公开(公告)号：US20080217184A1

公开(公告)日：2008-09-11

申请号：US11665976

申请日：2005-10-26

申请人： Masahiko Hori ,  Tadashi Ogasawara ,  Makoto Yamaguchi ,  Toru Uenishi ,  Masanori Yamaguchi ,  Yuichi Ono ,  Susumu Kosemura ,  Eiji Nishimura

发明人： Masahiko Hori ,  Tadashi Ogasawara ,  Makoto Yamaguchi ,  Toru Uenishi ,  Masanori Yamaguchi ,  Yuichi Ono ,  Susumu Kosemura ,  Eiji Nishimura

IPC分类号： C25C3/28

CPC分类号： C25C3/02 ,  C22B34/1268 ,  C22B34/1272 ,  C22B34/129 ,  C25C3/28 ,  C25C7/007

摘要： An apparatus for producing Ti by Ca reduction by the invention includes a reaction tank retaining a molten salt in which a molten salt CaCl2 is contained and Ca is dissolved, an electrolytic cell retaining a molten salt containing CaCl2, and a continuum body which is movably constructed while part of the continuum body is immersed in the molten salt either within the reaction tank or electrolytic cell. In the inventive method for producing Ti by Ca reduction, the molten salt in the electrolytic cell is electrolyzed to generate Ca on the cathode side which is transported to the reaction tank while deposited on and adheres to the continuum body, and TiCl4 is supplied to the reaction tank to generate Ti. The invention enables a feed rate of TiC14 as a raw material to be enhanced, and continuous production to be performed, while allowing Ca consumed in the TiCl4 reduction reaction to be replenished by electrolysis of CaCl2, which proves to have an economical advantage, thus becoming means for efficiently and economically producing high-purity metallic Ti to widely be applied.

摘要翻译： 通过本发明的通过Ca还原生产Ti的装置包括：保持熔融盐，其中包含熔融盐CaCl 2并溶解Ca的反应罐;保留含有CaCl 2的熔融盐的电解槽， 以及连续体，其在连续体的一部分浸入反应槽或电解槽内的熔融盐中时可移动地构造。 在通过Ca还原生产Ti的本发明方法中，电解池中的熔融盐被电解以在阴极侧产生Ca，同时沉积并附着在连续体上，并将TiCl 4 供应到反应罐中以产生Ti。 本发明能够使TiCl 4原料的进料速度提高，同时使TiCl 4还原反应中消耗的Ca为 通过电解CaCl 2补充，这被证明具有经济优势，因此成为有效和经济地生产广泛应用的高纯度金属Ti的手段。

公开(公告)号：US20080078679A1

公开(公告)日：2008-04-03

申请号：US11576887

申请日：2005-10-05

申请人： Masanori Yamaguchi ,  Yuichi Ono ,  Susumu Kosemura ,  Eiji Nishimura ,  Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi

发明人： Masanori Yamaguchi ,  Yuichi Ono ,  Susumu Kosemura ,  Eiji Nishimura ,  Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi

IPC分类号： C25C3/02 ,  C25C3/28 ,  C25C7/00

CPC分类号： C22B34/129 ,  C25C3/02 ,  C25C3/28 ,  C25C7/025

摘要： A method for production of metal by molten-salt electrolysis of the present invention is a method for production of metal by molten-salt electrolysis which is performed by filling a molten salt of calcium chloride in an electrolysis vessel having a anode and a cathode, one of the anode or cathode is arranged surrounding the other electrode, the cathode has at least one hole communicating the inner area surrounded by the cathode with the outer area, and the molten salt flows through the communicating holes from one area including the anode (the inner area or outer area) to the other area.

