Substituted metallocene compounds for olefin polymerization catalyst systems, their intermediates and methods for preparing them

    公开(公告)号:US06355819B1

    公开(公告)日:2002-03-12

    申请号:US09402934

    申请日:1999-12-20

    IPC分类号: C07F1700

    摘要: The invention relates to metallocene compounds having the formula (I): (CpYq)mMRnBo  (I) wherein: Cp or each same or different Cp is a non-substituted or substituted, fused or non-fused, homo(iso)cyclic or heterocyclic cyclopentadienyl ligand, indenyl ligand, tetrahydroindenyl ligand, fluorenyl ligand or octahydrofluorenyl ligand, Y or each same or different Y is a substituent at the cyclopentadienyl ring of said ligand Cp having the following structure (II): wherein: D is an element of Group 14 of the Periodic Table (IUPAC), R1, R2 and R3 are the same or different and are each one of a hydrogen, a halogen, a substituted or unsubstituted C1-C10 hydrocarbyl group, a substituted or unsubstituted C1-C10 hydrocarbyloxy group, a C1-C12 organosilicon group, or at least two of R1, R2 and R3 form together with D a C4-C20 ring structure; M is a transition metal of Group 4 of the Periodic Table (IUPAC) and is bound to the ligand Cp or ligands Cp in an &eegr;5 bonding mode; R or each same or different R is bound to M and is one of a hydrogen, a halogen, a substituted or unsubstituted C1-C10 hydrocarbyl group, a substituted or unsubstituted C1-C10 hydrocarbyloxy group, a C1-C12 organosilicon group, or two R form together with M a C4-C20 metallocyclic ring structure; B is a bridge atom or group between two Cp ligands or between one Cp ligand and M; q is, when Cp is non-bridged, 0-5 for the cyclopentadienyl ligand, 0-3 for the indenyl or tetrahydroindenyl ligand and 0-1 for the fluorenyl or octahydrofluorenyl ligand, q is, when Cp is bridged, 0-4 for the cyclopentadienyl ligand, 0-2 for the indenyl or tetrahydroindenyl ligand and 0 for the fluorenyl or octahydrofluorenyl ligand; m is 1 or 2; m·q≧1; o is 0 or 1; and n is 4-m-o, except when there is one bridge B between two Cp ligands, in which case n is 4-m, their intermediates, preparation and use.

    Flame retardant compositions
    5.
    发明申请
    Flame retardant compositions 审中-公开
    阻燃组合物

    公开(公告)号:US20070029531A1

    公开(公告)日:2007-02-08

    申请号:US10573850

    申请日:2004-09-22

    IPC分类号: C09K21/00

    CPC分类号: C08K5/0066 C08K5/23 C08L23/02

    摘要: The present invention is directed to a method of flame retarding a polymeric substrate using a specific group of azo and peroxide derivatives as flame retardants, to flame retardant compositions as well as to novel azo compounds usable as flame retarding compounds.

    摘要翻译: 本发明涉及使用特定的一组偶氮和过氧化物衍生物作为阻燃剂阻燃聚合物基质,阻燃组合物以及可用作阻燃化合物的新型偶氮化合物的方法。