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    Processes for producing polyurethane foams containing alkoxysilane functional polymers and uses therefor
    3.
    发明授权
    Processes for producing polyurethane foams containing alkoxysilane functional polymers and uses therefor 有权
    制造含有烷氧基硅烷官能聚合物的聚氨酯泡沫的方法及其用途

    公开(公告)号：US08846775B2

    公开(公告)日：2014-09-30

    申请号：US12170522

    申请日：2008-07-10

    申请人： Michael Mager ,  Michael Ludewig ,  Mathias Matner

    发明人： Michael Mager ,  Michael Ludewig ,  Mathias Matner

    IPC分类号： C08G18/08 ,  C08G18/48 ,  C08G18/71 ,  C08K5/00 ,  C08L83/00 ,  C08G101/00 ,  C08K3/00 ,  C08K5/5465

    CPC分类号： C08G18/718 ,  C08G18/4837 ,  C08G2101/00 ,  C08K3/013 ,  C08K5/0016 ,  C08K5/5465 ,  C08L83/00

    摘要： Processes comprising: (a) providing a composition comprising at least one silane-terminated polyurethane preploymer prepared by a process comprising: reacting (A) at least one polyether having a number average molecular weight (Mn) of 2000 to 8000 g/mol, and comprising 10 to 30 wt % ethylene oxide units based on all alkylene oxide units in the polyether; with (B) at least one isocyanate and alkoxysilane group-containing compound of the formula (I): wherein each of X, Y, and Z independently represents a C1-C8 alkyl or a C1-C8 alkoxy residue, with the proviso that at least one of X, Y, and Z represents a C1-C8 alkoxy group; and wherein R is an at least bifunctional, organic residue; (b) foaming the composition, and (c) curing the foamed composition in the presence of water; and uses of polyurethane foams prepared thereby.

    摘要翻译： 方法包括：（a）提供包含至少一种通过包括以下方法制备的硅烷封端的聚氨酯预聚合物的组合物：（A）至少一种数均分子量（Mn）为2000至8000g / mol的聚醚和 包含基于聚醚中所有烯化氧单元的10至30重量％的环氧乙烷单元; 与（B）至少一种式（I）的异氰酸酯和烷氧基硅烷基化合物：其中X，Y和Z各自独立地表示C1-C8烷基或C1-C8烷氧基残基，条件是在 X，Y和Z中的至少一个表示C1-C8烷氧基; 并且其中R是至少双官能的有机残基; （b）使组合物发泡，和（c）在水存在下使发泡组合物固化; 以及由此制备的聚氨酯泡沫的用途。

    PROCESSES FOR PRODUCING POLYURETHANE FOAMS CONTAINING ALKOXYSILANE FUNCTIONAL POLYMERS AND USES THEREFOR
    4.
    发明申请
    PROCESSES FOR PRODUCING POLYURETHANE FOAMS CONTAINING ALKOXYSILANE FUNCTIONAL POLYMERS AND USES THEREFOR 有权
    生产含有烷氧基官能聚合物的聚氨酯泡沫体的方法及其用途

    公开(公告)号：US20090018228A1

    公开(公告)日：2009-01-15

    申请号：US12170522

    申请日：2008-07-10

    申请人： Michael Mager ,  Michael Ludewig ,  Mathias Matner

    发明人： Michael Mager ,  Michael Ludewig ,  Mathias Matner

    IPC分类号： C08J9/228

    CPC分类号： C08G18/718 ,  C08G18/4837 ,  C08G2101/00 ,  C08K3/013 ,  C08K5/0016 ,  C08K5/5465 ,  C08L83/00

    摘要： Processes comprising: (a) providing a composition comprising at least one silane-terminated polyurethane preploymer prepared by a process comprising: reacting (A) at least one polyether having a number average molecular weight (Mn) of 2000 to 8000 g/mol, and comprising 10 to 30 wt % ethylene oxide units based on all alkylene oxide units in the polyether; with (B) at least one isocyanate and alkoxysilane group-containing compound of the formula (I): wherein each of X, Y, and Z independently represents a C1-C8 alkyl or a C1-C8 alkoxy residue, with the proviso that at least one of X, Y, and Z represents a C1-C8 alkoxy group; and wherein R is an at least bifunctional, organic residue; (b) foaming the composition, and (c) curing the foamed composition in the presence of water; and uses of polyurethane foams prepared thereby.

