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1.发明授权公开(公告)号：US08501888B2
公开(公告)日：2013-08-06
申请号：US12677187
申请日：2008-07-16
申请人： Satoshi Kurihara , Seiichiro Murata , Katsuyuki Sato , Masayosi Horiuti , Sumiko Mouri , Hideki Abe , Ji-Shan Jin
发明人： Satoshi Kurihara , Seiichiro Murata , Katsuyuki Sato , Masayosi Horiuti , Sumiko Mouri , Hideki Abe , Ji-Shan Jin
IPC分类号： C08F18/20
CPC分类号： C09K3/18 , C08F220/18 , C08F220/24 , C08F220/26
摘要： A fluorine-containing polymer comprising a fluoroalkyl alcohol (meth)acrylic acid derivative represented by a general formula, CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR═CH2 (in the formula, R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, preferably 2 to 4, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3) containing in 5 to 100 wt % as a polymerization unit. A organic solvent solution or aqueous dispersion of the fluorine-containing polymer is effectively used as, for example, a surface-modifying agent such as a water- and oil-repellent or an oil barrier.
摘要翻译： 包含由通式CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cOCOCR = CH2表示的氟烷基醇（甲基）丙烯酸衍生物的含氟聚合物（式中，R为氢原子或 甲基，n为1〜6的整数，优选为2〜4，a为1〜4的整数，b为0〜3的整数，c为1〜3的整数），以5〜100 wt％作为聚合单元。 含氟聚合物的有机溶剂溶液或水分散体有效地用作例如防水防油剂或油屏障的表面改性剂。
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2.发明申请Polyfluoroalkyl Alcohol, Or (METH)Acrylic Acid Derivative Thereof, And Process For Producing The Same 有权多氟烷基醇或（甲基）丙烯酸衍生物及其制备方法公开(公告)号：US20090036706A1
公开(公告)日：2009-02-05
申请号：US12224969
申请日：2007-03-09
CPC分类号： C07C31/38 , C07C17/275 , C07C19/16 , C07C29/09 , C07C29/124 , C07C67/08 , C07C69/653
摘要： A polyfluoroalkyl alcohol, or a (meth)acrylic acid derivative thereof, represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOR (R:H or (meth)acrylic acid group; n: 1-6; a: 1-4; b: 1-3; and c: 1-3). Polyfluoroalkyl alcohol (R: hydrogen atom) can be produced by reaction of fluoroalkyl iodide represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI with N-methyl formamide, followed by hydrolysis in the presence of an acid catalyst, whereas polyfluoroalkyl alcohol (meth)acrylic acid derivative (R: (meth)acrylic acid group) can be produced by reaction of the polyfluoroalkyl alcohol with (meth)acrylic acid.
摘要翻译： 一种多氟烷基醇或其（甲基）丙烯酸衍生物，由以下通式表示：<？in-line-formula description =“In-line formula”end =“lead”>> CnF2n + 1（CH2CF2）a （CF 2 CF 2）b（CH 2 CH 2）cOR <αin-line-formula description =“In-line Formulas”end =“tail”？>（R：H或（甲基）丙烯酸基团; n：1-6; a： 1-4; b：1-3;和c：1-3）。 多氟烷基醇（R：氢原子）可以通过以下通式表示的氟代烷基碘的反应来制备：<？in-line-formula description =“In-Line Formulas”end =“lead”？> CnF2n + 1（CH2CF2 ）a（CF 2 CF 2）b（CH 2 CH 2）cI <βin-line-formula description =“In-line Formulas”end =“tail”→与N-甲基甲酰胺，然后在酸催化剂存在下水解，而 多氟烷基醇（甲基）丙烯酸衍生物（R：（甲基）丙烯酸基））可以通过多氟烷基醇与（甲基）丙烯酸的反应来制备。
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公开(公告)号：US20100261869A1
公开(公告)日：2010-10-14
申请号：US12677579
申请日：2008-08-29
IPC分类号： C08G61/12
CPC分类号： C08F114/18 , C07C17/278 , C07C19/16 , C08F14/18 , C08F214/18 , C08F2/00
摘要： Provided is a terminally iodized polyfluoroalkane represented by the general formula: CnF2n+1(CHXCFY)s+p(CF2CF2)t+rI [I] (in the formula, X and Y are each a hydrogen atom or a fluorine atom, wherein when Y is a fluorine atom, X is also a fluorine atom; n is an integer of 1 to 6; s+p is an integer of 1 to 5 and denotes the number of CHXCFY group; and t+r is 0 or an integer of 1 to 6 and denotes the number of tetrafluoroethylene skeleton). The terminally iodized polyfluoroalkane is produced by telomerizing a fluorine-containing olefin CHX═CFY and tetrafluoroethylene, successively, to CnF2n+1I in the presence of a peroxide initiator.
