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    Mixture of fluoroalkyl alcohol-unsaturated carboxylic acid derivatives, polymer of the mixture, and water-and oil-repellent containing the polymer as active ingredient
    6.
    发明授权
    Mixture of fluoroalkyl alcohol-unsaturated carboxylic acid derivatives, polymer of the mixture, and water-and oil-repellent containing the polymer as active ingredient 有权
    氟代烷基醇 - 不饱和羧酸衍生物的混合物，混合物的聚合物和含有该聚合物作为活性成分的拒水拒油剂

    公开(公告)号：US08481660B2

    公开(公告)日：2013-07-09

    申请号：US12863465

    申请日：2009-01-20

    申请人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Satoshi Kurihara

    发明人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Satoshi Kurihara

    IPC分类号： C08F18/20

    CPC分类号： C07C69/653 ,  C07C67/08 ,  C08F20/22 ,  C09K3/18 ,  D06M15/263 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12

    摘要： Disclosed is (1) a mixture of fluoroalkyl alcohol-unsaturated carboxylic acid derivatives represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)c OCOCR═CH2 and CF3(CF2)n−1(CF═CH)a CF2(CF2CF2)b(CH2CH2)cOCOCR═CH2, wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 5, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3; (2) a fluorine-containing polymer containing the mixture as a polymerization unit; and (3) a water- and oil-repellent comprising the fluorine-containing polymer as an active ingredient. The fluoroalkyl alcohol-unsaturated carboxylic acid derivatives are produced by an esterification reaction of a mixture of fluoroalkyl alcohols represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)cOH and CF3(CF2)n−1(CF═CH)aCF2(CF2CF2)b, (CH2CH2)cOH, with acrylic acid or methacrylic acid.

    摘要翻译： 公开了（1）由以下通式表示的氟烷基醇 - 不饱和羧酸衍生物的混合物：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OCOCR = CH 2和CF 3（CF 2） 1（CF = CH）a CF 2（CF 2 CF 2）b（CH 2 CH 2）cOCOCR = CH 2，其中R是氢原子或甲基，n是1至5的整数，a是1至4的整数，b是 0〜3的整数，c为1〜3的整数。 （2）含有该混合物作为聚合单元的含氟聚合物; 和（3）含氟聚合物作为有效成分的拒水拒油剂。 氟代烷基醇 - 不饱和羧酸衍生物是由通式CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OH和CF 3（CF 2））表示的氟烷基醇的混合物的酯化反应产生的， n-1（CF = CH）aCF2（CF2CF2）b，（CH2CH2）cOH与丙烯酸或甲基丙烯酸反应。

    MIXTURE OF FLUOROALKYL ALCOHOL-UNSATURATED CARBOXYLIC ACID DERIVATIVES, POLYMER OF THE MIXTURE, AND WATER-AND OIL-REPELLENT CONTAINING THE POLYMER AS ACTIVE INGREDIENT
    7.
    发明申请
    MIXTURE OF FLUOROALKYL ALCOHOL-UNSATURATED CARBOXYLIC ACID DERIVATIVES, POLYMER OF THE MIXTURE, AND WATER-AND OIL-REPELLENT CONTAINING THE POLYMER AS ACTIVE INGREDIENT 有权
    氟烷基醇不饱和羧酸衍生物的混合物，混合物的聚合物和含有聚合物作为活性成分的水和油的混合物

    公开(公告)号：US20100292393A1

    公开(公告)日：2010-11-18

    申请号：US12863465

    申请日：2009-01-20

    申请人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Satoshi Kurihara

    发明人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Satoshi Kurihara

    IPC分类号： C08L33/14 ,  C09K3/00 ,  C08F20/22

    CPC分类号： C07C69/653 ,  C07C67/08 ,  C08F20/22 ,  C09K3/18 ,  D06M15/263 ,  D06M15/277 ,  D06M2200/11 ,  D06M2200/12

    摘要： Disclosed is (1) a mixture of fluoroalkyl alcohol-unsaturated carboxylic acid derivatives represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)c OCOCR═CH2 and CF3(CF2)n−1(CF═CH)a CF2(CF2CF2)b(CH2CH2)cOCOCR═CH2, wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 5, a is an integer of 1 to 4, b is an integer of 0 to 3, and c is an integer of 1 to 3; (2) a fluorine-containing polymer containing the mixture as a polymerization unit; and (3) a water- and oil-repellent comprising the fluorine-containing polymer as an active ingredient. The fluoroalkyl alcohol-unsaturated carboxylic acid derivatives are produced by an esterification reaction of a mixture of fluoroalkyl alcohols represented by the general formulae: CF3(CF2)n(CH═CF)a(CF2CF2)b(CH2CH2)cOH and CF3(CF2)n−1(CF═CH)aCF2(CF2CF2)b, (CH2CH2)cOH, with acrylic acid or methacrylic acid.

