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公开(公告)号：US20110196079A1
公开(公告)日：2011-08-11
申请号：US12701121
申请日：2010-02-05
IPC分类号： C08K5/52
摘要： A process to stabilize a polymer is described utilizing the step of adding a phosphite reaction product of a triphenyl phosphite or lower molecular weight trialkyl phosphite (e.g., trimethyl phosphite) or triaryl phosphite, with from approximately 1 to 2 moles of preferably a paracumyl phenol, and with from approximately 1 to 2 moles of at least C12-20 carbon alkyl or C12-20 alkenyl alcohol. In one embodiment of the invention, the phosphite reaction product is formula (I) wherein R1 is independently selected from the group consisting of H and C1-2 alkyls; R2 is independently selected from the group defined previously for R1; x is an integral value ranging from 0 to 4 inclusive; y is an integral value ranging from 0 to 4 inclusive; n is an integral value ranging from 1 to 2; R3 is independently selected from the group consisting of C12-20 alkyl or C12-20 alkenyl; R4 is independently selected from the group consisting of C1-10, alkyl and C9-15 arylalkyl; R5 is independently selected from the group defined previously for R4.
摘要翻译： 使用将亚磷酸三苯酯或低分子量亚磷酸三烷基酯（例如亚磷酸三甲酯）或亚磷酸三芳基酯与亚磷酸酯反应产物加入约1至2摩尔优选对枯基苯酚的步骤来描述稳定聚合物的方法， 和约1-2摩尔的至少C 12-20碳烷基或C 12-20烯基醇。 在本发明的一个实施方案中，亚磷酸酯反应产物是式（I），其中R 1独立地选自H和C 1-2烷基; R2独立地选自以下针对R1定义的基团; x是从0到4的整数值; y是从0到4的整数值; n是从1到2的整数值; R3独立地选自C12-20烷基或C12-20烯基; R 4独立地选自C 1-10，烷基和C 9-15芳烷基; R5独立地选自先前针对R4定义的基团。
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公开(公告)号：US07294684B2
公开(公告)日：2007-11-13
申请号：US11558902
申请日：2006-11-11
IPC分类号： C08G75/14
CPC分类号： C08K5/375 , C08L9/06 , C08L21/00 , C08L23/16 , C08L81/00 , C08L81/04 , C08L2312/00 , C08L2666/14
摘要： The invention relates to a process and composition-of-matter for the preparation of dimeric and polymeric alkylphenol polysulfides based on paracumyl phenol for use in vulcanizable rubbers in which the additive is a dimeric or polymeric alkylphenol polysulfide non-nitrosamine-releasing additive based on paracumyl phenol.
摘要翻译： 本发明涉及用于制备用于可硫化橡胶的基于对枯基苯酚的二聚和聚合烷基酚多硫化物的方法和物质组合物，其中所述添加剂是基于副产物的二聚或聚合烷基酚多硫化物非亚硝胺释放添加剂 苯酚。
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公开(公告)号：US06174125B1
公开(公告)日：2001-01-16
申请号：US09408434
申请日：1999-09-29
IPC分类号： B66F0918
CPC分类号： B66F9/185 , Y10S414/123
摘要： The present invention is directed towards a method for racking or unracking pipe to or from a rack and a device to facilitate the process. The method provides a controllable procedure for inserting or withdrawing the pipe that is less dangerous than prior art methods and does not damage the pipe end. The method entails inserting a pipe gripper having an expansion sleeve into an accessible end of a pipe. The expansion sleeve is forced against an inner wall of the pipe, coupling the pipe gripper to the pipe. Depending upon the application, the pipe is then either pushed fully onto the rack or is pulled partially off the rack. For unracking operations, a crane sling is attached to the partially unracked pipe and the pipe is further manipulated off the rack.