摘要翻译： 本发明的通过熔盐电解生产金属的方法是通过熔融盐电解生产金属的方法，其通过在具有阳极和阴极的电解容器中填充氯化钙的熔融盐，一种 阳极或阴极被布置为围绕另一电极，阴极具有至少一个孔，其将由阴极包围的内部区域与外部区域连通，并且熔融盐从包括阳极的一个区域（内部）流过连通孔 区域或外部区域）到另一个区域。

公开(公告)号：US20080053838A1

公开(公告)日：2008-03-06

申请号：US11576891

申请日：2005-10-05

申请人： Masanori Yamaguchi ,  Yuichi Ono ,  Susumu Kosemura ,  Eiji Nishimura ,  Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi

发明人： Masanori Yamaguchi ,  Yuichi Ono ,  Susumu Kosemura ,  Eiji Nishimura ,  Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi

IPC分类号： C25C3/28

CPC分类号： C25C3/02 ,  C22B34/129 ,  C25B1/26 ,  C25C3/28

摘要： A method for production of metal by molten-salt electrolysis is a method for production of metal by molten-salt electrolysis which is performed by filling molten salt of a metal chloride in an electrolysis vessel having an anode and a cathode, and a molten salt which reduces solubility of the metal in the molten salt is used.

摘要翻译： 通过熔盐电解生产金属的方法是通过熔盐电解生产金属的方法，其通过在具有阳极和阴极的电解容器中填充金属氯化物的熔融盐和熔融盐来进行， 使用熔融盐中金属的溶解度降低。

公开(公告)号：US07648560B2

公开(公告)日：2010-01-19

申请号：US10575225

申请日：2004-10-06

申请人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Katsunori Dakeshita

发明人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Katsunori Dakeshita

IPC分类号： C22B34/12 ,  C25C1/02

CPC分类号： C25C3/02 ,  C22B34/1268 ,  C22B34/1272 ,  C22B34/1295

摘要： The present invention is a method for producing Ti or a Ti alloy through reduction of TiCl4 by Ca, which can produce the high-purity metallic Ti or high-purity Ti alloy. A molten salt containing CaCl2 and having Ca dissolved therein is held in a reactor vessel, and a metallic chloride containing TiCl4 is reacted with Ca in the molten salt to generate Ti particles or Ti alloy particles in a molten CaCl2 solution, which allows enhancement of a feed rate of TiCl4 which is of a raw material of Ti, and also allows a continuous operation. Therefore, the high-purity metallic Ti or the high-purity Ti alloy can economically be produced with high efficiency. Further, the method by the present invention eliminates the need of replenishment of expensive metallic Ca and of the operation for separately handling Ca which is highly reactive and difficult to handle.

摘要翻译： 本发明是通过还原TiCl 4来生产Ti或Ti合金的方法，其可以生产高纯度金属Ti或高纯Ti合金。 将含有CaCl 2并将Ca溶解在其中的熔融盐保持在反应容器中，含有TiCl 4的金属氯化物与熔融盐中的Ca反应，生成熔融CaCl 2溶液中的Ti粒子或Ti合金粒子， 作为原料Ti的TiCl4的进料速度，并且还允许连续操作。 因此，可以高效率地经济地制造高纯度金属Ti或高纯Ti合金。 此外，本发明的方法消除了对昂贵的金属Ca的补充的需要和用于单独处理高反应性和难以处理的Ca的操作。

公开(公告)号：US20070187255A1

公开(公告)日：2007-08-16

申请号：US10589879

申请日：2005-02-16

申请人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Katsunori Dakeshita

发明人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Katsunori Dakeshita

IPC分类号： C25C3/28

CPC分类号： C22B34/1272 ,  C22B34/129 ,  C25C5/04

摘要： The invention is a method for producing Ti or Ti alloys through reduction of TiCl4 by Ca, which can produce high-purity Ti metals or Ti alloys. A molten salt containing CaCl2 and having Ca dissolved therein is held in a reactor cell, electrolysis is performed in the molten salt in the reactor cell, and particulate Ti or Ti alloys are generated in the molten salt by supplying a metallic chloride containing TiCl4 to the molten salt so as to react with Ca generated on a cathode electrode side by the electrolysis, allowing enhancement of a feed rate of TiCl4 as a raw material of Ti, and also a continuous operation. Further, the method by the invention eliminates the need of the separate handling of Ca, because a reducing reaction and an electrolytic reaction can simultaneously proceed in the reactor cell to replenish Ca, consumed in the reducing reaction, by the electrolytic reaction. Accordingly, the production method by the invention can be used as means for efficiently and economically producing high-purity Ti metals or Ti alloys.