    摘要翻译： 公开了（1）由以下通式表示的氟烷基醇 - 不饱和羧酸衍生物的混合物：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OCOCR = CH 2和CF 3（CF 2） 1（CF = CH）a CF 2（CF 2 CF 2）b（CH 2 CH 2）cOCOCR = CH 2，其中R为氢原子或甲基，n为1〜5的整数，a为1〜4的整数，b为 0〜3的整数，c为1〜3的整数。 （2）含有该混合物作为聚合单元的含氟聚合物; 和（3）含氟聚合物作为有效成分的拒水拒油剂。 氟烷基醇 - 不饱和羧酸衍生物通过由以下通式表示的氟烷基醇的酯化反应制备：CF 3（CF 2）n（CH = CF）a（CF 2 CF 2）b（CH 2 CH 2）c OH和CF 3（CF 2） n-1（CF = CH）aCF2（CF2CF2）b，（CH2CH2）cOH与丙烯酸或甲基丙烯酸反应。

    Terminally Iodized Polyfluoroalkane Oligomer and Process for Producing the Same
    8.
    发明申请
    Terminally Iodized Polyfluoroalkane Oligomer and Process for Producing the Same 审中-公开
    末端碘化多氟烷烃低聚物及其制备方法

    公开(公告)号：US20090018294A1

    公开(公告)日：2009-01-15

    申请号：US12224469

    申请日：2007-02-28

    申请人： Masayosi Horiuti ,  Seiichiro Murata ,  Katsuyuki Sato ,  Hideki Abe

    发明人： Masayosi Horiuti ,  Seiichiro Murata ,  Katsuyuki Sato ,  Hideki Abe

    IPC分类号： C08G61/02 ,  C08F4/28

    CPC分类号： C07C19/16 ,  C07C17/278

    摘要： A terminally iodized polyfluoroalkane oligomer represented by the following general formula: CnF2n+1(CH2CF2)s+p(CF2CF2)t+rI  [I] (wherein n is an integer of 1 to 6, s+p is an integer of 1 to 4, showing the number of vinylidene fluoride skeleton, and t+r is an integer of 1 to 6, showing the number of tetrafluoroethylene skeleton, the adjacent group to the CnF2n+1 group being the CH2CF2 group) can be produced by reaction of a terminally iodized polyfluoroalkane, represented by the following general formula: CnF2n+1(CH2CF2)s+p(CF2CF2)tI with tetrafluoroethylene in the presence of a peroxide initiator.

    摘要翻译： 由以下通式表示的末端碘化多氟烷烃低聚物：<？in-line-formula description =“In-line formula”end =“lead”？> CnF2n + 1（CH2CF2）s + p（CF2CF2）t + I] <？in-line-formula description =“In-line Formulas”end =“tail”？>（其中n为1〜6的整数，s + p为1〜4的整数， 偏氟乙烯骨架，t + r为1〜6的整数，表示四氟乙烯骨架的数量，CnF2n + 1组为CH2CF2组的相邻基团）可以通过末端碘化的多氟烷烃 以下通式：<？in-line-formula description =“In-line Formulas”end =“lead”？> CnF2n + 1（CH2CF2）s + p（CF2CF2）tI <？in-line-formula description =“ 在过氧化物引发剂存在下，使用四氟乙烯在线配方“end =”tail“？”。

    Polyfluoroalkyl Alcohol, Or (METH)Acrylic Acid Derivative Thereof, And Process For Producing The Same
    9.
    发明申请
    Polyfluoroalkyl Alcohol, Or (METH)Acrylic Acid Derivative Thereof, And Process For Producing The Same 有权
    多氟烷基醇或（甲基）丙烯酸衍生物及其制备方法

    公开(公告)号：US20090036706A1

    公开(公告)日：2009-02-05

    申请号：US12224969

    申请日：2007-03-09

    申请人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Hideki Abe ,  Haruyoshi Tatsu

    发明人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Hideki Abe ,  Haruyoshi Tatsu

