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    Polymer electrolyte membranes crosslinked by nitrile trimerization
    1.
    发明授权
    Polymer electrolyte membranes crosslinked by nitrile trimerization 失效
    通过腈三聚交联的聚合物电解质膜

    公开(公告)号：US07074841B2

    公开(公告)日：2006-07-11

    申请号：US10712589

    申请日：2003-11-13

    申请人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

    发明人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

    IPC分类号： C08J3/28 ,  C08J3/00 ,  C08J5/22 ,  C08J5/20

    CPC分类号： C08J5/225 ,  C08J2327/12

    摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1–15 carbon atoms and 0–4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

    摘要翻译： 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R

    Polymer electrolyte membranes crosslinked by nitrile trimerization
    2.
    发明授权
    Polymer electrolyte membranes crosslinked by nitrile trimerization 有权
    通过腈三聚交联的聚合物电解质膜

    公开(公告)号：US07435498B2

    公开(公告)日：2008-10-14

    申请号：US11419515

    申请日：2006-05-22

    申请人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

    发明人： Michael A. Yandrasits ,  Steven J. Hamrock ,  Werner M. Grootaert ,  Miguel A. Guerra ,  Naiyong Jing

    IPC分类号： B01J39/16 ,  B01J39/18 ,  C08F12/02 ,  C08F12/20 ,  C08F14/18 ,  H01M8/10

    CPC分类号： C08J5/225 ,  C08J2327/12

    摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

    摘要翻译： 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R

    Partially fluorinated sulfinic acid monomers and their salts
    5.
    发明授权
    Partially fluorinated sulfinic acid monomers and their salts 有权
    部分氟化亚磺酸单体及其盐

    公开(公告)号：US09187416B2

    公开(公告)日：2015-11-17

    申请号：US13885202

    申请日：2011-12-09

    申请人： Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

    发明人： Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

    IPC分类号： C07C313/04 ,  C07C17/275 ,  C07C303/22 ,  C08F214/18

    CPC分类号： C07C313/04 ,  C07C17/275 ,  C07C303/22 ,  C08F214/186 ,  C07C19/07 ,  C07C19/075 ,  C07C309/82 ,  C07C309/80 ,  C07C309/81

    摘要： Described herein is a composition according to formula I or its precursor, formula II: CX1X3═CX2—(R1)p—CZ1 Z2-SO2M (I) wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3 and CH3, and wherein at least one of X1, X2, or X3 is a H; R1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF3, and a perfluoroalkyl group; p is 0 or 1; and M is a cation; and CX4X1X3—CX5X2—(R1)p—CZ1Z2-SO2M (II) wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3 and CH3, wherein at least one of X1, X2, or X3 is a H, and X4 and X5 are independently selected from H, F, Cl, Br and I; R1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF3, and a perfluoroalkyl group, p is 0 or 1; and M is selected from F, and a cation.

    摘要翻译： 本文描述了根据式I或其前体，式II的组合物：CX1X3 = CX2-（R1）p-CZ1Z2-SO2M（I）其中X1，X2和X3独立地选自H，F，Cl，Br ，I，CF 3和CH 3，并且其中X 1，X 2或X 3中的至少一个为H; R1是连接基团; Z 1和Z 2独立地选自F，Cl，Br，I，CF 3和全氟烷基; p为0或1; M是阳离子; 和CX4X1X3-CX5X2-（R1）对CZ1Z2-SO2M（Ⅱ），其中X1，X2和X3独立地选自H，F，Cl，Br，I，CF3和CH3，其中X1，X2， 或X 3为H，X 4和X 5独立地选自H，F，Cl，Br和I; R1是连接基团; Z 1和Z 2独立地选自F，Cl，Br，I，CF 3和全氟烷基，p为0或1; 并且M选自F和阳离子。