摘要翻译： 本发明是通过Ca还原TiCl 4制备Ti或Ti合金的方法，其可以生产高纯Ti金属或Ti合金。 将含有CaCl 2 Ca的Ca盐溶解在其中的熔融盐保持在反应器电池中，在反应器电池中的熔融盐中进行电解，并且在熔融盐中产生颗粒状的Ti或Ti合金， 将含有TiCl 4的金属氯化物供给熔融盐，以便通过电解与在阴极电极侧产生的Ca反应，从而提高TiCl 4的进料速率， 作为Ti的原料，也是连续操作。 此外，本发明的方法消除了对Ca的单独处理的需要，因为还原反应和电解反应可以在反应器电池中同时进行以补充通过电解反应在还原反应中消耗的Ca。 因此，本发明的制造方法可以用作高效且经济地制造高纯度Ti金属或Ti合金的手段。

公开(公告)号：US20070131057A1

公开(公告)日：2007-06-14

申请号：US10575224

申请日：2004-10-06

申请人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Yuko Urasaki ,  Kazuo Takemura

发明人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Yuko Urasaki ,  Kazuo Takemura

IPC分类号： B22F9/24

CPC分类号： C25C3/28 ,  C22B34/1272 ,  C22B34/1295 ,  C25C3/02

摘要： A method for producing Ti or Ti alloys through reduction by Ca, including: a reduction step of holding a molten salt, containing CaCl2 and having Ca dissolved therein, in a reactor vessel 1, and reacting a metallic chloride containing TiCl4 with Ca in said salt to generate particles of Ti or Ti alloys in said salt; and a separation step of separating particles of Ti or Ti alloys, generated in said salt, from said salt. An electrolysis step 8, in which CaCl2 discharged outside the reactor vessel 1 is electrolyzed into Ca and Cl2, and the generated Ca is used for the generation reaction of Ti or Ti alloys in the reactor vessel 1, is preferably added. In the electrolysis step 8, an alloy electrode made of a molten Ca alloy, if applied for a cathode, is effective in enhancing the electricity efficiency, and also can be effectively utilized as a carrier medium of Ca for raising a Ca concentration of molten salt. By this method, high-purity Ti metals can be efficiently and economically produced.

摘要翻译： 一种通过Ca还原制造Ti或Ti合金的方法，包括：将含有CaCl 2·Ca和Ca的溶解在其中的熔融盐保持在反应容器1中的还原步骤，并使金属 在所述盐中含有TiCl 4 Si与Ca的氯化物，以在所述盐中产生Ti或Ti合金颗粒; 以及分离步骤，从所述盐分离在所述盐中产生的Ti或Ti合金的颗粒。 电解步骤8，其中排放到反应容器1外部的CaCl 2电解为Ca和Cl 2，并且所产生的Ca用于Ti或 优选添加反应器容器1中的Ti合金。 在电解工序8中，如果用于阴极，则由熔融的Ca合金构成的合金电极，对于提高电效率是有效的，也可以有效地利用Ca作为提高熔融盐的Ca浓度的载体介质 。 通过这种方法，可以高效且经济地生产高纯度Ti金属。

公开(公告)号：US20100089204A1

公开(公告)日：2010-04-15

申请号：US11992162

申请日：2006-08-22

申请人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Toru Uenishi ,  Masahiko Hori ,  Kazuo Takemura ,  Katsunori Dakeshita

发明人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Toru Uenishi ,  Masahiko Hori ,  Kazuo Takemura ,  Katsunori Dakeshita

IPC分类号： C22B34/12

CPC分类号： C25C3/28 ,  C22B34/1272 ,  C22B34/129 ,  C22B34/1295 ,  C25C3/02 ,  C25C7/005 ,  C25C7/06

摘要： A process for producing Ti, comprising a reduction step of reacting TiCl4 with Ca in a CaCl2-containing molten salt having the Ca dissolved therein to thereby form Ti particles, a separation step of separating the Ti particles formed in said molten salt from said molten salt and an electrolysis step of electrolyzing the molten salt so as to increase the Ca concentration, wherein the molten salt increased in Ca concentration in the electrolysis step is introduced into a regulating cell to thereby render the Ca concentration of the molten salt constant and thereafter the molten salt is used for the reduction of TiCl4 in the reduction step. In the present invention, the Ca concentration of the molten salt to be fed to the corresponding reduction vessel can be inhibited from fluctuating and, at the same time, can maintain high concentration levels. Further, a large volume of the molten salt can be treated continuously. Therefore, the reduction reaction of TiCl4 can be efficiently performed, and the process can be effectively utilized in the production of Ti by Ca reduction as a production process for realizing Ti production on an industrial scale.

