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公开(公告)号：US20110081492A1
公开(公告)日：2011-04-07
申请号：US12573369
申请日：2009-10-05
IPC分类号： B05D3/10
CPC分类号： B05D3/046 , A63B37/0023 , A63B45/00 , B05D3/108 , B05D2201/00 , B05D2503/00 , C08G18/10 , C08G18/4854 , C08G18/758 , C08G18/3863
摘要： Multi-piece, solid golf balls having a cover material made from a polyurethane/urea hybrid composition are provided. The balls include an inner core preferably made of polybutadiene and may include at least one intermediate layer disposed between the core and outer cover. The cover materials are prepared by first forming a polyurethane prepolymer which undergoes two curing steps. In the first step, the prepolymer is chemically-cured by reacting it with hydroxyl curing agents, amine curing agents, or mixtures thereof. In the second step, the composition is moisture-cured. The cured material may be used to make a golf ball cover having improved durability, cut/tear resistance, and impact strength.
摘要翻译： 提供具有由聚氨酯/尿素混合组合物制成的覆盖材料的多片固体高尔夫球。 球包括优选由聚丁二烯制成的内芯，并且可以包括设置在芯和外盖之间的至少一个中间层。 覆盖材料通过首先形成经历两个固化步骤的聚氨酯预聚物来制备。 在第一步中，预聚物通过与羟基固化剂，胺固化剂或其混合物反应而化学固化。 在第二步中，组合物湿润。 固化材料可以用于制造具有改善的耐久性，耐撕裂性和冲击强度的高尔夫球罩。
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公开(公告)号：US20110081497A1
公开(公告)日：2011-04-07
申请号：US12573349
申请日：2009-10-05
IPC分类号： B05D3/10
CPC分类号： B05D3/046 , A63B37/0024 , A63B45/00 , B05D3/108 , B05D2201/00 , B05D2503/00 , C08G18/10 , C08G18/4854 , C08G18/758 , C08G18/324
摘要： Multi-piece, solid golf balls having a cover material made from a polyurea or polyurea/urethane hybrid composition are provided. The cover materials are prepared by first forming a polyurea prepolymer which undergoes two curing steps. In the first step, the prepolymer is chemically-cured by reacting it with hydroxyl curing agents, amine curing agents, or mixtures thereof. In the second step, the composition is moisture-cured. The cured material may be used to make a golf ball cover having improved durability, cut/tear resistance, and impact strength.
摘要翻译： 提供具有由聚脲或聚脲/聚氨酯混合组合物制成的覆盖材料的多片固体高尔夫球。 覆盖材料通过首先形成经历两个固化步骤的聚脲预聚物来制备。 在第一步中，预聚物通过与羟基固化剂，胺固化剂或其混合物反应而化学固化。 在第二步中，组合物湿润。 固化材料可以用于制造具有改善的耐久性，耐撕裂性和冲击强度的高尔夫球罩。
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公开(公告)号：US08487063B2
公开(公告)日：2013-07-16
申请号：US12975491
申请日：2010-12-22
CPC分类号： A63B37/0027 , A63B37/0075 , C08G18/10 , C08G18/721 , C08G18/722 , C08G18/792 , C08L75/02 , C08G18/3225 , C08G18/72
摘要： Methods for making polyurea polymer compositions are provided. The methods involve preparing an amine-terminated first prepolymer by reacting isocyanate compound A with a stoichiometric excess of polyamine. The first prepolymer is reacted with a stoichiometric excess of isocyanate compound B to form an isocyanate-terminated second prepolymer. The second prepolymer is reacted with a chain extender. The polymer compositions can be used in different products and are particularly suitable for making golf balls. For example, the polymer compositions can be used to make golf ball covers.
摘要翻译： 提供制备聚脲聚合物组合物的方法。 所述方法包括通过异氰酸酯化合物A与化学计量过量的多胺反应来制备胺封端的第一预聚物。 第一预聚物与化学计量过量的异氰酸酯化合物B反应以形成异氰酸酯封端的第二预聚物。 第二预聚物与扩链剂反应。 聚合物组合物可以用于不同的产品中，特别适用于制造高尔夫球。 例如，聚合物组合物可用于制备高尔夫球罩。
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4.发明申请公开(公告)号：US20120165469A1
公开(公告)日：2012-06-28
申请号：US12975491
申请日：2010-12-22
IPC分类号： C08L75/02
CPC分类号： A63B37/0027 , A63B37/0075 , C08G18/10 , C08G18/721 , C08G18/722 , C08G18/792 , C08L75/02 , C08G18/3225 , C08G18/72
摘要： Methods for making polyurea polymer compositions are provided. The methods involve preparing an amine-terminated first prepolymer by reacting isocyanate compound A with a stoichiometric excess of polyamine. The first prepolymer is reacted with a stoichiometric excess of isocyanate compound B to form an isocyanate-terminated second prepolymer. The second prepolymer is reacted with a chain extender. The polymer compositions can be used in different products and are particularly suitable for making golf balls. For example, the polymer compositions can be used to make golf ball covers.