    PARTIALLY FLUORINATED SULFINIC ACID MONOMERS AND THEIR SALTS
    7.
    发明申请
    PARTIALLY FLUORINATED SULFINIC ACID MONOMERS AND THEIR SALTS 有权
    部分氟化硫酸单体及其销售

    公开(公告)号：US20130253220A1

    公开(公告)日：2013-09-26

    申请号：US13885202

    申请日：2011-12-09

    申请人： Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

    发明人： Zai-Ming Qiu ,  Gregg D. Dahlke ,  Tatsuo Fukushi ,  Werner M. Grootaert ,  Miguel A. Guerra

    IPC分类号： C07C313/04

    CPC分类号： C07C313/04 ,  C07C17/275 ,  C07C303/22 ,  C08F214/186 ,  C07C19/07 ,  C07C19/075 ,  C07C309/82 ,  C07C309/80 ,  C07C309/81

    摘要： Described herein is a composition according to formula I or its precursor, formula II: CX1X3═CX2—(R1)p—CZ1Z2-SO2M (I) wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3 and CH3, and wherein at least one of X1, X2, or X3 is a H; R1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF3, and a perfluoroalkyl group; p is 0 or 1; and M is a cation; and CX4X1X3—CX5X2—(R1)p—CZ1Z2-SO2M (II) wherein X1, X2, and X3 are independently selected from H, F, Cl, Br, I, CF3 and CH3, wherein at least one of X1, X2, or X3 is a H, and X4 and X5 are independently selected from H, F, Cl, Br and I; R1 is a linking group; Z1 and Z2 are independently selected from F, Cl, Br, I, CF3, and a perfluoroalkyl group, p is 0 or 1; and M is selected from F, and a cation.

    摘要翻译： 本文描述了根据式I或其前体，式II的组合物：CX1X3 = CX2-（R1）p-CZ1Z2-SO2M（I）其中X1，X2和X3独立地选自H，F，Cl，Br， I，CF 3和CH 3，并且其中X 1，X 2或X 3中的至少一个为H; R1是连接基团; Z 1和Z 2独立地选自F，Cl，Br，I，CF 3和全氟烷基; p为0或1; M是阳离子; 和CX4X1X3-CX5X2-（R1）对CZ1Z2-SO2M（Ⅱ），其中X1，X2和X3独立地选自H，F，Cl，Br，I，CF3和CH3，其中X1，X2， 或X 3为H，X 4和X 5独立地选自H，F，Cl，Br和I; R1是连接基团; Z 1和Z 2独立地选自F，Cl，Br，I，CF 3和全氟烷基，p为0或1; 并且M选自F和阳离子。

    Reinforced polymer electrolyte membrane
    10.
    发明授权
    Reinforced polymer electrolyte membrane 有权
    增强聚合物电解质膜

    公开(公告)号：US07259208B2

    公开(公告)日：2007-08-21

    申请号：US10712360

    申请日：2003-11-13

    申请人： Miguel A. Guerra ,  Michael A. Yandrasits

    发明人： Miguel A. Guerra ,  Michael A. Yandrasits

    IPC分类号： C08F8/30

    CPC分类号： C08J5/2281 ,  C08J2379/06 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/103 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56

    摘要： A method is provided for making a reinforced polymer electrolyte membrane, such as may be used in electrolytic cells such as fuel cells, by mixing a sulfonate- or sulfonyl halide-functional polymer with a bisamidine compound and subsequently trimerizing the amidine groups of the bisamidine compound to form triazine linkages. The sulfonyl halide or sulfonate groups may then be converted to sulfonic acid groups, yielding a polymer electrolyte reinforced with a polytriazine.

    摘要翻译： 提供了用于制造增强聚合物电解质膜的方法，例如可以用于诸如燃料电池的电解池中，通过将磺酸盐或磺酰卤官能聚合物与双脒化合物混合，随后将双脒化合物的脒基团三聚 以形成三嗪键。 然后将磺酰卤或磺酸酯基团转化为磺酸基团，产生用聚三嗪增强的聚合物电解质。