摘要翻译： 一种制备Ti的方法，包括在溶解有Ca的含CaCl 2的熔融盐中使TiCl4与Ca反应从而形成Ti颗粒的还原步骤，将在所述熔融盐中形成的Ti颗粒与所述熔融盐分离的分离步骤 以及电解电解步骤，电解所述熔融盐以增加所述Ca浓度，其中将所述电解步骤中的Ca浓度升高的所述熔融盐引入调节池中，从而使所述熔融盐的Ca浓度恒定， 盐在还原步骤中用于还原TiCl4。 在本发明中，可以抑制供给到相应的还原容器的熔融盐的Ca浓度的波动，同时可以保持高浓度水平。 此外，可以连续地处理大量的熔融盐。 因此，可以有效地进行TiCl 4的还原反应，并且通过Ca还原可以有效地利用Ti的制造，作为实现工业规模的Ti生产的制造方法。

公开(公告)号：US20070295167A1

公开(公告)日：2007-12-27

申请号：US10590863

申请日：2004-10-13

申请人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Kazuo Takemura

发明人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Kazuo Takemura

IPC分类号： C22B34/12 ,  C25C3/28

CPC分类号： C22B34/1272 ,  C22B5/04 ,  C22B34/129 ,  C22B34/1295 ,  Y02P10/212

摘要： A mixed molten salt containing CaCl2 and NaCl is held in the reactor cell 1 at a temperature not more than 600° C. TiCl4 which is of a Ti raw material is introduced into the reactor cell 1 while Na is introduced into the reactor cell 1. Na introduced into the reactor cell 1 is replaced by Ca, Ca is dissolved in the molten salt, Ca reduces TiCl4 introduced into the reactor cell 1, and thereby Ti particles are generated. The generated Ti particles are introduced to a separation cell 2 along with the molten salt, and the Ti particles and Na are separated from the molten salt. The residual molten salt is introduced to an electrolytic cell 3 to generate Na by high-temperature electrolysis at the temperature more than 600° C. The generated Na is returned to the reactor cell 1 to replenish Na consumed in the reactor cell 1. The highly reactive Ca is not directly handled, and Na which is easy to handle is used in a circulating manner. Therefore, the Ti or Ti alloy can economically be produced by Ca reduction.

摘要翻译： 将含有CaCl 2 N 2和NaCl的混合熔融盐在不高于600℃的温度下保持在反应器电池1中。Ti原料的TiCl 4为 引入反应器电池1中，同时将Na引入反应器电池1中。 引入反应器电池1的Na被Ca替代，Ca溶解在熔融盐中，Ca使引入反应器电池1的TiCl 4导致，从而产生Ti颗粒。 所产生的Ti颗粒与熔融盐一起被引入分离池2中，并将Ti颗粒和Na与熔融盐分离。 将残留的熔融盐引入电解槽3中，通过在600℃以上的高温下进行高温电解而生成Na。将所生成的Na返回到反应器电池1，补充反应器电池1中消耗的Na。 高反应性Ca不能直接处理，易于处理的Na以循环方式使用。 因此，Ti或Ti合金可经济地通过Ca还原产生。