摘要翻译： 提供制备聚脲聚合物组合物的方法。 所述方法包括通过异氰酸酯化合物A与化学计量过量的多胺反应来制备胺封端的第一预聚物。 第一预聚物与化学计量过量的异氰酸酯化合物B反应以形成异氰酸酯封端的第二预聚物。 第二预聚物与扩链剂反应。 聚合物组合物可以用于不同的产品中，特别适用于制造高尔夫球。 例如，聚合物组合物可用于制备高尔夫球罩。
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公开(公告)号：US08809415B2
公开(公告)日：2014-08-19
申请号：US12187046
申请日：2008-08-06
CPC分类号： A63B37/0044
摘要： Compositions for golf balls that include polyurethane and/or polyurea linkages and that are crosslinked in the soft segments of the polymer backbone to improve the crosslink density and effect a hardness gradient throughout the molded article.
摘要翻译： 用于高尔夫球的组合物包括聚氨酯和/或聚脲键，并且在聚合物骨架的软链段中交联以改善交联密度并影响整个模塑制品的硬度梯度。
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公开(公告)号：US20090286628A1
公开(公告)日：2009-11-19
申请号：US12184502
申请日：2008-08-01
CPC分类号： A63B37/0092 , A63B37/0073 , B29D99/0042 , B29L2022/02 , B29L2031/54 , B29L2031/546
摘要： Golf balls having a hard outer skin produced from a material that includes crosslinks in both the hard and soft segments of the polymer backbone that improve the crosslink density. Compositions formed from polyurethane and/or polyurea prepolymers that are first cured with a curative blend including an isocyanate-reactive component to crosslink the hard segment and then exposed to a free radical initiator and radiation to crosslink the soft segments are used in an outer layer of a golf ball, a unitary golf ball, or other golf ball constructions.
摘要翻译： 由具有改善交联密度的聚合物主链的硬链段和软链段之间交联的材料制成的具有硬外皮的高尔夫球。 由聚氨酯和/或聚脲预聚物形成的组合物首先用包含异氰酸酯反应性组分的固化共混物固化以交联硬链段，然后暴露于自由基引发剂和辐射以交联软链段， 高尔夫球，单一高尔夫球或其他高尔夫球结构。
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7.发明申请GOLF BALLS COMPRISING THERMOPLASTIC OR THERMOSET COMPOSITION HAVING CONTROLLED GEL TIME 审中-公开包含具有控制凝胶时间的热塑性或热固性组合物的高尔夫球公开(公告)号：US20110136587A1
公开(公告)日：2011-06-09
申请号：US13028702
申请日：2011-02-16
CPC分类号： A63B37/0024 , A63B37/0003 , A63B37/02 , A63B37/12
摘要： A golf ball comprising a core and at least one layer disposed about the core, wherein at least one of the core and the layer comprises a thermoplastic or thermoset composition comprising a reaction product of a polyurethane or polyurea prepolymer comprising at least one isocyanate and a curative comprising a blend of at least one aliphatic diamine and at least one polyaspartic ester formed from reactants comprising at least one aliphatic primary polyamine and at least one maleic or fumaric diester, and wherein the thermoplastic or thermoset composition comprises a gel time of about 90 seconds or greater. Also, a golf ball comprising a core and at least one layer disposed about the core wherein at least one of the core and the layer comprises a thermoplastic or thermoset composition T comprising a reaction product of a polyurethane or polyurea prepolymer P comprising at least one isocyanate and a curative C comprising a blend of at least one aliphatic diamine D and at least one polyaspartic ester formed from reactants comprising at least one aliphatic primary polyamine and at least one maleic or fumaric diester, wherein the thermoplastic or thermoset composition T has a gel time X such that X>1.25Y, and wherein Y is the gel time of a thermoplastic or thermoset composition T′ comprising a reaction product of the polyurethane or polyurea prepolymer P and a curative C′ comprising a blend of aliphatic diamine D and a polyaspartic ester consisting of N,N′-diethylmaleate-2-methyl-pentamethylene diamine.
