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    High impact resistant blends of thermoplastic polyamides and modified block copolymers
    5.
    发明授权
    High impact resistant blends of thermoplastic polyamides and modified block copolymers 失效
    热塑性聚酰胺和改性嵌段共聚物的高抗冲击混合物

    公开(公告)号：US5506299A

    公开(公告)日：1996-04-09

    申请号：US262192

    申请日：1994-06-20

    申请人： Richard Gelles ,  William P. Gergen ,  Robert G. Lutz ,  Michael J. Modic

    发明人： Richard Gelles ,  William P. Gergen ,  Robert G. Lutz ,  Michael J. Modic

    IPC分类号： C08L67/02 ,  C08L77/00

    CPC分类号： C08L67/02 ,  C08L77/00

    摘要： A super-toughened multiphase thermoplastic composition is provided by combining at least one modified selectively hydrogenated conjugated diene/alkenyl arene block copolymer to which has been grafted an effective amount of succinic groups primarily in the selectively hydrogenated conjugated diene blocks thereof and optionally at least one unmodified selectively hydrogenated conjugated diene/alkenyl arene block copolymer with at least one .alpha.,.omega.-polyamide.

    摘要翻译： 通过组合至少一种改性的选择性氢化的共轭二烯/烯基芳烃嵌段共聚物来提供超级增韧的多相热塑性组合物，其中主要在其选择性氢化的共轭二烯嵌段中接枝有效量的琥珀酸基团，以及任选的至少一种未改性的 选择性氢化共轭二烯/烯基芳烃嵌段共聚物与至少一种α，ω-聚酰胺。

    High impact resistant blends of thermoplastic polyamides and modified block copolymers
    6.
    发明授权
    High impact resistant blends of thermoplastic polyamides and modified block copolymers 失效
    热塑性聚酰胺和改性嵌段共聚物的高抗冲击混合物

    公开(公告)号：US5371141A

    公开(公告)日：1994-12-06

    申请号：US863370

    申请日：1992-04-02

    申请人： Richard Gelles ,  William P. Gergen ,  Robert G. Lutz ,  Michael J. Modic

    发明人： Richard Gelles ,  William P. Gergen ,  Robert G. Lutz ,  Michael J. Modic

    IPC分类号： C08L67/02 ,  C08L77/00

    CPC分类号： C08L67/02 ,  C08L77/00

    摘要： A super-toughened multiphase thermoplastic composition is provided by combining at least one modified selectively hydrogenated conjugated diene/alkenyl arene block copolymer to which has been grafted an effective amount of succinic groups primarily in the selectively hydrogenated conjugated diene blocks thereof and optionally at least one unmodified selectively hydrogenated conjugated diene/alkenyl arene block copolymer with at least one .alpha.,.omega.-polyamide.

    摘要翻译： 通过组合至少一种改性的选择性氢化的共轭二烯/烯基芳烃嵌段共聚物来提供超级增韧的多相热塑性组合物，其中主要在其选择性氢化的共轭二烯嵌段中接枝有效量的琥珀酸基团，以及任选的至少一种未改性的 选择性氢化共轭二烯/烯基芳烃嵌段共聚物与至少一种α，ω-聚酰胺。

    High impact resistant blends of thermoplastic polyesters and modified block copolymers
    8.
    发明授权
    High impact resistant blends of thermoplastic polyesters and modified block copolymers 失效
    热塑性聚酯和改性嵌段共聚物的高抗冲击混合物

    公开(公告)号：US4868243A

    公开(公告)日：1989-09-19

    申请号：US152706

    申请日：1988-02-05

    申请人： Richard Gelles ,  Carl L. Willis ,  Michael J. Modic

    发明人： Richard Gelles ,  Carl L. Willis ,  Michael J. Modic

    IPC分类号： C08L67/02

    CPC分类号： C08L67/02

    摘要： A suber-toughened multiphase thermoplastic composition is provided by incorporating an effective amount of at least one functionalized, selectively hydrogenated alkenyl arene/conjugated diene block copolymer to which has been grafted an effective amount of carboxyl functional groups primarily in the alkenyl arene blocks thereof with poly (ethylene terephthalate). The carboxyl functional groups are present as carboxylic acids and their salts in an effective salt to acid ratio for super-toughening the composition. Additionally, the block copolymer phase has an effective phase size for super-toughening the composition.

