酸单体 。
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公开(公告)号：US08916058B2
公开(公告)日：2014-12-23
申请号：US12531757
申请日：2008-03-14
IPC分类号： A62D1/00 , C08F214/20 , C08F214/18 , C08F220/24 , C08F220/38
CPC分类号： C08F214/18 , C08F214/20 , C08F220/24 , C08F220/38
摘要： It has been discovered by in present invention that, compared with a fluorosurfactant having only one betaine group per molecule, a fluorosurfactant having a plurality of betaine groups per molecule is superior in its ability to undergo electrostatic interaction with other components of a fire fighting composition thereby improving the performance of the fire fighting composition. Previously known fluorosurfactants comprise only one betaine group per molecule. In contrast, the present invention provides for a fluorobetaine copolymer containing a plurality of betaine groups.
摘要翻译： 在本发明中已经发现，与每分子仅具有一个甜菜碱基团的含氟表面活性剂相比，每分子具有多个甜菜碱基团的含氟表面活性剂的耐受性与其它消防组合物的其它组分的静电相互作用相比是优异的 提高消防组合的表现。 以前已知的含氟表面活性剂每分子仅包含一个甜菜碱基团。 相反，本发明提供含有多个甜菜碱基团的氟代甜菜碱共聚物。
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公开(公告)号：US07638589B2
公开(公告)日：2009-12-29
申请号：US11311077
申请日：2005-12-19
IPC分类号： C08G77/08
CPC分类号： C08G77/26 , C08G77/24 , C08G77/388 , Y10T428/31663
摘要： A polymer for imparting repellency and stain resistance to substrates is disclosed of Formula 1: (W)a(R2)bSi(R1)2—O—[Si(R1)2—O]n—[Si(W)c(R1)d(R2)e—O]m—Si(R1)2—(W)f(R2)g 1 wherein: a, b, c, d, e, f and g are each independently 0 or 1, provided that (a+b) is 1, (f+g) is 1, and (c+d+e) is 2, each R1 is a C1 to C8 alkyl, each R2 is independently H or C1 to C8 alkyl, optionally containing oxygen, nitrogen, or sulfur, or a combination thereof, and n=0 to 500, m=1 to 100, each W is independently (Rf—X—A—X)p—Y—X— wherein: Rf is a straight or branched perfluoroalkyl group having from about 2 to about 20 carbon atoms, or a mixture thereof, which is optionally interrupted by at least one oxygen atom, each X is independently an organic divalent linking group having from about 1 to about 20 carbon atoms, optionally containing oxygen, nitrogen, or sulfur, or a combination thereof, A is a 1,2,3-triazole, p=1 to 2, Y is O, N, or NR wherein R is H or C1 to C20 alkyl, optionally containing oxygen, nitrogen, or sulfur, or a combination thereof.
摘要翻译： 式（1）公开了：（W）a（R2）bSi（R1）2-O- [Si（R1）2-O] n- [Si（W）c（R1） ）d（R2）eO] m-Si（R1）2-（W）f（R2）g1其中：a，b，c，d，e，f和g各自独立地为0或1，条件是（a + b）为1，（f + g）为1，（c + d + e）为2，每个R 1为C 1至C 8烷基，每个R 2独立地为H或C 1至C 8烷基，任选地含有氧，氮 ，或硫，或其组合，n = 0〜500，m = 1〜100，各W独立地为（Rf-XAX）pYX-，其中：Rf为直链或支链的全氟烷基，其具有约2至约20 碳原子或其混合物，其任选被至少一个氧原子间隔，每个X独立地为具有约1至约20个碳原子的有机二价连接基团，任选地含有氧，氮或硫，或组合 其中A为1,2,3-三唑，p = 1至2，Y为O，N或NR，其中R为H或C 1至C 20烷基，任选含有氧，硝基 烯或硫，或其组合。
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公开(公告)号：US20130209575A1
公开(公告)日：2013-08-15
申请号：US13585953
申请日：2012-08-15
申请人： MARK WALLACE SQUIRE , Catherine Mary Chaloner , Sharon Elizabeth Hicks , Kelly Ann Board , Martial Jean-Jacques Pabon
发明人： MARK WALLACE SQUIRE , Catherine Mary Chaloner , Sharon Elizabeth Hicks , Kelly Ann Board , Martial Jean-Jacques Pabon
CPC分类号： A01N59/02 , A01N33/12 , A01N41/04 , A01N41/08 , A01N59/00 , C11D1/94 , C11D3/046 , C11D3/28 , C11D3/30 , C11D3/323 , C11D3/349 , C11D3/3942 , C11D3/3945 , C11D3/48 , A01N47/44 , A01N2300/00
摘要： A multi-part kit system comprising (i) a solid part A which comprises 10 to 80 wt. % of peroxy compound selected from the group consisting of KHSO5, K2S2O8, Na2S2O8, magnesium monoperoxyphthalate hexahydrate, sodium percarbonate and sodium perborate, 0.1 to 10 wt. % of LiCl, NaCl and/or KCl and 1 to 20 wt. % of H2N(CH2)nSO3H with n=0, 1, 2 or 3, and (ii) a liquid part B in the form of an aqueous solution which comprises 0 to 20 wt. % of nonionic surfactant, 3.6 to 20 wt. % of amphoteric surfactant and 0.5 to 20 wt. % of at least one compound comprising substituted ammonium selected from the group consisting of dihydrocarbyl dimethylammonium chlorides or bromides, didecyl methyl-poly(oxyethyl)ammonium propionate, chlorhexidine gluconate, cetylpyridinium chloride or bromide, and polyhexamethylene biguanide hydrochloride, wherein at least one of the two hydrocarbyl residues comprises 8 to 18 carbon atoms.
摘要翻译： 一种多部分试剂盒系统，其包含（i）固体部分A，其包含10至80wt。 ％的过氧化合物选自KHSO 5，K 2 S 2 O 8，Na 2 S 2 O 8，单过氧邻苯二甲酸镁六水合物，过碳酸钠和过硼酸钠，0.1至10wt。 ％的LiCl，NaCl和/或KCl和1至20wt。 ％的H 2 N（CH 2）n SO 3 H，n = 0,1,2或3，和（ii）水溶液形式的液体部分B，其包含0-20重量％ ％的非离子表面活性剂，3.6-20wt。 ％的两性表面活性剂和0.5〜20wt。 至少一种至少一种选自二烃基二甲基氯化铵或溴化物的取代铵的化合物，二癸基甲基 - 聚（氧乙基）丙酸铵，氯己定葡萄糖酸盐，十六烷基吡啶鎓氯化物或溴化物，以及聚六亚甲基双胍盐酸盐，其中至少一种 两个烃基残基包含8至18个碳原子。
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