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    Poly(ethylene-butylene) (meth)acrylates and related compositions
    2.
    发明申请
    Poly(ethylene-butylene) (meth)acrylates and related compositions 有权
    聚（乙烯 - 丁烯）（甲基）丙烯酸酯和相关组合物

    公开(公告)号：US20050154121A1

    公开(公告)日：2005-07-14

    申请号：US11035357

    申请日：2005-01-12

    申请人： Mingxin Fan ,  Jeffrey Allan Klang ,  Gary Ceska ,  James Horgan

    发明人： Mingxin Fan ,  Jeffrey Allan Klang ,  Gary Ceska ,  James Horgan

    IPC分类号： C08C19/00 ,  C08C19/38 ,  C08G18/62 ,  C08G18/69 ,  C08K3/00 ,  C08L15/00 ,  C08L19/00

    CPC分类号： C08C19/38 ,  B33Y70/00 ,  C08G18/69 ,  C08L15/00 ,  C08L19/006

    摘要： A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.

    摘要翻译： 一种组合物，其包含根据结构1的聚合物，其中R是H，Me，Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字，如果B没有，f = 1; A是氢化聚丁二烯骨架的残基; 和B无关，或者是双官能的有机连接基。 该组合物可以固化并用于宽范围的制品中，例如光聚合物印刷版，密封剂，填缝剂，密封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层， 焊料掩模，颜料分散体，立体光刻胶，层压树脂，接枝共聚物，复合材料，光纤涂层，纸张涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎 发动机支架，垫片，高尔夫球芯和橡胶辊。

    Radiation curable acrylate-terminated polymers having polycarbonate repeating units
    3.
    发明授权
    Radiation curable acrylate-terminated polymers having polycarbonate repeating units 有权
    具有聚碳酸酯重复单元的可辐射固化的丙烯酸酯封端的聚合物

    公开(公告)号：US06451958B1

    公开(公告)日：2002-09-17

    申请号：US09932559

    申请日：2001-04-06

    申请人： Mingxin Fan ,  Gary Ceska ,  James Horgan

    发明人： Mingxin Fan ,  Gary Ceska ,  James Horgan

    IPC分类号： C08G6400

    CPC分类号： C09D175/16 ,  C08G18/672 ,  Y10T428/31504 ,  Y10T428/31507 ,  Y10T428/31551 ,  C08G18/44

    摘要： Polymer having repeating polycarbonate moieties of the formula (I) (Acr)y(A)(Q)(PC)[(Q)(PC)]x(Q)(A)(Acr)y  (I) wherein (Acr)y(A) is the residue of hydroxyalkyl acrylate or hydroxyalkyl methacrylate having an alkyl moiety, A, and where said alkyl, A, has 2 to 5 carbon atoms and wherein Acr is an acrylate or methacrylate moiety; Q is the residue of one or more organic polyisocyantes which are connected with A via a urethane linkage; PC is the residue of an alkylene diol polycarbonate of the formula (II) HO(ROCOO)nROH  (II) R is one or more (C2 to C10) alkylene or one or more (C6 to C12) aromatic group; y is an integer from 1 to 5; x is from 1 to 20; PC and Q are connected via a urethane group. The acrylate terminate polymers are useful for radiation cured coatings which have superior adhesion and reverse impact strength, especially when applied to plastic substrates.

    摘要翻译： 具有式（I）的重复聚碳酸酯部分的聚合物其中（Acr）y（A）是具有烷基部分A的丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯的残基，并且其中所述烷基A具有2至5个碳原子，其中 Acr是丙烯酸酯或甲基丙烯酸酯部分; Q是通过氨基甲酸酯键与A连接的一种或多种有机聚异氰酸酯的残基; PC是式（II）的亚烷基二醇聚碳酸酯的残基R是一个或多个（C2 至C10）亚烷基或一个或多个（C6至C12）芳族基团; y为1至5的整数; x为1至20; PC和Q通过氨基甲酸酯基团连接。丙烯酸酯末端聚合物可用于辐射 具有优异的附着力和反冲击强度的固化涂层，特别是当应用于塑料基材时。

    Poly(ethylene-butylene) (meth)acrylates and related compositions
    4.
    发明授权
    Poly(ethylene-butylene) (meth)acrylates and related compositions 有权
    聚（乙烯 - 丁烯）（甲基）丙烯酸酯和相关组合物

    公开(公告)号：US07569641B2

    公开(公告)日：2009-08-04

    申请号：US11035357

    申请日：2005-01-12

    申请人： Mingxin Fan ,  Jeffrey Allan Klang ,  Gary W. Ceska ,  James Horgan

    发明人： Mingxin Fan ,  Jeffrey Allan Klang ,  Gary W. Ceska ,  James Horgan

    IPC分类号： C08C19/02 ,  C08C19/04 ,  C08C19/28 ,  C08C19/38 ,  C08F36/06

    CPC分类号： C08C19/38 ,  B33Y70/00 ,  C08G18/69 ,  C08L15/00 ,  C08L19/006

    摘要： A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.