摘要翻译： 提供由以下通式表示的末端碘化多氟烷烃：CnF2n + 1（CHXCFY）s + p（CF2CF2）t + rI [I]（在该式中，X和Y各自为氢原子或氟原子，其中当 Y为氟原子，X为氟原子，n为1〜6的整数，s + p为1〜5的整数，表示CHXCFY基的数，t + r为0或整数 1〜6，表示四氟乙烯骨架的数量）。 末端碘化的多氟烷烃是通过在含有过氧化物引发剂的存在下将含氟烯烃CHX = CFY和四氟乙烯连续地调节至C n F 2n + 1 I来制备的。
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公开(公告)号：US08278361B2
公开(公告)日：2012-10-02
申请号：US12863464
申请日：2009-01-20
CPC分类号： C07C33/423 , C07C29/09
摘要： Disclosed is a mixture of fluoroalkyl alcohols represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)cOH [Ia] and CF3(CF2)n-1(CF═CH)aCF2(CF2CF2)b(CH2CH2)cOH [Ib], wherein n is an integer of 1 to 5, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3. This fluoroalkyl alcohol mixture is produced by the reaction of a fluoroalkyl iodide represented by the general formula: CF3(CF2)n(CH2CF2)a(CF2CF2)b(CH2CH2)cI [II], with N-methylformamide, followed by hydrolysis in the presence of a basic compound.
摘要翻译： 公开了由以下通式表示的氟烷基醇的混合物：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）cOH [Ia]和CF 3（CF 2）n-1（CF = CH）aCF 2 CF 2 CF 2）b（CH 2 CH 2）c OH [Ib]，其中n为1〜5的整数，a为1〜4的整数，b为0〜3的整数，c为1〜3的整数。 氟烷基醇混合物通过由通式CF 3（CF 2）n（CH 2 CF 2）a（CF 2 CF 2）b（CH 2 CH 2）c I [II]表示的氟代烷基碘与N-甲基甲酰胺反应制备，然后在存在下水解 的基本化合物。
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5.发明授权Polyfluoroalkyl alcohol, or (METH)acrylic acid derivative thereof, and process for producing the same 有权多氟烷基醇或其（METH）丙烯酸衍生物及其制造方法公开(公告)号：US07566801B2
公开(公告)日：2009-07-28
申请号：US12224969
申请日：2007-03-09
IPC分类号： C07C67/36
CPC分类号： C07C31/38 , C07C17/275 , C07C19/16 , C07C29/09 , C07C29/124 , C07C67/08 , C07C69/653
摘要： A polyfluoroalkyl alcohol, or a (meth)acrylic acid derivative thereof, represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOR (R:H or (meth)acrylic acid group; n: 1-6; a: 1-4; b: 1-3; and c: 1-3). Polyfluoroalkyl alcohol (R: hydrogen atom) can be produced by reaction of fluoroalkyl iodide represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI with N-methyl formamide, followed by hydrolysis in the presence of an acid catalyst, whereas polyfluoroalkyl alcohol (meth)acrylic acid derivative (R: (meth)acrylic acid group) can be produced by reaction of the polyfluoroalkyl alcohol with (meth)acrylic acid.