摘要翻译： 本发明涉及一种用于将管道从架子上取出或从机架排出的方法，以及用于促进该过程的装置。 该方法提供了一种用于插入或抽出比现有技术方法危险性较小并且不损坏管端的可控程序。 该方法需要将具有膨胀套筒的管夹将管插入管的可接近端。 膨胀套筒被迫靠在管子的内壁上，将管夹持器连接到管道上。 根据应用情况，管道将被完全推入机架上，或者部分地从机架上拉出。 对于起重作业，起重机吊索连接到部分未开挖的管道上，并且管道进一步从机架上操纵。
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公开(公告)号：US4246369A
公开(公告)日：1981-01-20
申请号：US942931
申请日：1978-09-18
IPC分类号： C08G18/02 , C08G18/62 , C08G18/80 , C08G59/40 , C09D5/44 , C09D175/00 , B05D3/02 , C08G18/32
CPC分类号： C09D175/00 , C08G18/02 , C08G18/62 , C08G18/80 , C08G18/8006 , C08G18/8054 , C08G18/8083 , C08G59/4057 , C09D5/4473 , C08G2150/20 , Y10S524/901
摘要： An ungelled composition of matter comprising a compound containing groups reactive with isocyanate, a compound containing groups reactive with mercaptan, and a carbamothioate curing agent adapted to generate a plurality of curing units upon being subjected to heating above about critical temperature. The generated curing units contain isocyanate groups, mercaptan groups, or combinations thereof. In preferred embodiments of this invention, the ungelled composition is adapted for use in powder coatings, anodic electrocoating, and cathodic electrocoating.
摘要翻译： 一种未凝胶化的组合物，其包含含有与异氰酸酯反应的基团的化合物，含有与硫醇反应的基团的化合物和适于在经受高于约临界温度的加热产生多个固化单元的氨基甲酸酯固化剂。 产生的固化单元含有异氰酸酯基，硫醇基或其组合。 在本发明的优选实施方案中，非凝胶组合物适用于粉末涂料，阳极电泳涂层和阴极电泳涂层。
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5.发明授权Process for electrodeposition of compositions containing carbamothioate curing agents 失效用于电沉积含有氨基硫代硫酸酯固化剂的组合物的方法
公开(公告)号：US4204932A
公开(公告)日：1980-05-27
申请号：US942994
申请日：1978-09-18
CPC分类号： C08G18/8083 , C08G18/02 , C08G18/8006 , C08G18/8054 , C08G59/4057 , C09D5/4473 , C08G2150/20
摘要： An ungelled composition of matter comprising a compound containing groups reactive with isocyanate, a compound containing groups reactive with mercaptan, and a carbamothioate curing agent adapted to generate a plurality of curing units upon being subjected to heating above about critical temperature. The generated curing units contain isocyanate groups, mercaptan groups, or combinations thereof. In preferred embodiments of this invention, the ungelled composition is adapted for use in powder coatings, anodic electrocoating, and cathodic electrocoating.
摘要翻译： 一种未凝胶化的组合物，其包含含有与异氰酸酯反应的基团的化合物，含有与硫醇反应的基团的化合物和适于在经受高于约临界温度的加热产生多个固化单元的氨基甲酸酯固化剂。 产生的固化单元含有异氰酸酯基，硫醇基或其组合。 在本发明的优选实施方案中，非凝胶组合物适用于粉末涂料，阳极电泳涂层和阴极电泳涂层。
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公开(公告)号：US4178326A
公开(公告)日：1979-12-11
申请号：US851085
申请日：1977-11-14
摘要： This invention pertains to low-shrink polyester molding resin mixtures primarily based on a certain low-shrink thermoplastic additive produced by synthesizing the vinyl copolymer thermoplastic additive in a hydroxyl terminated polymeric diluent. The resulting vinyl copolymer is dispersed in the hydroxyl containing polymeric diluent which can be post reacted with isocyanate material to produce a polyurethane-vinyl copolymer thermoplastic additive. This thermoplastic additive can be added directly to the thermosetting polyester polymer and monomer mixture to provide a low-shrink molding resin system.