    摘要翻译： 一种组合物，其包含根据结构1的聚合物，其中R是H，Me，Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字，如果B没有，f = 1; A是氢化聚丁二烯骨架的残基; 和B无关，或者是双官能的有机连接基。 该组合物可以固化并用于宽范围的制品中，例如光聚合物印刷版，密封剂，填缝料，密封剂，道路标线漆，光致抗蚀剂，粘合剂，抗冲改性剂，聚合物改性剂，氧气或水蒸气阻隔涂料，保形涂层， 焊料掩模，颜料分散体，立体光刻胶，层压树脂，接枝共聚物，复合材料，光纤涂层，纸张涂层，金属涂层，玻璃涂层，塑料涂层，木器涂料，防水材料，电绝缘材料，汽车皮带或软管，轮胎 发动机支架，垫片，高尔夫球芯和橡胶辊。

    Cycloaliphatic epoxide compounds
    5.
    发明授权
    Cycloaliphatic epoxide compounds 失效
    环脂族环氧化合物

    公开(公告)号：US5767150A

    公开(公告)日：1998-06-16

    申请号：US831677

    申请日：1997-04-10

    申请人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan ,  Henri Strub

    发明人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan ,  Henri Strub

    IPC分类号： C07D301/12 ,  C07D303/16 ,  C07D303/40 ,  C08G59/24 ,  C08G59/32 ,  A61K31/335 ,  C07D303/00

    CPC分类号： C08G59/24 ,  C07D301/12 ,  C07D303/16 ,  C07D303/40 ,  C08G59/3218

    摘要： Compounds having the formula ##STR1## wherein X is selected from O, (CH.sub.2).sub.m O, S, (CH.sub.2).sub.m S, NH, (CH.sub.2).sub.m NH, COO.sup.-, (CH.sub.2).sub.m COO.sup.-, .sup.- OOC and .sup.- OOC (CH.sub.2).sub.m ; m is 1 to 6; n is 1 to 100; R.sub.1 is (C.sub.1 -C.sub.20) ester; and A is a saturated organic linking group selected from residues of polyol, polythiol, polyamine, and polyacid, are prepared by reacting compounds according to formula II ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.

    摘要翻译： 具有式（I）的化合物其中X选自O，（CH 2）m O，S，（CH 2）m S，NH，（CH 2）m NH，COO-，（CH 2）m COO-， - OOC和 -OOC（CH 2）m; m为1〜6; n为1〜100; R1是（C1-C20）酯; 并且A是选自多元醇，多硫醇，多胺和多元酸的残基的饱和有机连接基团，其通过使式II（II）的化合物与（a）钨酸或其 金属盐，（b）磷酸或其金属盐，和（c）至少一种相转移催化剂。

    Process for preparing unsaturated esters containing cyclic epoxy group
    6.
    发明授权
    Process for preparing unsaturated esters containing cyclic epoxy group 失效
    制备含环状环氧基的不饱和酯的方法

    公开(公告)号：US06124483A

    公开(公告)日：2000-09-26

    申请号：US773524

    申请日：1996-12-23

    申请人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan

    发明人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan

    IPC分类号： B01J31/24 ,  B01J31/34 ,  C07D301/12 ,  C07D303/16 ,  C07D303/24 ,  C07D303/40 ,  C08F20/32 ,  C08G59/24

    CPC分类号： C07D303/40 ,  C07D301/12 ,  C07D303/16 ,  C07D303/24 ,  C08G59/24

    摘要： Process of making compounds of the formula ##STR1## wherein R.sub.1 =(C.sub.1 -C.sub.6) alkyl;X=O, S, NH;R.sub.2 =divalent saturated organic group;Y=O, S, NH, ester;R.sub.3 =cyclic moiety containing oxirane group;comprising reacting a compound of the formula ##STR2## wherein R.sub.4 is a cyclic moiety containing C.dbd.C group with hydrogen peroxide in the presence of (a) tungstic acid, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst;polymers of compounds of formula I; andcompounds of formula I except for compounds wherein R.sub.4 is a dicyclopentenyl epoxide, Y is O, R.sub.2 is --CH.sub.2 CH.sub.2 --, X is O, and R.sub.1 is H or methyl.

