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    Soluble, electrically conductive polymers, process for preparing them, and their use
    1.
    发明授权
    Soluble, electrically conductive polymers, process for preparing them, and their use 失效
    可溶性导电聚合物，制备方法及其使用

    公开(公告)号：US5093033A

    公开(公告)日：1992-03-03

    申请号：US88662

    申请日：1987-08-24

    申请人： Michael Feldhues ,  Thomas Mecklenburg ,  Peter Wegener ,  Gunther Kampf

    发明人： Michael Feldhues ,  Thomas Mecklenburg ,  Peter Wegener ,  Gunther Kampf

    IPC分类号： C08G61/10 ,  C08G61/12 ,  C08L101/00 ,  C09D165/00 ,  H01B1/12

    CPC分类号： C08G61/126 ,  H01B1/127 ,  Y10T428/2933 ,  Y10T428/31504

    摘要： The invention relates to intrinsically electrically conductive polymers, preferably oligomers, which, in the oxidized form, are completely soluble in dipolar aprotic solvents at room temperature and which contain structural units which are derived from at least one monomer of the formula (I) ##STR1## in which R.sup.1 is a C.sub.1 -C.sub.2 -alkoxy group or --O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.3 with n=1 to 4 and R.sup.2 is a hydrogen atom, a C.sub.1 -C.sub.12 -alkyl group, a C.sub.1 -C.sub.12 -alkoxy group or --O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.3 with n=1 to 4, or R.sup.1 and R.sup.2 together are --O(CH.sub.2).sub.m --CH.sub.2 or --O(CH.sub.2).sub.m --O-- with m=1 to 12. The invention also relates to a process for the preparation of these polymers by electrochemical polymerization of at least one monomer of this formula (I) in the presence of a conductive salt, the anode having a specific surface area of at least 0.01 m.sup.2 /g and preferably a gauze, sponge, fabric or felt structure, the electrolyte solvent being dipolar and aprotic and the electrolyte system being moved only slightly or not at all relative to the anode. The polymers according to the invention can readily be used especially for coating purposes.

    摘要翻译： 本发明涉及本征导电聚合物，优选低聚物，其以氧化形式在室温下完全溶于偶极非质子溶剂中，并且其含有衍生自式（I）的至少一种单体的结构单元

    Electrically conducting polymers and their preparation
    2.
    发明授权
    Electrically conducting polymers and their preparation 失效
    电导体聚合物及其制备

    公开(公告)号：US5225109A

    公开(公告)日：1993-07-06

    申请号：US308882

    申请日：1989-02-09

    申请人： Michael Feldhues ,  Gunther Kampf

    发明人： Michael Feldhues ,  Gunther Kampf

    IPC分类号： C08G61/10 ,  C08G61/12 ,  C09D5/00 ,  C09D5/24 ,  C09D5/30 ,  D06M15/21 ,  H01B1/12

    CPC分类号： C08G61/126 ,  H01B1/127

    摘要： The invention relates to electrically conducting polymers which are obtainable as self-supporting films or composite bodies and which contain structural units which are derived from at least one monomer of the formula (I) ##STR1## wherein R.sup.1 represents a C.sub.1 -C.sub.12 -alkoxy group and R.sup.2 represents a C.sub.1 -C.sub.12 -alkyl group. The invention furthermore relates to a process for preparing said polymers by oxidative polymerization of at least one monomer of said formula (I). The polymers according to the invention may be used, in particular, for applications for which high chemical, mechanical or thermal stability simultaneously accompanied by high electrical conductivity is necessary and of advantage.

    摘要翻译： 本发明涉及可作为自支撑膜或复合体获得并且含有由至少一种式（I）单体衍生的结构单元的导电聚合物，其中R1表示C1-C12 - 烷氧基，R2表示C1-C12-烷基。 本发明还涉及通过至少一种所述式（I）单体的氧化聚合制备所述聚合物的方法。 根据本发明的聚合物可以特别用于同时具有高电导率的高化学，机械或热稳定性以及有利的应用。

    Process for modifying electroconductive polymers using ion exchange
    4.
    发明授权
    Process for modifying electroconductive polymers using ion exchange 失效
    使用离子交换改性导电聚合物的方法

    公开(公告)号：US5066731A

    公开(公告)日：1991-11-19

    申请号：US517924

    申请日：1990-05-02

    申请人： Michael Feldhues ,  Gunther Kampf ,  Thomas Mecklenburg

    发明人： Michael Feldhues ,  Gunther Kampf ,  Thomas Mecklenburg

    IPC分类号： C08G61/12 ,  H01B1/12

    CPC分类号： H01B1/127 ,  C08G61/126

    摘要： In electrically conducting polymers in their oxidized (doped) form, which are known per se, the anions can be exchanged in any desired manner, if the polymer in solution is brought into contact with a salt containing the anion to be exchanged and the solution equilibrium is established, taking account of the solubility product of the salts present. In this manner, the properties of the electrically conducting polymers can be adapted to different purposes.

    摘要翻译： 在本身已知的氧化（掺杂）形式的导电聚合物中，如果将溶液中的聚合物与含有待交换阴离子的盐和溶液平衡接触，则阴离子可以以任何所需的方式进行交换 考虑到存在的盐的溶解度积，成立。 以这种方式，导电聚合物的性质可以适应于不同的目的。

    Electrochemical process for the production of electrically conducting poly(alkoxythiophenes) with carboxylic acids added
    8.
    发明授权
    Electrochemical process for the production of electrically conducting poly(alkoxythiophenes) with carboxylic acids added 失效
    生产带有羧基酸的电导体聚（烷氧基聚氧乙烯）的电化学工艺

    公开(公告)号：US5098529A

    公开(公告)日：1992-03-24

    申请号：US577927

    申请日：1990-09-05

    申请人： Michael Feldhues

    发明人： Michael Feldhues

    IPC分类号： C07D333/06 ,  C08G61/10 ,  C08G61/12 ,  C09K3/16 ,  C25B3/00 ,  H01B1/12

    CPC分类号： C08G61/126 ,  H01B1/127

    摘要： Electrochemical process for the production of electrically conducting poly(alkoxythiophenes) with carboxylic acids added.Poly(alkoxythiophenes) are of great interest as electrically conducting polymers as a result of their high stability towards air and water and as a result of their good temperature resistance.Suitable for the production of such polymers on an industrial scale is an electrochemical process for the production of electrically conducting poly(alkoxythiophenes) in which the protons needed for the cathode process are made available by adding carboxylic acids to conducting salt and electrolyte solvent. The counterions in the doped polymer originate from the conducting salt, with the result that the properties of the polymer are substantially independent of the proton source.

    摘要翻译： 用加入羧酸生产导电聚（烷氧基噻吩）的电化学工艺。 作为导电聚合物由于其对空气和水的高稳定性以及由于它们具有良好的耐温性而导致的聚（烷氧基噻吩）是非常有意义的。 适用于在工业规模生产这种聚合物的电化学方法是用于生产导电的聚（烷氧基噻吩）的电化学方法，其中通过向导电盐和电解质溶剂中加入羧酸使阴极工艺所需的质子得到。 掺杂聚合物中的抗衡离子源自导电盐，结果聚合物的性质基本上与质子源无关。