摘要翻译： 本发明涉及低收缩聚酯模塑树脂混合物，主要基于通过在羟基封端的聚合物稀释剂中合成乙烯基共聚物热塑性添加剂而制备的某些低收缩热塑性添加剂。 所得乙烯基共聚物分散在含羟基的聚合物稀释剂中，其可以与异氰酸酯材料反应以产生聚氨酯 - 乙烯基共聚物热塑性添加剂。 该热塑性添加剂可直接加入到热固性聚酯聚合物和单体混合物中以提供低收缩模塑树脂体系。
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公开(公告)号：US4048257A
公开(公告)日：1977-09-13
申请号：US630757
申请日：1975-11-10
申请人： Donald R. Stevenson
发明人： Donald R. Stevenson
IPC分类号： C08F299/04 , C08G63/52 , C08G63/553 , C08L67/06
CPC分类号： C08G63/52 , C08F299/04 , C08G63/553
摘要： This invention pertains to a pigmentable, low-shrink molding composition based on thermosetting, unsaturated polyester resin in combination with lightly cross-linked polymer particles. The lightly cross-linked polymer particles have a particle size preferably between about 20 microns to 50 microns and can be selected from lightly cross-linked condensation polymers and lightly cross-linked addition polymers. In a preferred aspect of the invention the lightly cross-linked polymer particles contain minor amounts of pendant reactive groups selected from amino and oxirane groups to produce a one-pack stabilized low-shrink molding resin mixture. The pigmentable, low-shrink molding compositions are stabilized dispersions containing pigments dispersed therein in conjunction with thermosetting polyester polymer, monomer, and lightly cross-linked polymer particles as well as fillers to provide a pigmentable low-shrink molding composition which cures to uniformly pigmented low-profiled molded part.
摘要翻译： 本发明涉及基于热固性不饱和聚酯树脂与轻度交联的聚合物颗粒组合的可着色的低收缩模塑组合物。 轻度交联的聚合物颗粒的粒度优选为约20微米至50微米，并且可以选自轻度交联的缩聚物和轻度交联的加成聚合物。 在本发明的优选方面，轻度交联的聚合物颗粒含有少量的选自氨基和环氧乙烷基团的侧链反应性基团，以产生单组分稳定的低收缩模塑树脂混合物。 可着色的低收缩成型组合物是含有分散在其中的颜料与热固性聚酯聚合物，单体和轻度交联的聚合物颗粒以及填料一起的稳定的分散体，以提供可着色均匀着色的低密度低密度成型组合物 - 成型件。
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8.发明申请公开(公告)号：US20140329943A1
公开(公告)日：2014-11-06
申请号：US14332550
申请日：2014-07-16
CPC分类号： C08K5/52 , C08G79/04 , C08K5/524 , C08K2201/014 , C08L85/02
摘要： An alkylphenol-free colorless liquid copolymeric polyphosphite is described of generic formula: wherein each R1, R2, R3, R4 and R5 can be the same or different and independently selected from the group consisting of C12-20 alkyl, C12-22 alkenyl, C12-40 cycloalkyl, C12-40-cycloalkenyl, C12-20 alkyl glycol ethers and A-OH and B—OH as an end-capping groups; each A and B are different and independently selected from the group consisting of C2-40 alkylene, C7-40 cycloalkylene, C3-20 alkyl glycol ethers, C3-40 alkyl lactone, and —R7—N(R8)—R9—; wherein R7, R8 and R9 are independently selected from the group C1-20 alkyl, C2-22 alkenyl, C6-40 cycloalkyl, C7-40 cycloalkylene and H; m and n are integral values ranging from 1 to 100 inclusive, with the proviso that when —O-A or —O—B are C3-20 alkyl glycol ethers, x or y is an integral value no less than 7; x and y are integral values ranging from 1 to 1,000 wherein x+y sum to at least 3; and further wherein no more than two of R1, R2, R3, R4 and R5 are terminated with an hydroxyl group.
