利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

66 条记录 (耗时 0.023 秒)

    LOW EQUIVALENT WEIGHT POLYMERS
    3.
    发明申请
    LOW EQUIVALENT WEIGHT POLYMERS 有权
    低等量重量聚合物

    公开(公告)号：US20140141357A1

    公开(公告)日：2014-05-22

    申请号：US14234464

    申请日：2012-07-27

    申请人： Kai H. Lochhaas ,  Steven J. Hamrock ,  Klaus Hintzer

    发明人： Kai H. Lochhaas ,  Steven J. Hamrock ,  Klaus Hintzer

    IPC分类号： H01M8/10

    CPC分类号： H01M8/102 ,  C08F214/18 ,  C08J5/2237 ,  C08L41/00 ,  H01M8/1023 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1051 ,  H01M8/1072 ,  H01M8/109 ,  H01M2300/0082 ,  Y02P70/56

    摘要： Described herein is a composition comprising: a polymer derived from (a) a fluorinated olefin monomer; (b) a highly fluorinated sulfur-containing monomer of the formula: CX1X2═CX3[(CX4X5)w—O—R1—SO2Y] where X1, X2, X3, X4, and X5 are independently selected from H, Cl, or F; w is 0 or 1; R1 is a non-fluorinated or fluorinated alkylene group; and Y is selected from F, Cl, Br, I, or OM, where M is a cation; and (c) a poly-functional monomer comprising at least two functional groups, wherein the functional groups are selected from the group consisting of: (i) a fluorovinyl ether group, (ii) a fluoroallyl ether group, (iii) a fluorinated olefinic group, and (iv) combinations thereof; articles thereof; and a method of making such polymers.

    摘要翻译： 本文描述的组合物包含：衍生自（a）氟化烯烃单体的聚合物; （b）具有下式的高度含氟的含硫单体：CX1X2 = C3 [[（CX4X5）w-O-R1-SO2Y]其中X1，X2，X3，X4和X5独立地选自H，Cl或F ; w为0或1; R1是非氟化或氟化亚烷基; Y选自F，Cl，Br，I或OM，其中M是阳离子; 和（c）包含至少两个官能团的多官能单体，其中所述官能团选自：（i）氟乙烯基醚基团，（ii）氟烯基醚基团，（iii）氟化烯烃 组，和（iv）它们的组合; 其制品; 和制备这种聚合物的方法。

    High durability fuel cell components with cerium salt additives
    4.
    发明授权
    High durability fuel cell components with cerium salt additives 有权
    高耐久性燃料电池组件与铈盐添加剂

    公开(公告)号：US08628871B2

    公开(公告)日：2014-01-14

    申请号：US11262268

    申请日：2005-10-28

    申请人： Matthew H. Frey ,  Daniel M. Pierpont ,  Steven J. Hamrock

    发明人： Matthew H. Frey ,  Daniel M. Pierpont ,  Steven J. Hamrock

    IPC分类号： H01M8/10

    CPC分类号： H01M8/1051 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1027 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1058 ,  H01M8/1072 ,  H01M8/1081 ,  H01M2300/0091 ,  Y02E60/521 ,  Y02P70/56

    摘要： A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane which comprises a polymer that comprises bound anionic functional groups, wherein the polymer electrolyte membrane additionally comprises cerium cations. In another aspect, a fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane which comprises a polymer that comprises bound anionic functional groups, wherein at least a portion of the anionic functional groups are in acid form and at least a portion of the anionic functional groups are neutralized by cerium cations. In another aspect, a polymer electrolyte membrane is provided which comprises a polymer that comprises bound anionic functional groups, wherein the polymer electrolyte membrane additionally comprises cerium cations, and wherein the amount of cerium cations present is between 0.001 and 0.5 charge equivalents based on the molar amount of acid functional groups present in the polymer electrolyte, more typically between 0.005 and 0.2, more typically between 0.01 and 0.1, and more typically between 0.02 and 0.05.

