摘要:
An alkylphenol-free colorless liquid copolymeric polyphosphite is described of generic formula: wherein each R1, R2, R3, R4 and R5 can be the same or different and independently selected from the group consisting of C12-20 alkyl, C12-22 alkenyl, C12-40 cycloalkyl, C12-40-cycloalkenyl, C12-20 alkyl glycol ethers and A-OH and B—OH as an end-capping groups; each A and B are different and independently selected from the group consisting of C2-40 alkylene, C7-40 cycloalkylene, C3-20 alkyl glycol ethers, C3-40 alkyl lactone, and —R7—N(R8)—R9—; wherein R7, R8 and R9 are independently selected from the group C1-20 alkyl, C2-22 alkenyl, C6-40 cycloalkyl, C7-40 cycloalkylene and H; m and n are integral values ranging from 1 to 100 inclusive, with the proviso that when —O-A or —O—B are C3-20 alkyl glycol ethers, x or y is an integral value no less than 7; x and y are integral values ranging from 1 to 1,000 wherein x+y sum to at least 3; and further wherein no more than two of R1, R2, R3, R4 and R5 are terminated with an hydroxyl group.
摘要:
The invention relates to liquid polymer additive compositions comprising blends of phosphite esters selected from the group consisting of aryl phosphites, alkyl phosphites, aryl/alkyl phosphites, bisphenol-A phosphites, dialkylene glycol phosphites and polydialkylene glycol phosphites, pentaerythritol phosphites, p-cumyl phenol phosphites with from 50 to 800 ppm inclusive of zinc per 100 parts resin. The stabilizer is used as either a complete or a partial replacement of toxic-metal containing antioxidant stabilizer additives.
摘要:
Various phenol-free phosphites for use in PVC as an alternative to the conventional phenol-containing products phenyl diisodecyl phosphite and diphenyl isodecyl phosphite were tested. These phosphites utilize para-cumyl phenol-based derivatives in order to provide a phenol free derivative of the above mentioned conventional phosphites.
摘要:
The invention relates to a liquid polymer additive composition comprising at least one phosphite ester selected from the group consisting of aryl phosphites, alkyl phosphites, aryl/alkyl phosphites, bisphenol-A phosphites, dialkylene glycol phosphites and polydialkylene glycol phosphites, pentaerythritol phosphites, p-cumyl phenol phosphites and blends thereof and approximately from 50 to 800 ppm inclusive of zinc per 100 parts resin. The stabilizer is used as either a complete or a partial replacement of toxic-metal containing antioxidant stabilizer additives.