公开(公告)号：US08773118B2

公开(公告)日：2014-07-08

申请号：US13003109

申请日：2009-07-10

申请人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Jacobus Lucas Visagie ,  Jan van de Loosdrecht

发明人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Jacobus Lucas Visagie ,  Jan van de Loosdrecht

IPC分类号： G01R33/02 ,  G01R33/12 ,  G01R33/16 ,  C07C27/00 ,  B01D50/00

CPC分类号： G01R33/028

摘要： A magnetometer which includes an elongate reactor in which a sample can be secured in a sample support zone and which is located within a magnetic field space of a magnetic field generator and one or more signal pickup coils. Movement generating means is provided for generating relative movement in a generally linear direction between the reactor and at least one of the magnetic field and pickup coil, preferably by moving the reactor in its length. The magnetometer is characterised in that the reactor is a metal tube having a length which permits its ends to remain external of the signal pickup device during the relative movement.

摘要翻译： 磁力计，其包括细长的反应器，其中样品可以固定在样品支撑区域中，并且位于磁场发生器的磁场空间和一个或多个信号拾取线圈中。 运动产生装置被提供用于在反应器和磁场和拾取线圈中的至少一个之间的大致线性方向产生相对运动，优选通过使反应器的长度移动。 磁力计的特征在于，反应器是具有允许其端部在相对运动期间保持在信号拾取装置外部的长度的金属管。

公开(公告)号：US20110204884A1

公开(公告)日：2011-08-25

申请号：US13003109

申请日：2009-07-10

申请人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Jacobus Lucas Visagie ,  Jan van de Loosdrecht

发明人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Jacobus Lucas Visagie ,  Jan van de Loosdrecht

IPC分类号： G01R33/028

CPC分类号： G01R33/028

摘要： A magnetometer which includes an elongate reactor in which a sample can be secured in a sample support zone and which is located within a magnetic field space of a magnetic field generator and one or more signal pickup coils. Movement generating means is provided for generating relative movement in a generally linear direction between the reactor and at least one of the magnetic field and pickup coil, preferably by moving the reactor in its length. The magnetometer is characterised in that the reactor is a metal tube having a length which permits its ends to remain external of the signal pickup device during the relative movement.

摘要翻译： 磁力计，其包括细长的反应器，其中样品可以固定在样品支撑区域中，并且位于磁场发生器的磁场空间和一个或多个信号拾取线圈中。 运动产生装置被提供用于在反应器和磁场和拾取线圈中的至少一个之间的大致线性方向产生相对运动，优选通过使反应器的长度移动。 磁力计的特征在于，反应器是具有允许其端部在相对运动期间保持在信号拾取装置外部的长度的金属管。

公开(公告)号：US08513463B2

公开(公告)日：2013-08-20

申请号：US12988052

申请日：2009-04-15

申请人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

发明人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

IPC分类号： C07C231/00 ,  C07C233/00 ,  C07F9/02

CPC分类号： C07C231/10 ,  C07C253/00 ,  C07F9/505 ,  C07C233/03 ,  C07C255/03

摘要： A process is described for the production of one or more of linear nitriles, amides and formamides which includes reacting a nitrogen containing compound, such as ammonia or NOx, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A further process for the production of one or more of linear phosphorous containing compounds is also described, which includes reacting a phosphorous containing compound, such as a phosphine, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A supported cobalt, iron, ruthenium or rhodium catalyst or an unsupported (bulk) promoted iron catalyst, modified with a promoter is used. The synthesis gas is a mixture of hydrogen and carbon monoxide, in a ratio from 0.5:1 to 5:1; or a mixture of hydrogen and carbon dioxide; or a mixture of water and carbon monoxide. The suppression of the formation of oxygenates in the process is a feature of the invention and oxygenates may even be included in the feed to become converted to corresponding nitrogen containing compounds in the process.

摘要翻译： 描述了用于生产线性腈，酰胺和甲酰胺中的一种或多种的方法，其包括在160℃和400℃之间的温度下使含氮化合物如氨或NO x与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 还描述了用于生产一种或多种含有线性磷的化合物的另外的方法，其包括在160℃和400℃之间的温度下使含磷化合物如磷化氢与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 使用经助催化剂改性的负载型钴，铁，钌或铑催化剂或未负载（体积）促进的铁催化剂。 合成气是氢和一氧化碳的混合物，其比例为0.5:1至5:1; 或氢和二氧化碳的混合物; 或水和一氧化碳的混合物。 在该过程中抑制含氧化合物的形成是本发明的一个特征，并且氧化物甚至可以包含在进料中以在该方法中转化成相应的含氮化合物。