    IPC分类号： C07C67/08 ,  C07C31/38

    CPC分类号： C07C31/38 ,  C07C17/275 ,  C07C19/16 ,  C07C29/09 ,  C07C29/124 ,  C07C67/08 ,  C07C69/653

    摘要： A polyfluoroalkyl alcohol, or a (meth)acrylic acid derivative thereof, represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOR (R:H or (meth)acrylic acid group; n: 1-6; a: 1-4; b: 1-3; and c: 1-3). Polyfluoroalkyl alcohol (R: hydrogen atom) can be produced by reaction of fluoroalkyl iodide represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI with N-methyl formamide, followed by hydrolysis in the presence of an acid catalyst, whereas polyfluoroalkyl alcohol (meth)acrylic acid derivative (R: (meth)acrylic acid group) can be produced by reaction of the polyfluoroalkyl alcohol with (meth)acrylic acid.

    摘要翻译： 一种多氟烷基醇或其（甲基）丙烯酸衍生物，由以下通式表示：<？in-line-formula description =“In-line formula”end =“lead”>> CnF2n + 1（CH2CF2）a （CF 2 CF 2）b（CH 2 CH 2）cOR <αin-line-formula description =“In-line Formulas”end =“tail”？>（R：H或（甲基）丙烯酸基团; n：1-6; a： 1-4; b：1-3;和c：1-3）。 多氟烷基醇（R：氢原子）可以通过以下通式表示的氟代烷基碘的反应来制备：<？in-line-formula description =“In-Line Formulas”end =“lead”？> CnF2n + 1（CH2CF2 ）a（CF 2 CF 2）b（CH 2 CH 2）cI <βin-line-formula description =“In-line Formulas”end =“tail”→与N-甲基甲酰胺，然后在酸催化剂存在下水解，而 多氟烷基醇（甲基）丙烯酸衍生物（R：（甲基）丙烯酸基））可以通过多氟烷基醇与（甲基）丙烯酸的反应来制备。

    Polyfluoroalkyl alcohol, or (METH)acrylic acid derivative thereof, and process for producing the same
    10.
    发明授权
    Polyfluoroalkyl alcohol, or (METH)acrylic acid derivative thereof, and process for producing the same 有权
    多氟烷基醇或其（METH）丙烯酸衍生物及其制造方法

    公开(公告)号：US07566801B2

    公开(公告)日：2009-07-28

    申请号：US12224969

    申请日：2007-03-09

    申请人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Hideki Abe ,  Haruyoshi Tatsu

    发明人： Seiichiro Murata ,  Masayosi Horiuti ,  Katsuyuki Sato ,  Hideki Abe ,  Haruyoshi Tatsu

    IPC分类号： C07C67/36

    CPC分类号： C07C31/38 ,  C07C17/275 ,  C07C19/16 ,  C07C29/09 ,  C07C29/124 ,  C07C67/08 ,  C07C69/653

    摘要： A polyfluoroalkyl alcohol, or a (meth)acrylic acid derivative thereof, represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOR (R:H or (meth)acrylic acid group; n: 1-6; a: 1-4; b: 1-3; and c: 1-3). Polyfluoroalkyl alcohol (R: hydrogen atom) can be produced by reaction of fluoroalkyl iodide represented by the following general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI with N-methyl formamide, followed by hydrolysis in the presence of an acid catalyst, whereas polyfluoroalkyl alcohol (meth)acrylic acid derivative (R: (meth)acrylic acid group) can be produced by reaction of the polyfluoroalkyl alcohol with (meth)acrylic acid.

    摘要翻译： 一种多氟烷基醇或其（甲基）丙烯酸衍生物，由以下通式表示：<？in-line-formula description =“In-line formula”end =“lead”>> CnF2n + 1（CH2CF2）a （CF 2 CF 2）b（CH 2 CH 2）cOR <αin-line-formula description =“In-line Formulas”end =“tail”？>（R：H或（甲基）丙烯酸基团; n：1-6; a： 1-4; b：1-3;和c：1-3）。 多氟烷基醇（R：氢原子）可以通过以下通式表示的氟代烷基碘的反应来制备：<？in-line-formula description =“In-line formula”end =“lead”>> CnF2n + 1（CH2CF2 ）a（CF 2 CF 2）b（CH 2 CH 2）cI <βin-line-formula description =“In-line Formulas”end =“tail”→与N-甲基甲酰胺，然后在酸催化剂存在下水解，而 多氟烷基醇（甲基）丙烯酸衍生物（R：（甲基）丙烯酸基））可以通过多氟烷基醇与（甲基）丙烯酸的反应来制备。