公开(公告)号：US20060219053A1

公开(公告)日：2006-10-05

申请号：US10569602

申请日：2004-07-14

申请人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi

发明人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi

IPC分类号： C22B34/00 ,  C22B34/12

CPC分类号： C25C3/02 ,  C22B5/04 ,  C22B34/1268 ,  C22B34/129 ,  C25B1/26

摘要： The present invention relates to a method for producing a metal by a direct oxide reduction process with Ca. A CaCl2-based molten salt containing Ca is held in a reduction chamber 1, a metal oxide is introduced into the molten salt in the reduction chamber 1, and the metal oxide is reduced with the Ca in the molten salt to form said metal. The metal formed in the molten salt is separated from the molten salt in a separation means 2, and the molten salt deprived of the metal is introduced into a chlorination chamber 7 and subjected to chlorination treatment with chlorine gas to eliminate the byproduct CaO in the molten salt. The molten salt after chlorination treatment is introduced into an electrolysis chamber 8 and electrolyzed for the formation of Ca and chlorine from CaCl2, and the thus-formed Ca or Ca-containing molten salt is transferred from the electrolysis chamber 8 to the reduction chamber 1. The chlorine obtained in the electrolysis chamber 8 is used in the chlorination chamber 7. Thus, the present invention provides a metal production method and an apparatus wherein high levels of productivity are obtained and the product metal can be inhibited from carbon contamination due to CaO, without any generation of CO2 from the production process, while their being based on the direct oxide reduction process comprising the step of reducing a metal oxide with Ca.

摘要翻译： 本发明涉及通过直接氧化还原法制备金属的方法。 含有CaCl 2的基于Ca的熔融盐保持在还原室1中，金属氧化物被引入到还原室1中的熔融盐中，并且金属氧化物与Ca中的Ca还原 熔融盐形成所述金属。 在熔融盐中形成的金属与分离装置2中的熔融盐分离，将不含金属的熔融盐引入氯化室7中，并用氯气进行氯化处理，以消除熔融的 盐。 将氯化处理后的熔融盐引入电解室8中，电解，从CaCl 2 2形成Ca和氯，将由此形成的含Ca或Ca的熔融盐从电解 室8到还原室1。 在氯化室7中使用电解室8中得到的氯。 因此，本发明提供了一种金属制造方法和装置，其中获得了高水平的生产率，并且可以抑制产品金属由于CaO而导致的碳污染，而不会从生产中产生CO 2 而它们基于直接氧化还原方法，包括用Ca.还原金属氧化物的步骤。

公开(公告)号：US20070193411A1

公开(公告)日：2007-08-23

申请号：US10575225

申请日：2004-10-06

申请人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Katsunori Dakeshita

发明人： Tadashi Ogasawara ,  Makoto Yamaguchi ,  Masahiko Hori ,  Toru Uenishi ,  Katsunori Dakeshita

IPC分类号： B22F9/20

CPC分类号： C25C3/02 ,  C22B34/1268 ,  C22B34/1272 ,  C22B34/1295

摘要： The present invention is a method for producing Ti or a Ti alloy through reduction of TiCl4 by Ca, which can produce the high-purity metallic Ti or high-purity Ti alloy. A molten salt containing CaCl2 and having Ca dissolved therein is held in a reactor vessel, and a metallic chloride containing TiCl4 is reacted with Ca in the molten salt to generate Ti particles or Ti alloy particles in a molten CaCl2 solution, which allows enhancement of a feed rate of TiCl4 which is of a raw material of Ti, and also allows a continuous operation. Therefore, the high-purity metallic Ti or the high-purity Ti alloy can economically be produced with high efficiency. Further, the method by the present invention eliminates the need of replenishment of expensive metallic Ca and of the operation for separately handling Ca which is highly reactive and difficult to handle.

摘要翻译： 本发明是通过Ca还原TiCl 4或Ti合金的方法，其可以生产高纯度金属Ti或高纯Ti合金。 将含有CaCl 2 Ca的Ca盐溶解在其中的熔盐保存在反应器容器中，含有TiCl 4的金属氯化物与熔融盐中的Ca反应生成Ti 颗粒或Ti合金颗粒在熔融的CaCl 2溶液中，这样可以提高Ti原料Ti的进料速率，并且还允许连续的 操作。 因此，可以高效率地经济地制造高纯度金属Ti或高纯Ti合金。 此外，本发明的方法消除了对昂贵的金属Ca的补充的需要和用于单独处理高反应性和难以处理的Ca的操作。