公开(公告)号：US20110092728A1

公开(公告)日：2011-04-21

申请号：US12988052

申请日：2009-04-15

申请人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

发明人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

IPC分类号： C07C253/00 ,  C07C231/10 ,  C07F9/02

CPC分类号： C07C231/10 ,  C07C253/00 ,  C07F9/505 ,  C07C233/03 ,  C07C255/03

摘要： A process is described for the production of one or more of linear nitriles, amides and formamides which includes reacting a nitrogen containing compound, such as ammonia or NOx, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A further process for the production of one or more of linear phosphorous containing compounds is also described, which includes reacting a phosphorous containing compound, such as a phosphine, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A supported cobalt, iron, ruthenium or rhodium catalyst or an unsupported (bulk) promoted iron catalyst, modified with a promoter is used. The synthesis gas is a mixture of hydrogen and carbon monoxide, in a ratio from 0.5:1 to 5:1; or a mixture of hydrogen and carbon dioxide; or a mixture of water and carbon monoxide. The suppression of the formation of oxygenates in the process is a feature of the invention and oxygenates may even be included in the feed to become converted to corresponding nitrogen containing compounds in the process.

摘要翻译： 描述了用于生产线性腈，酰胺和甲酰胺中的一种或多种的方法，其包括在160℃和400℃之间的温度下使含氮化合物如氨或NO x与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 还描述了用于生产一种或多种含有线性磷的化合物的另外的方法，其包括在160℃和400℃之间的温度下使含磷化合物如磷化氢与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 使用经助催化剂改性的负载型钴，铁，钌或铑催化剂或未负载（体积）促进的铁催化剂。 合成气是氢和一氧化碳的混合物，其比例为0.5:1至5:1; 或氢和二氧化碳的混合物; 或水和一氧化碳的混合物。 在该过程中抑制含氧化合物的形成是本发明的一个特征，并且氧化物甚至可以包含在进料中以在该方法中转化成相应的含氮化合物。

公开(公告)号：US08558047B2

公开(公告)日：2013-10-15

申请号：US12937694

申请日：2009-04-15

申请人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

发明人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

IPC分类号： C07C1/00

CPC分类号： C10G2/50 ,  C10G2/32 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/22 ,  Y02P20/142

摘要： A process is provided for the production of hydrocarbons from synthesis gas wherein the synthesis gas is fed to a reactor in which a catalyst acts on the feed at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 5 bar. The feed includes a compound containing one or both nitrogen and phosphorus added to the reactor with the synthesis gas. The compound containing nitrogen typically constitutes at least 1 vol % and preferably of the order of 4 to 20 vol % or more of the feed. The carbonaceous gas may be carbon monoxide with a ratio of hydrogen to carbon monoxide in the synthesis gas of from 0.5:1 to 5:1. The catalyst is preferably a supported cobalt catalyst and may be modified with a promoter. The process produces an enhanced proportion of olefins, in the hydrocarbons produced.

摘要翻译： 提供了一种用于从合成气生产烃的方法，其中合成气进料到反应器中，其中催化剂在160℃和400℃之间的温度下进料到进料上，压力在1巴之间 和5巴。 进料包括含有合成气加入反应器中的一种或两种氮和磷的化合物。 含有氮的化合物通常构成进料的至少1体积％，优选为4〜20体积％以上。 含碳气体可以是合成气中氢与一氧化碳的比例为0.5:1至5:1的一氧化碳。 催化剂优选为负载型钴催化剂，并可用助催化剂进行改性。 该方法在所生产的烃中产生增加比例的烯烃。

公开(公告)号：US20110160510A1

公开(公告)日：2011-06-30

申请号：US12937694

申请日：2009-04-15

申请人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

发明人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

IPC分类号： C07C1/20

CPC分类号： C10G2/50 ,  C10G2/32 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/22 ,  Y02P20/142

摘要： A process is provided for the production of hydrocarbons that include olefins from synthesis gas containing at least one of carbon monoxide and or carbon dioxide wherein the synthesis gas is fed to a reactor in which a catalyst acts on the feed at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. The feed includes a compound containing one or both of nitrogen and phosphorous, such as ammonia and a phosphine, added to the reactor with the synthesis gas. The compound containing nitrogen typically constitutes at least 1 vol % and preferably of the order of 4 to 20 vol % or more of the feed. The carbonaceous gas may be carbon monoxide with a ratio of hydrogen to carbon monoxide in the synthesis gas of from 0.5:1 to 5:1. The catalyst is preferably a supported cobalt catalyst and may be modified with a promoter. The process produces an enhanced proportion of olefins, especially linear olefins, in the hydrocarbons produced.

摘要翻译： 提供了一种用于生产包含含有一氧化碳和/或二氧化碳中的至少一种的合成气的烯烃的方法，其中将合成气进料到反应器中，其中催化剂在160℃的温度下作用在进料上 和400℃的压力和1巴与50巴之间的压力。 进料包括一种含有氮和磷中的一种或两种的化合物，例如氨和膦，并与合成气一起加入到反应器中。 含有氮的化合物通常构成进料的至少1体积％，优选为4〜20体积％以上。 含碳气体可以是合成气中氢与一氧化碳的比例为0.5:1至5:1的一氧化碳。 催化剂优选为负载型钴催化剂，并可用助催化剂进行改性。 该方法在所生产的烃中产生较高比例的烯烃，特别是直链烯烃。