摘要翻译： 描述了一种不含烷基酚的无色液体共聚多磷酸酯，其通式如下：其中每个R 1，R 2，R 3，R 4和R 5可以相同或不同，并且独立地选自C 12-20烷基，C 12-22烯基，C 12 -40环烷基，C12-40-环烯基，C12-20烷基二醇醚和作为封端基的A-OH和B-OH; 每个A和B不同且独立地选自C2-40亚烷基，C7-40亚烷基，C3-20烷基二醇醚，C3-40烷基内酯和-R7-N（R8）-R9-; 其中R 7，R 8和R 9独立地选自C 1-20烷基，C 2--22烯基，C 6-40环烷基，C 7-40亚环烷基和H; m和n是范围从1到100（包括端值）的整数值，条件是当-O-A或-O-B是C 3-20烷基二醇醚时，x或y是不小于7的整数值; x和y是范围从1到1,000的积分值，其中x + y和至少3; 并且其中R 1，R 2，R 3，R 4和R 5不超过2个被羟基封端。
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公开(公告)号：US07320764B2
公开(公告)日：2008-01-22
申请号：US10709510
申请日：2004-05-11
CPC分类号： C08K5/524 , C08K2201/014
摘要： The invention relates to liquid polymer additive compositions comprising blends of phosphite esters selected from the group consisting of aryl phosphites, alkyl phosphites, aryl/alkyl phosphites, bisphenol-A phosphites, dialkylene glycol phosphites and polydialkylene glycol phosphites, pentaerythritol phosphites, p-cumyl phenol phosphites with from 50 to 800 ppm inclusive of zinc per 100 parts resin. The stabilizer is used as either a complete or a partial replacement of toxic-metal containing antioxidant stabilizer additives.
摘要翻译： 本发明涉及包含亚磷酸酯的混合物的液体聚合物添加剂组合物，其选自亚磷酸芳基酯，亚磷酸烷基酯，亚磷酸亚烷基酯，亚磷酸双酚A，亚磷酸二亚烷基二醇亚磷酸酯和聚二亚烷基二醇亚磷酸酯，季戊四醇亚磷酸酯，对枯基苯酚 每100份树脂含50至800ppm的亚磷酸盐，包括锌。 稳定剂用作完全或部分替代含有毒金属的抗氧化剂稳定剂添加剂。
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公开(公告)号：US5939366A
公开(公告)日：1999-08-17
申请号：US031305
申请日：1998-02-26
IPC分类号： C10M105/38 , C10M129/74 , C10M173/00 , C10M173/02 , C10N30/06 , C10N40/20 , C10M129/72
CPC分类号： C10M129/74 , C10M173/00 , C10M173/02 , C10M2201/02 , C10M2207/283 , C10N2240/40 , C10N2250/02
摘要： The invention pertains to chlorine-free extreme pressure metalworking fluid additives and lies in the recognition of the improved hydrolytic stability of alkanoic acid esters of cyclohexane dimethanol and other esters embodying similar structures. The various derivatives which are effective as extreme pressure additives include those which fall within the generic description ##STR1## wherein R.sup.1 through R.sup.4 are independently selected from the group hydrogen and C.sub.1-24 hydrocarbyl groups and R.sup.5 and R.sup.6 are independently selected from the group C.sub.3-24 hydrocarbyl groups.
摘要翻译： 本发明涉及无氯极压金属加工液添加剂，并且在于认识到环己烷二甲醇的链烷酸酯和体现相似结构的其它酯的改进的水解稳定性。 作为极压添加剂有效的各种衍生物包括属于通用描述的那些，其中R 1至R 4独立地选自氢和C 1-4烃基，R 5和R 6独立地选自C 3-4烃基 。
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