    摘要翻译： 制备下式化合物的方法其中R1 =（C1-C6）烷基; X = O，S，NH; R2 =二价饱和有机基团; Y = O，S，NH，酯; R3 =含环氧乙烷基团的环状部分; 包括在（a）钨酸，（b）磷酸或其金属盐存在下使下式化合物其中R 4是含有C = C基团的环状部分与过氧化氢反应，和（c）至少一种相转移 催化剂; 式I化合物的聚合物; 和式I化合物，除了其中R 4是二环戊烯基环氧化物，Y是O，R 2是-CH 2 CH 2 - ，X是O，R 1是H或甲基的化合物。

    Allyl urethane resin compositions
    7.
    发明授权
    Allyl urethane resin compositions 有权
    烯丙基聚氨酯树脂组合物

    公开(公告)号：US06559260B1

    公开(公告)日：2003-05-06

    申请号：US09535176

    申请日：2000-03-27

    申请人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan

    发明人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan

    IPC分类号： C08L7516

    CPC分类号： C09D175/16 ,  C08G18/6715

    摘要： The present invention is for a new class of allyl urethane resin which can be cured with peroxide at high temperature alone or in combination with some accelerators. These allyl urethane resins can be sued alone or in combination with other free radically polymerizable materials such as allyl monomers and ligomers or (meth)acrylate monomers and oligomers. These new allyl urethane resins contain at least two allyl functional groups.

    摘要翻译： 本发明是一种新的烯丙基聚氨酯树脂，其可以单独或与一些加速剂组合使用，可以在高温下用过氧化物固化。 这些烯丙基聚氨酯树脂可以单独或与其它可自由基聚合的材料如烯丙基单体和连接体或（甲基）丙烯酸酯单体和低聚物组合起来。 这些新的烯丙基聚氨酯树脂含有至少两个烯丙基官能团。

    Method for making cycloaliphatic epoxides
    8.
    发明授权
    Method for making cycloaliphatic epoxides 失效
    制备脂环族环氧化物的方法

    公开(公告)号：US6084111A

    公开(公告)日：2000-07-04

    申请号：US62593

    申请日：1998-04-17

    申请人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan ,  Henri Strub

    发明人： Mingxin Fan ,  Gary W. Ceska ,  James Horgan ,  Henri Strub

    IPC分类号： C07D301/12 ,  C07D303/16 ,  C07D303/40 ,  C08G59/24 ,  C08G59/32 ,  C07D303/00

    CPC分类号： C08G59/24 ,  C07D301/12 ,  C07D303/16 ,  C07D303/40 ,  C08G59/3218

    摘要： Compounds having the formula ##STR1## wherein X is selected from O, (CH.sub.2).sub.m O, S, (CH.sub.2).sub.m S, NH, (CH.sub.2).sub.m NH, COO.sup.-, (CH.sub.2).sub.m COO.sup.-, .sup.- OOC and .sup.- OOC (CH.sub.2).sub.m ;m is 1 to 6;n is 1 to 100;R.sub.1 is selected from H, (C.sub.1 -C.sub.20) alkyl, (C.sub.1 -C.sub.20) alkoxy and (C.sub.1 -C.sub.20) ester; andA is a saturated organic linking group selected from residues of polyol, polythiol, polyamine, and polyacid, are prepared by reacting compounds according to formula II ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.

    摘要翻译： 具有下式的化合物其中X选自O，（CH 2）m O，S，（CH 2）m S，NH，（CH 2）m NH，COO-，（CH 2）m COO-， - OOC和-OOC（CH 2）m; m为1〜6; n为1〜100; R1选自H，（C1-C20）烷基，（C1-C20）烷氧基和（C1-C20）酯; （a）钨酸或其金属盐的存在下，通过使根据式II的化合物与过氧化氢反应制备A是选自多元醇，多硫醇，多胺和多元酸的残基的饱和有机连接基团，（b） 磷酸或其金属盐，以及（c）至少一种相转移催化剂。