摘要翻译： 一种多氟烷基醇或其（甲基）丙烯酸衍生物，由以下通式表示：<？in-line-formula description =“In-line formula”end =“lead”>> CnF2n + 1（CH2CF2）a （CF 2 CF 2）b（CH 2 CH 2）cOR <αin-line-formula description =“In-line Formulas”end =“tail”？>（R：H或（甲基）丙烯酸基团; n：1-6; a： 1-4; b：1-3;和c：1-3）。 多氟烷基醇（R：氢原子）可以通过以下通式表示的氟代烷基碘的反应来制备：<？in-line-formula description =“In-line formula”end =“lead”>> CnF2n + 1（CH2CF2 ）a（CF 2 CF 2）b（CH 2 CH 2）cI <βin-line-formula description =“In-line Formulas”end =“tail”→与N-甲基甲酰胺，然后在酸催化剂存在下水解，而 多氟烷基醇（甲基）丙烯酸衍生物（R：（甲基）丙烯酸基））可以通过多氟烷基醇与（甲基）丙烯酸的反应来制备。
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6.发明申请FLUORINE-CONTAINING POLYMER AND SURFACE-MODIFYING AGENT CONTAINING THE SAME AS ACTIVE INGREDIENT 有权含有含氟聚合物和表面改性剂，其含有活性成分公开(公告)号：US20110009555A1
公开(公告)日：2011-01-13
申请号：US12677187
申请日：2008-07-16
申请人： Satoshi Kurihara , Seiichiro Murata , Katsuyuki Sato , Masayosi Horiuti , Sumiko Mouri , Hideki Abe , Ji-Shan Jin
发明人： Satoshi Kurihara , Seiichiro Murata , Katsuyuki Sato , Masayosi Horiuti , Sumiko Mouri , Hideki Abe , Ji-Shan Jin
IPC分类号： C08L27/12 , C08F114/18 , C08F214/18
CPC分类号： C09K3/18 , C08F220/18 , C08F220/24 , C08F220/26
摘要： A fluorine-containing polymer comprising a fluoroalkyl alcohol (meth)acrylic acid derivative represented by a general formula, CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR═CH2 (in the formula, R is a hydrogen atom or a methyl group, n is an integer of 1 to 6, preferably 2 to 4, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3) containing in 5 to 100 wt % as a polymerization unit. A organic solvent solution or aqueous dispersion of the fluorine-containing polymer is effectively used as, for example, a surface-modifying agent such as a water- and oil-repellent or an oil barrier.
摘要翻译： 包含由通式CnF2n + 1（CH2CF2）a（CF2CF2）b（CH2CH2）cOCOCR=CH2表示的氟烷基醇（甲基）丙烯酸衍生物的含氟聚合物（式中，R为氢原子或 甲基，n为1〜6的整数，优选为2〜4，a为1〜4的整数，b为0〜3的整数，c为1〜3的整数），以5〜100 wt％作为聚合单元。 含氟聚合物的有机溶剂溶液或水分散体有效地用作例如防水防油剂或油屏障的表面改性剂。
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7.发明申请Terminally Iodized Polyfluoroalkane Oligomer and Process for Producing the Same 审中-公开末端碘化多氟烷烃低聚物及其制备方法公开(公告)号：US20090018294A1
公开(公告)日：2009-01-15
申请号：US12224469
申请日：2007-02-28
申请人： Masayosi Horiuti , Seiichiro Murata , Katsuyuki Sato , Hideki Abe
发明人： Masayosi Horiuti , Seiichiro Murata , Katsuyuki Sato , Hideki Abe
CPC分类号： C07C19/16 , C07C17/278
摘要： A terminally iodized polyfluoroalkane oligomer represented by the following general formula: CnF2n+1(CH2CF2)s+p(CF2CF2)t+rI [I] (wherein n is an integer of 1 to 6, s+p is an integer of 1 to 4, showing the number of vinylidene fluoride skeleton, and t+r is an integer of 1 to 6, showing the number of tetrafluoroethylene skeleton, the adjacent group to the CnF2n+1 group being the CH2CF2 group) can be produced by reaction of a terminally iodized polyfluoroalkane, represented by the following general formula: CnF2n+1(CH2CF2)s+p(CF2CF2)tI with tetrafluoroethylene in the presence of a peroxide initiator.