    摘要翻译： 方法包括：（a）提供包含至少一种通过包括以下方法制备的硅烷封端的聚氨酯预聚合物的组合物：（A）至少一种数均分子量（Mn）为2000至8000g / mol的聚醚和 包含基于聚醚中所有烯化氧单元的10至30重量％的环氧乙烷单元; 与（B）至少一种式（I）的异氰酸酯和烷氧基硅烷基化合物：其中X，Y和Z各自独立地表示C1-C8烷基或C1-C8烷氧基残基，条件是在 X，Y和Z中的至少一个表示C1-C8烷氧基; 并且其中R是至少双官能的有机残基; （b）使组合物发泡，和（c）在水存在下使发泡组合物固化; 以及由此制备的聚氨酯泡沫的用途。

    POLYESTER PREPOLYMERS
    5.
    发明申请
    POLYESTER PREPOLYMERS 有权
    聚酯预处理剂

    公开(公告)号：US20110130512A1

    公开(公告)日：2011-06-02

    申请号：US13023924

    申请日：2011-02-09

    申请人： Michael Ludewig ,  Mathias Matner

    发明人： Michael Ludewig ,  Mathias Matner

    IPC分类号： C08G18/00 ,  C08L83/04

    CPC分类号： C09J175/06 ,  C08G18/10 ,  C08G18/3821 ,  C08G18/4241 ,  C08G18/718 ,  C08G18/289

    摘要： The invention relates to prepolymers containing alkoxysilane groups based on special, low-viscosity polyester polyols, which exhibit particularly high tensile strength, a process for the production thereof and their use as a binder for adhesives, primers or coatings.

    摘要翻译： 本发明涉及含有基于特殊的低粘度聚酯多元醇的烷氧基硅烷基团的预聚物，其具有特别高的拉伸强度，其制备方法以及它们作为粘合剂，底漆或涂料粘合剂的用途。

    Polyurethane prepolymers containing alkoxysilane groups and allophanate and/or biuret groups
    6.
    发明申请
    Polyurethane prepolymers containing alkoxysilane groups and allophanate and/or biuret groups 有权
    含有烷氧基硅烷基团和脲基甲酸酯和/或缩二脲基团的聚氨酯预聚物

    公开(公告)号：US20070055010A1

    公开(公告)日：2007-03-08

    申请号：US11513000

    申请日：2006-08-30

    申请人： Michael Ludewig ,  Mathias Matner

    发明人： Michael Ludewig ,  Mathias Matner

    IPC分类号： C08G18/08

    CPC分类号： C08G18/10 ,  C08G18/222 ,  C08G18/4866 ,  C08G18/755 ,  C08G18/71 ,  C08G18/282 ,  C08G18/718 ,  C08G18/289

    摘要： The present invention relates to modified alkoxysilane-functional polyurethanes containing allophanate and/or biuret groups, wherein at least 10 mol % of the allophanate and/or biuret groups are formed from a monoisocyanate of the formula R-NCO, wherein R is an optionally heteroatom-containing alkyl, aralkyl or aryl radical having up to 20 carbon atoms, provided that these radicals do not contain any other reactive groups with the exception of the NCO group that is part of the allophanate structure and any alkoxysilyl groups present. The present invention also relates to a process for preparing alkoxysilane-functional prepolymers by A) reacting some or all of the urethane groups and/or urea groups of alkoxysilane-functional polyurethane prepolymers with monoisocyanates of the formula, R-NCO to form allophanate groups and/or biuret groups, or B) reacting some or all urethane groups and/or urea groups of alkoxysilyl-free polyurethane prepolymers with monoisocyanates of the formula R-NCO to form allophanate groups and/or biuret groups, the radical R having at least one alkoxysilyl group. The present invention further relates to sealants, adhesives, primers and coatings based on the polyurethane prepolymers of the invention.

    摘要翻译： 本发明涉及含有脲基甲酸酯和/或缩二脲基团的改性烷氧基硅烷官能的聚氨酯，其中至少10摩尔％的脲基甲酸酯和/或缩二脲基团由式R-NCO的单异氰酸酯形成，其中R是任选的杂原子 包含具有至多20个碳原子的烷基，芳烷基或芳基，条件是除了作为脲基甲酸酯结构和任何烷氧基甲硅烷基的一部分的NCO基除外，这些基团不含任何其它反应性基团。 本发明还涉及通过以下步骤制备烷氧基硅烷官能预聚物的方法：A）使烷氧基硅烷官能的聚氨酯预聚物的一些或全部氨基甲酸酯基和/或脲基与式R-NCO的单异氰酸酯反应形成脲基甲酸酯基， 或/或缩二脲基团，或B）使不含烷氧基甲硅烷基的聚氨酯预聚物的一些或所有氨基甲酸酯基团和/或脲基团与式R-NCO的单异氰酸酯反应以形成脲基甲酸酯基团和/或缩二脲基团，所述基团R具有至少一个 烷氧基甲硅烷基。 本发明还涉及基于本发明的聚氨酯预聚物的密封剂，粘合剂，底漆和涂料。