摘要翻译： 一种高尔夫球，包括芯和围绕所述芯设置的至少一层，其中所述芯和所述层中的至少一个包含热塑性或热固性组合物，其包含聚氨酯或聚脲预聚物的反应产物，所述聚氨酯或聚脲预聚物包含至少一种异氰酸酯和固化剂 包括至少一种脂族二胺和至少一种由包含至少一种脂肪族初级多胺和至少一种马来酸或富马酸二酯的反应物形成的聚天冬氨酸酯的共混物，并且其中所述热塑性或热固性组合物包含约90秒的凝胶时间或 更大 此外，高尔夫球包括芯和围绕芯设置的至少一层，其中芯和层中的至少一个包含热塑性或热固性组合物T，其包含聚氨酯或聚脲预聚物P的反应产物，所述聚氨酯或聚脲预聚物P包含至少一种异氰酸酯 和包含至少一种脂族二胺D和至少一种由包含至少一种脂肪族初级多胺和至少一种马来酸或富马酸二酯的反应物形成的聚天冬氨酸酯的共混物的固化剂C，其中热塑性或热固性组合物T具有凝胶时间 X，使得X> 1.25Y，并且其中Y是包含聚氨酯或聚脲预聚物P的反应产物和包含脂族二胺D和聚天冬氨酸酯的共混物的固化剂C'的热塑性或热固性组合物T'的凝胶时间 由N，N'-二乙基马来酸酯-2-甲基 - 戊二胺组成。
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公开(公告)号：US20090286629A1
公开(公告)日：2009-11-19
申请号：US12187046
申请日：2008-08-06
CPC分类号： A63B37/0044
摘要： Compositions for golf balls that include polyurethane and/or polyurea linkages and that are crosslinked in the soft segments of the polymer backbone to improve the crosslink density and effect a hardness gradient throughout the molded article.
摘要翻译： 用于高尔夫球的组合物包括聚氨酯和/或聚脲键，并且在聚合物骨架的软链段中交联以改善交联密度并影响整个模塑制品的硬度梯度。
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9.发明授权公开(公告)号：US08586678B2
公开(公告)日：2013-11-19
申请号：US12910914
申请日：2010-10-25
CPC分类号： A63B37/005 , A63B37/0039 , A63B37/0051 , A63B37/0074 , A63B37/0075 , C08L9/00
摘要： The invention relates to golf ball formulations formed from blends of linear and branched polybutadienes catalyzed with neodymium that have improved properties and processing characteristics. Golf ball components may be formed from the blends to provide high coefficient of restitution.
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公开(公告)号：US08529374B2
公开(公告)日：2013-09-10
申请号：US13117246
申请日：2011-05-27
IPC分类号： A63B37/06
CPC分类号： A63B37/0063 , A63B37/0062 , A63B37/0064 , A63B37/0075 , A63B37/0076 , A63B37/0092
摘要： A golf ball comprising a single layer core and a cover layer disposed about the single layer core, the single layer core being formed from a substantially homogenous formulation and comprising a geometric center and an outer surface, the single layer core further comprising an inner core region disposed about the geometric center, an outer core region adjacent the outer surface, and an intermediate core region disposed between the inner and outer core regions and extending radially from about 8 mm to about 18 mm from the geometric center. The single layer core has first, second and third hardnesses disposed within the inner core region, outer core region, intermediate core region, respectively, wherein the third hardness is greater than the first hardness and the second hardness, and a hardness of the outer surface is substantially the same as or lower than a hardness of the geometric center.
摘要翻译： 一种高尔夫球，包括单层芯和围绕单层芯设置的覆盖层，所述单层芯由基本均匀的制剂形成并且包括几何中心和外表面，所述单层芯还包括内芯区域 围绕所述几何中心设置的外芯区域和邻近所述外表面的外芯区域以及设置在所述内芯区域和所述外芯区域之间并且从所述几何中心从约8mm至约18mm径向延伸的中间芯区域。 单层芯具有分别设置在内芯区域，外芯区域，中间芯区域中的第一，第二和第三硬度，其中第三硬度大于第一硬度和第二硬度，并且外表面的硬度 与几何中心的硬度基本相同或不足。
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