摘要翻译： 由以下通式表示的末端碘化多氟烷烃低聚物：<？in-line-formula description =“In-line formula”end =“lead”？> CnF2n + 1（CH2CF2）s + p（CF2CF2）t + I] <？in-line-formula description =“In-line Formulas”end =“tail”？>（其中n为1〜6的整数，s + p为1〜4的整数， 偏氟乙烯骨架，t + r为1〜6的整数，表示四氟乙烯骨架的数量，CnF2n + 1组为CH2CF2组的相邻基团）可以通过末端碘化的多氟烷烃 以下通式：<？in-line-formula description =“In-line Formulas”end =“lead”？> CnF2n + 1（CH2CF2）s + p（CF2CF2）tI <？in-line-formula description =“ 在过氧化物引发剂存在下，使用四氟乙烯在线配方“end =”tail“？”。
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8.发明授权Mixture of fluoroalkyl alcohol-unsaturated carboxylic acid derivatives, polymer of the mixture, and water-and oil-repellent containing the polymer as active ingredient 有权氟代烷基醇 - 不饱和羧酸衍生物的混合物，混合物的聚合物和含有该聚合物作为活性成分的拒水拒油剂公开(公告)号：US08481660B2
公开(公告)日：2013-07-09
申请号：US12863465
申请日：2009-01-20
IPC分类号： C08F18/20
CPC分类号： C07C69/653 , C07C67/08 , C08F20/22 , C09K3/18 , D06M15/263 , D06M15/277 , D06M2200/11 , D06M2200/12
摘要： Disclosed is (1) a mixture of fluoroalkyl alcohol-unsaturated carboxylic acid derivatives represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)c OCOCR═CH2 and CF3(CF2)n−1(CF═CH)a CF2(CF2CF2)b(CH2CH2)cOCOCR═CH2, wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 5, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3; (2) a fluorine-containing polymer containing the mixture as a polymerization unit; and (3) a water- and oil-repellent comprising the fluorine-containing polymer as an active ingredient. The fluoroalkyl alcohol-unsaturated carboxylic acid derivatives are produced by an esterification reaction of a mixture of fluoroalkyl alcohols represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)cOH and CF3(CF2)n−1(CF═CH)aCF2(CF2CF2)b, (CH2CH2)cOH, with acrylic acid or methacrylic acid.
摘要翻译： 公开了（1）由以下通式表示的氟烷基醇 - 不饱和羧酸衍生物的混合物：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OCOCR = CH 2和CF 3（CF 2） 1（CF = CH）a CF 2（CF 2 CF 2）b（CH 2 CH 2）cOCOCR = CH 2，其中R是氢原子或甲基，n是1至5的整数，a是1至4的整数，b是 0〜3的整数，c为1〜3的整数。 （2）含有该混合物作为聚合单元的含氟聚合物; 和（3）含氟聚合物作为有效成分的拒水拒油剂。 氟代烷基醇 - 不饱和羧酸衍生物是由通式CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OH和CF 3（CF 2））表示的氟烷基醇的混合物的酯化反应产生的， n-1（CF = CH）aCF2（CF2CF2）b，（CH2CH2）cOH与丙烯酸或甲基丙烯酸反应。
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公开(公告)号：US08357772B2
公开(公告)日：2013-01-22
申请号：US12677579
申请日：2008-08-29
CPC分类号： C08F114/18 , C07C17/278 , C07C19/16 , C08F14/18 , C08F214/18 , C08F2/00
摘要： Provided is a terminally iodized polyfluoroalkane represented by the general formula: CnF2n+1(CHXCFY)s+p(CF2CF2)t+rI [I] (in the formula, X and Y are each a hydrogen atom or a fluorine atom, wherein when Y is a fluorine atom, X is also a fluorine atom; n is an integer of 1 to 6; s+p is an integer of 1 to 5 and denotes the number of CHXCFY group; and t+r is 0 or an integer of 1 to 6 and denotes the number of tetrafluoroethylene skeleton). The terminally iodized polyfluoroalkane is produced by telomerizing a fluorine-containing olefin CHX═CFY and tetrafluoroethylene, successively, to CnF2n+1I in the presence of a peroxide initiator.