    摘要翻译： 提供一种燃料电池膜电极组件，其包括聚合物电解质膜，其包含含有结合的阴离子官能团的聚合物，其中所述聚合物电解质膜另外包含铈阳离子。 在另一方面，提供一种燃料电池膜电极组件，其包括聚合物电解质膜，其包含含有结合的阴离子官能团的聚合物，其中至少一部分阴离子官能团为酸形式，并且至少部分阴离子 官能团被铈阳离子中和。 在另一方面，提供了一种聚合物电解质膜，其包含含有结合的阴离子官能团的聚合物，其中所述聚合物电解质膜另外包含铈阳离子，并且其中存在的铈阳离子的量为0.001至0.5当量，基于摩尔 存在于聚合物电解质中的酸官能团的量更多，通常在0.005至0.2之间，更典型地在0.01至0.1之间，更典型地在0.02至0.05之间。

    Polymer electrolytes including heteropolyacids
    6.
    发明授权
    Polymer electrolytes including heteropolyacids 有权
    包括杂多酸的聚合物电解质

    公开(公告)号：US08206874B2

    公开(公告)日：2012-06-26

    申请号：US12266932

    申请日：2008-11-07

    申请人： Steven J. Hamrock ,  Matthew H. Frey ,  Michael A. Yandrasits ,  Gregory M. Haugen ,  Andrew M. Herring ,  James L. Horan ,  Niccolo V. Aieta

    发明人： Steven J. Hamrock ,  Matthew H. Frey ,  Michael A. Yandrasits ,  Gregory M. Haugen ,  Andrew M. Herring ,  James L. Horan ,  Niccolo V. Aieta

    IPC分类号： H01M8/10

    CPC分类号： H01M8/1032 ,  C08J5/2231 ,  C08J2333/02 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/1039 ,  H01M8/1048

    摘要： This disclosure provides polymer electrolytes, polymer electrolyte membranes (PEM's) and membrane electrode assemblies (MEA's) such as may be useful in fuel cells which contain or comprise polyoxometalates (POM's) or heteropolyacids (HPA's). In some embodiments the polyoxometalate, it's counterions or both may comprise Mn and/or Ce. In some embodiments the polymer electrolyte is fluorinated. In some embodiments the polymer electrolyte comprises a second acidic functional group other than a polyoxometalate. In another aspect, the present disclosure provides methods of making polymer electrolytes including methods which comprising a step of copolymerizing monomers comprising a covalently bound polyoxometalates and methods which comprise a step of covalently attaching a polyoxometalate to the polymer.

    摘要翻译： 本公开提供了聚合物电解质，聚合物电解质膜（PEM）和膜电极组件（MEA's），例如可用于含有或包含多金属氧酸盐（POM）或杂多酸（HPA））的燃料电池。 在一些实施方案中，多金属氧酸盐，其抗衡离子或两者可以包含Mn和/或Ce。 在一些实施方案中，聚合物电解质是氟化的。 在一些实施方案中，聚合物电解质包含除多金属氧酸盐以外的第二酸性官能团。 在另一方面，本公开提供了制备聚合物电解质的方法，包括使包含共价结合的多金属氧酸盐的单体共聚的步骤的方法和包括将多金属氧酸盐共价连接到聚合物上的步骤的方法。

    METHOD OF MAKING DURABLE POLYMER ELECTROLYTE MEMBRANES
    8.
    发明申请
    METHOD OF MAKING DURABLE POLYMER ELECTROLYTE MEMBRANES 有权
    制备耐久聚合物电解质膜的方法

    公开(公告)号：US20080160380A1

    公开(公告)日：2008-07-03

    申请号：US11962971

    申请日：2007-12-21

    申请人： Steven J. HAMROCK

    发明人： Steven J. HAMROCK

    IPC分类号： H01M8/10 ,  B05D1/02 ,  B05D1/16

    CPC分类号： H01M8/1004 ,  H01M8/1048 ,  H01M8/1088 ,  H01M2300/0082 ,  H01M2300/0094 ,  Y02P70/56

    摘要： A method of making a durable fuel cell polymer electrolyte membrane is provided comprising the steps of: a) providing a polymer electrolyte membrane; b) providing a solution of a salt selected from the group consisting of manganese salts and cerium salts or a suspension of particles of a compound selected from the group consisting of manganese oxides and cerium oxides; and c) applying the solution or suspension to the polymer electrolyte membrane by a method selected from the group consisting of brushing, spraying and use of a slot die. Some embodiments comprise metered application of the solution to the polymer electrolyte membrane.

    摘要翻译： 提供一种制造耐久性燃料电池聚合物电解质膜的方法，包括以下步骤：a）提供聚合物电解质膜; b）提供选自锰盐和铈盐的盐或者选自氧化锰和氧化铈的化合物的颗粒的悬浮液; 和c）通过选自由刷模，喷涂和使用槽模组组成的组中的方法将溶液或悬浮液施加到聚合物电解质膜上。 一些实施方案包括将溶液计量施加到聚合物电解质膜。