摘要:
A process of making a negative electrode for a storage battery including a positive electrode capable of being reversibly charged and discharged, a nonaqueous electrolyte containing lithium salt, and a negative electrode is provided. The negative electrode is made of an inorganic carbon material which has an improved surface having a specific surface area sufficiently large enough to store the largest possible amount of lithium ions therein to provide the largest possible charge and discharge capacitances for the storage battery. The electrode is made by adding an acid to an inorganic carbon containing material to form a mixture, heating the mixture for at least 10 hours to obtain a carbon material having a specific surface area of more than 8.0 m.sup.2 /g and forming the electrode using the carbon material.
摘要:
An electrode for a non-aqueous electrolyte secondary battery to be embodied in both the anode and cathode. It comprises a mixture including, an active material having reversibility for charging and discharging, and a whisker which is chemically and electrochemically inert. Said active material is a substance capable of reversibly intercalating and deintercalating lithium. Said mixture includes a binding agent and constitutes a solid structural body. Said whisker is at least one selected from the group consisting of silicon carbide whisker, silicon nitride whisker, potassium titanate whisker and aluminum borate whisker.
摘要:
A lithium secondary battery comprising a positive electrode a double oxide of lithium and nickel wherein said double oxide is formed by burning a mixture of a nickel compound such as nickel carbonate, and a lithium compound such as lithium nitrate, at an atomic ratio of Li/Ni of from >1.0 to 1.4, in either air or oxygen, and a method of manufacturing the same.
摘要:
A non-aqueous electrolyte secondary battery comprises rechargeable positive and negative electrodes and a non-aqueous electrolyte. The positive electrode comprises at least one selected from LiCo0.sub.2, LiMn.sub.2 0.sub.4 and LiNi0.sub.2 and the negative electrode consists most of alkai metals such as lithium, etc. The non-aqueous electrolyte contains lithium salts and has concentration ranging from 0.002 to 1.0 mol/liter of at least one acid anhydride selected from acetic anhydride, benzoic anhydride, succinic anhydride, phtalic anhydride and maleic anhydride.
摘要翻译:非水电解质二次电池包括可再充电的正极和负极以及非水电解质。 正极包含选自LiCoO 2,LiMn 2 O 4和LiNiO 2中的至少一种,负极由大部分碱金属如锂等组成。非水电解质含有锂盐,其浓度范围为0.002〜1.0mol / 选自乙酸酐,苯甲酸酐,琥珀酸酐,邻苯二甲酸酐和马来酸酐中的至少一种酸酐。
摘要:
A process for the production of LiNi.sub.1-x Mn.sub.x O.sub.2 (0.005.ltoreq..times..ltoreq.0.45) as a positive electrode active material for a nonaqueous lithium secondary cell comprising a) mixing aqueous solutions of a lithium salt, a nickel salt and manganese nitrate, b) heating with stirring the solution to dryness and c) pre-calcining from 250.degree. C. to 400.degree. C., grinding and mixing the product and finally calcining from 600.degree. C. to 900.degree. C.
摘要:
There is provided a secondary battery comprising a positive and a negative electrode and a nonaqueous electrolyte. The positive electrode is made by dipping an electrode comprising a positive active material such as LiMn.sub.2 O.sub.4, LiMnO.sub.2, LiCoO.sub.2, LiNiO.sub.2, LiFeO.sub.2 or .gamma.LiV.sub.2 O.sub.5, in a solution containing butyllithium, phenyllithium, or naphthyllithium. The negative electrode of the battery absorbs and desorbs lithium by charging and discharging, and the nonaqueous electrolyte contains a lithium salt. Also provided is a method of manufacturing a secondary battery comprising a nonaqueous electrolyte. The method comprises the steps of preparing an electrode group containing a positive electrode of LiMn.sub.2 O.sub.4, LiMnO.sub.2, LiCoO.sub.2, LiNiO.sub.2, LiFeO.sub.2 or .gamma.-LiV.sub.2 O.sub.5, as the active material, and a negative electrode which absorbs and desorbs lithium by charging and discharging, with a separator therebetween. The group is placed in a battery case, and to the case is added a solution containing butyllithium etc. The solution is removed and an organic electrolyte as a nonaqueous electrolyte is added to the battery case.
摘要翻译:提供一种包含正极和负极和非水电解质的二次电池。 正极通过在包含丁基锂,苯基锂或萘基锂的溶液中浸渍包含LiMn 2 O 4,LiMnO 2,LiCoO 2,LiNiO 2,LiFeO 2或γLiV 2 O 5等正极活性物质的电极。 电池的负极通过充放电吸收和解吸锂,非水电解质含有锂盐。 还提供了一种制造包含非水电解质的二次电池的方法。 该方法包括以下步骤:制备含有LiMn 2 O 4,LiMnO 2,LiCoO 2,LiNiO 2,LiFeO 2或γ-LiV 2 O 5的正极作为活性材料的电极组,以及通过充电和放电吸收和解吸锂的负极, 分离器之间。 将该组放置在电池壳体中,并且向壳体中加入含有丁基锂等的溶液。除去溶液,并将电解质的有机电解质添加到电池壳体中。
摘要:
A positive electrode for a non-aqueous electrolyte lithium secondary battery comprises an active material represented by the formula Li.sub.x A.sub.1-y M.sub.y O.sub.2 (wherein A represents at least one transition element selected from the group consisting of Mn, Co, and Ni, M represents at least one element selected from the group consisting of B, Mg, Ca, Sr, Ba, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, In, Nb, Mo, W, Y, and Rh, and wherein 0.05.ltoreq.x.ltoreq.1.1, and 0.ltoreq.y.ltoreq.0.5), a binder, a conductive agent and a current collector. The binder is selected from the group consisting of a copolymer comprising a tetrafluoroethylene unit and a hexafluoropropylene unit, a copolymer comprising a vinylidene fluoride unit, a copolymer comprising a propylene unit and a tetrafluoroethylene unit, and a polymer comprising a trifluoropropylmethylsiloxane unit.
摘要:
A non-aqueous electrolyte secondary battery having a low manufacturing cost and a high energy density and being excellent in the high rate charge/discharge characteristic and in the characteristics in operation at high temperature provided by an improvement on its positive electrode active material is disclosed. The positive electrode active material comprises a specific compound wherein a part of nickel or lithium in LiNiO.sub.2 is substituted with another element in a specified range. The element for the substitution comprises Mg, Ca, Sr, Ba, Al Cr, B and Co which may be employed solely or in combination.
摘要:
A non-aqueous electrolyte secondary battery is disclosed which has an anode comprising a carbon material. The carbon material contains at least one of 7-35 wt % sulfur, 6.5-25 wt % oxygen and 10.5-18.3 wt % nitrogen, provided that if the carbon material contains at least two of these elements, the total amount of the elements does not exceed 35 wt %.
摘要:
A cathode active material for a nonaqueous electrolyte secondary battery is provided. The cathode active material is a composite oxide with a spinel-type structure represented by the general formula Li.sub.2-x �Mn.sub.2-y Li.sub.y !O.sub.4, wherein -0.1.ltoreq.x
摘要翻译:提供一种非水电解质二次电池用正极活性物质。 正极活性物质是具有由通式Li 2-x [Mn 2-y Li y] O 4表示的尖晶石型结构的复合氧化物,其中-0.1≤x≤1.0且0.3≤y≤0.35,其中 通式中的[Mn2-yLiy]位于由立方密堆积氧离子配位的八面体位置。