摘要翻译： 提供由以下通式表示的末端碘化多氟烷烃：CnF2n + 1（CHXCFY）s + p（CF2CF2）t + rI [I]（在该式中，X和Y各自为氢原子或氟原子，其中当 Y为氟原子，X为氟原子，n为1〜6的整数，s + p为1〜5的整数，表示CHXCFY基的数，t + r为0或整数 1〜6，表示四氟乙烯骨架的数量）。 末端碘化的多氟烷烃是通过在含有过氧化物引发剂的存在下将含氟烯烃CHX = CFY和四氟乙烯连续地调节至C n F 2n + 1 I来制备的。
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10.发明申请MIXTURE OF FLUOROALKYL ALCOHOL-UNSATURATED CARBOXYLIC ACID DERIVATIVES, POLYMER OF THE MIXTURE, AND WATER-AND OIL-REPELLENT CONTAINING THE POLYMER AS ACTIVE INGREDIENT 有权氟烷基醇不饱和羧酸衍生物的混合物，混合物的聚合物和含有聚合物作为活性成分的水和油的混合物公开(公告)号：US20100292393A1
公开(公告)日：2010-11-18
申请号：US12863465
申请日：2009-01-20
CPC分类号： C07C69/653 , C07C67/08 , C08F20/22 , C09K3/18 , D06M15/263 , D06M15/277 , D06M2200/11 , D06M2200/12
摘要： Disclosed is (1) a mixture of fluoroalkyl alcohol-unsaturated carboxylic acid derivatives represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)c OCOCR═CH2 and CF3(CF2)n−1(CF═CH)a CF2(CF2CF2)b(CH2CH2)cOCOCR═CH2, wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 5, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3; (2) a fluorine-containing polymer containing the mixture as a polymerization unit; and (3) a water- and oil-repellent comprising the fluorine-containing polymer as an active ingredient. The fluoroalkyl alcohol-unsaturated carboxylic acid derivatives are produced by an esterification reaction of a mixture of fluoroalkyl alcohols represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)cOH and CF3(CF2)n−1(CF═CH)aCF2(CF2CF2)b, (CH2CH2)cOH, with acrylic acid or methacrylic acid.
摘要翻译： 公开了（1）由以下通式表示的氟烷基醇 - 不饱和羧酸衍生物的混合物：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OCOCR = CH 2和CF 3（CF 2） 1（CF = CH）a CF 2（CF 2 CF 2）b（CH 2 CH 2）cOCOCR = CH 2，其中R为氢原子或甲基，n为1〜5的整数，a为1〜4的整数，b为 0〜3的整数，c为1〜3的整数。 （2）含有该混合物作为聚合单元的含氟聚合物; 和（3）含氟聚合物作为有效成分的拒水拒油剂。 氟烷基醇 - 不饱和羧酸衍生物通过由以下通式表示的氟烷基醇的酯化反应制备：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OH和CF 3（CF 2） n-1（CF = CH）aCF2（CF2CF2）b，（CH2CH2）cOH与丙烯酸或甲基丙烯酸反应。
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