    摘要翻译： 通过加入有效量的至少一种官能化的选择性氢化的烯基芳烃/共轭二烯嵌段共聚物来提供旭格增韧的多相热塑性组合物，其中已经有效量的羧基官能团主要在其烯基芳烃嵌段中与聚 （对苯二甲酸乙二醇酯）。 羧基官能团作为羧酸及其盐以有效的盐与酸的比例存在，用于超级组合物的增韧。 此外，嵌段共聚物相具有用于超增韧组合物的有效相尺寸。

    Polymeric composition
    9.
    发明授权
    Polymeric composition 失效
    聚合物组成

    公开(公告)号：US4859737A

    公开(公告)日：1989-08-22

    申请号：US124644

    申请日：1987-11-24

    申请人： Michael J. Modic ,  Richard Gelles

    发明人： Michael J. Modic ,  Richard Gelles

    IPC分类号： C08L67/02

    CPC分类号： C08L67/02

    摘要： A polyester resin composition comprising a poly(alkylene terephthalate), said alkylene radical containing at least 3 carbon atoms, a carboxylated hydrogenated or selectively hydrogenated conjugated diolefin polymer and a transesterification catalyst. It has surprisingly been discovered that when a transesterification catalyst such as p-toluene sulfonic acid is present at a concentration within the range from about 1 mmoles to about 5 mmoles per 100 g of combined polyester and carboxylated, hydrogenated or selectively hydrogenated conjugated diolefin polymer, a significant improvement in impact strength is realized. Inclusion of a transesterification catalyst in the composition, then, enables significant improvement in impact strength even when the carboxylated, hydrogenated or selectively hydrogenated conjugated diolefin polymer is present in the composition at a concentration as low as 17 parts, by weight, per 100 parts, by weight, of polyester. The poly(alkylene terephthalate) is preferably poly(butylene terephthalate). The carboxylated, hydrogenated or selectively hydrogenated conjugated diolefin polymer is preferably an unsaturated block copolymer comprising at least one polymeric block containing predominantly monoalkenyl aromatic hydrocarbon monomer units and at least one polymeric block containing predominantly conjugated diolefin monomer units. Most preferably, the carboxylated elastomeric polymer is a maleated, selectively hydrogenated styrene-butadiene-styrene triblock copolymer.

    摘要翻译： 包含聚（对苯二甲酸亚烷基酯），所述含有至少3个碳原子的亚烷基，羧化氢化或选择性氢化的共轭二烯烃聚合物和酯交换催化剂的聚酯树脂组合物。 令人惊讶地发现，当酯交换催化剂如对甲苯磺酸的存在浓度范围为每100克组合的聚酯和羧化，氢化或选择性氢化的共轭二烯烃聚合物约1毫摩尔至约5毫摩尔时， 实现了冲击强度的显着提高。 即使当组合物中存在羧基化，氢化或选择性氢化的共轭二烯烃聚合物的浓度低于每100份重量的17份（重量）时，包含酯基转移催化剂在组合物中也能显着改善冲击强度， 的聚酯。 聚对苯二甲酸亚烷基酯优选为聚（对苯二甲酸丁二醇酯）。 羧化，氢化或选择性氢化的共轭二烯烃聚合物优选是包含至少一个主要含有单链烯基芳族烃单体单元的聚合嵌段和至少一个含有主要共轭的二烯烃单体单元的聚合嵌段的不饱和嵌段共聚物。 最优选地，羧化的弹性体聚合物是马来酸化的，选择性氢化的苯乙烯 - 丁二烯 - 苯乙烯三嵌段共聚物。

    Process for producing high diblock content block copolymer compositions
    10.
    发明授权
    Process for producing high diblock content block copolymer compositions 失效
    制备高二嵌段含量嵌段共聚物组合物的方法

    公开(公告)号：US5420203A

    公开(公告)日：1995-05-30

    申请号：US245097

    申请日：1994-05-17

    申请人： Steven H. Dillman ,  David J. St. Clair ,  Mark A. Berggren ,  Michael J. Modic

    发明人： Steven H. Dillman ,  David J. St. Clair ,  Mark A. Berggren ,  Michael J. Modic

    IPC分类号： C08F297/04 ,  C09J153/02 ,  C08L53/02

    CPC分类号： C08F297/044 ,  C09J153/02

    摘要： The present invention is a process for producing high diblock content block copolymer compositions which comprises (a) anionically polymerizing at least one vinyl aromatic hydrocarbon and at least one conjugated diene to form a living block copolymer, (b) coupling the block copolymer with a coupling agent selected from the group consisting of esters of carboxylic acids and asymmetric silanes to create a coupled polymer, (c) combining the coupled polymer with other components to form an enduse composition, and (d) heating the composition at a temperature up to 130.degree. C. for a time sufficient to decouple the coupled copolymer such that the amount of uncoupled copolymer in the composition ranges from 10 to 100% by weight of the total amount of block copolymer.

    摘要翻译： 本发明是一种制备高二嵌段含量嵌段共聚物组合物的方法，其包括（a）阴离子聚合至少一种乙烯基芳族烃和至少一种共轭二烯以形成活性嵌段共聚物，（b）将嵌段共聚物与偶联剂 选自羧酸和不对称硅烷的酯的试剂以产生偶联的聚合物，（c）将偶联的聚合物与其它组分组合以形成末端组合物，和（d）在高达130℃的温度下加热组合物 C.足够的时间使得偶联的共聚物分离，使得组合物中非偶联共聚物的量为嵌段共聚物总量的10-100重量％。