    Low viscosity, alkoxysilane-functional prepolymers and a process for their preparation
    7.
    发明申请
    Low viscosity, alkoxysilane-functional prepolymers and a process for their preparation 有权
    低粘度烷氧基硅烷功能预聚物及其制备方法

    公开(公告)号：US20070055035A1

    公开(公告)日：2007-03-08

    申请号：US11512487

    申请日：2006-08-30

    申请人： Michael Ludewig ,  Mathias Matner ,  Frank Kobelka

    发明人： Michael Ludewig ,  Mathias Matner ,  Frank Kobelka

    IPC分类号： C08L83/04 ,  C08G77/06 ,  C08G77/04 ,  B32B27/00

    CPC分类号： C08G18/718 ,  C08G18/4825 ,  C08G2190/00

    摘要： The present invention relates to a process for preparing alkoxysilane-functional prepolymers by reacting A) 1.0 equivalent of a polyol component have a number average molecular weight of 3000 g/mol to 20,000 g/mol and containing one or more polyQxyalkylene polyols or polyoxyalkylene polyol prepolymers with B) 1.05 to 1.50 equivalent of an isocyanate-and alkoxysilane-functional compound of formula I) wherein X, Y, and Z independently of one another are linear or branched C1-C8 alkyl or C1-C8 alkoxy radicals, wherein at least one of the radicals is a C1-C8 alkoxy group and R is an organic radical having a functionality of at least two, and subsequently further reacting the remaining free NCO groups by allophanatization or by reaction with C) an isocyanate-reactive component. The present invention also relates to the alkoxysilane-functional prepolymers obtained by the process of the invention.

    摘要翻译： 本发明涉及通过使A）1.0当量的多元醇组分的数均分子量为3000g / mol至20,000g / mol并含有一种或多种聚亚烷基多元醇或聚氧化烯多元醇预聚物来制备烷氧基硅烷官能预聚物的方法 其中B）1.05至1.50当量的式I）的异氰酸酯和烷氧基硅烷官能化合物，其中X，Y和Z彼此独立地为直链或支链C 1 -C 8 C 1 -C 12烷基或C 1 -C 8烷氧基，其中至少一个基团是C 1 -C 3亚烷基 > 8个烷氧基，R是官能度至少为2的有机基团，随后通过醛基化反应或通过与C）异氰酸酯反应性组分的反应进一步使剩余的游离NCO基团反应。 本发明还涉及通过本发明的方法获得的烷氧基硅烷官能的预聚物。

    Polyurethane prepolymers containing alkoxysilane groups and allophanate and/or biuret groups
    9.
    发明授权
    Polyurethane prepolymers containing alkoxysilane groups and allophanate and/or biuret groups 有权
    含有烷氧基硅烷基团和脲基甲酸酯和/或缩二脲基团的聚氨酯预聚物

    公开(公告)号：US07812087B2

    公开(公告)日：2010-10-12

    申请号：US11513000

    申请日：2006-08-30

    申请人： Michael Ludewig ,  Mathias Matner

    发明人： Michael Ludewig ,  Mathias Matner

    IPC分类号： C08G18/08

    CPC分类号： C08G18/10 ,  C08G18/222 ,  C08G18/4866 ,  C08G18/755 ,  C08G18/71 ,  C08G18/282 ,  C08G18/718 ,  C08G18/289

    摘要： The present invention relates to modified alkoxysilane-functional polyurethanes containing allophanate and/or biuret groups, wherein at least 10 mol % of the allophanate and/or biuret groups are formed from a monoisocyanate of the formula R—NCO, wherein R is an optionally heteroatom-containing alkyl, aralkyl or aryl radical having up to 20 carbon atoms, provided that these radicals do not contain any other reactive groups with the exception of the NCO group that is part of the allophanate structure and any alkoxysilyl groups present. The present invention also relates to a process for preparing alkoxysilane-functional prepolymers by A) reacting some or all of the urethane groups and/or urea groups of alkoxysilane-functional polyurethane prepolymers with monoisocyanates of the formula, R—NCO to form allophanate groups and/or biuret groups, or B) reacting some or all urethane groups and/or urea groups of alkoxysilyl-free polyurethane prepolymers with monoisocyanates of the formula R—NCO to form allophanate groups and/or biuret groups, the radical R having at least one alkoxysilyl group. The present invention further relates to sealants, adhesives, primers and coatings based on the polyurethane prepolymers of the invention.

    摘要翻译： 本发明涉及含有脲基甲酸酯和/或缩二脲基团的改性烷氧基硅烷官能的聚氨酯，其中至少10摩尔％的脲基甲酸酯和/或缩二脲基团由式R-NCO的单异氰酸酯形成，其中R是任选的杂原子 包含具有至多20个碳原子的烷基，芳烷基或芳基，条件是除了作为脲基甲酸酯结构和任何烷氧基甲硅烷基的一部分的NCO基除外，这些基团不含任何其它反应性基团。 本发明还涉及通过以下步骤制备烷氧基硅烷官能预聚物的方法：A）使烷氧基硅烷官能的聚氨酯预聚物的一些或全部氨基甲酸酯基和/或脲基与式R-NCO的单异氰酸酯反应形成脲基甲酸酯基， 或/或缩二脲基团，或B）使不含烷氧基甲硅烷基的聚氨酯预聚物的一些或所有氨基甲酸酯基团和/或脲基团与式R-NCO的单异氰酸酯反应以形成脲基甲酸酯基团和/或缩二脲基团，所述基团R具有至少一个 烷氧基甲硅烷基。 本发明还涉及基于本发明的聚氨酯预聚物的密封剂，粘合剂，底漆和涂料。

    Polyurethane prepolymers with reduced functionality having terminal alkoxysilane and OH groups, a method of preparing them and their use
    10.
    发明授权
    Polyurethane prepolymers with reduced functionality having terminal alkoxysilane and OH groups, a method of preparing them and their use 失效
    具有缩合官能度的聚氨酯预聚物具有末端烷氧基硅烷和OH基团，其制备方法及其应用

    公开(公告)号：US06762270B2

    公开(公告)日：2004-07-13

    申请号：US10357002

    申请日：2003-02-03

    申请人： Michael Ludewig ,  Mathias Matner ,  Stefan Groth ,  Gerhard Ruttmann

    发明人： Michael Ludewig ,  Mathias Matner ,  Stefan Groth ,  Gerhard Ruttmann

    IPC分类号： C08G7726

    CPC分类号： C09K3/1021 ,  C08G18/10 ,  C08G18/289

    摘要： The present invention relates to polyurethane prepolymer having terminal alkoxysilane and OH groups which is the reaction product of A) a polyurethane prepolymer prepared by incomplete reaction of i) an aromatic, aliphatic or cycloaliphatic diisocyanate component having an NCO content of 20 to 60% by weight with ii) a polyol component comprising a polyoxyalkylene diol having a number average molecular weight of 3000 to 20,000, wherein the reaction is stopped after 50 to 90% of the OH groups of component ii) are reacted and 10 to 50% are unreacted, with B) a compound having alkoxysilane and amino groups, preferably a compound containing alkoxysilane and aspartate groups. The present invention also relates to a process for preparing these polyurethane prepolymers containing terminal alkoxysilane and OH groups and to isocyanate-free, sealants, adhesives, primers and coatings containing these polyurethane prepolymers containing terminal alkoxysilane and OH groups as binders.

    摘要翻译： 本发明涉及具有末端烷氧基硅烷和OH基团的聚氨酯预聚物，其是A）由NCO含量为20〜60重量％的芳香族，脂肪族或脂环族二异氰酸酯成分的不完全反应制备的聚氨酯预聚物，ii） 包含数均分子量为3000〜20,000的聚氧化亚烷基二醇的多元醇成分，其中在组分ⅱ）的50〜90％的OH基反应10〜50％后，反应停止，B）化合物 具有烷氧基硅烷和氨基，优选含有烷氧基硅烷和天冬氨酸基团的化合物。本发明还涉及一种制备这些含有末端烷氧基硅烷和OH基团的聚氨酯预聚物和不含异氰酸酯的密封剂，粘合剂，底漆和含有这些聚氨酯的涂料的方法 含有末端烷氧基硅烷和OH基作为粘合剂的预聚物。