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    Silver halide photographic materials
    1.
    发明授权
    Silver halide photographic materials 失效

    公开(公告)号：US4977062A

    公开(公告)日：1990-12-11

    申请号：US178391

    申请日：1988-04-06

    申请人： Morio Yagihara ,  Hisashi Okada ,  Kazunobu Katoh ,  Nobuaki Inoue

    发明人： Morio Yagihara ,  Hisashi Okada ,  Kazunobu Katoh ,  Nobuaki Inoue

    IPC分类号： G03C1/06

    CPC分类号： G03C1/061

    摘要： An ultra-high contrast negative type silver halide photographic material comprising:(1) at least one silver halide emulsion layer on a support;(2) at least one compound selected from among hydrazine derivatives which can be represented by formula (I) below, which is included in said emulsion layer or in another hydrophilic colloid layer, ##STR1## wherein A.sub.1 and A.sub.2 both represent hydrogen atoms or one represents a hydrogen atom and the other represents a sulfinic acid residual group or an acyl group, R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group, R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, or an amino group, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group or an N-substituted or unsubstituted iminomethylene group, and at least one of R.sub.1 and R.sub.2 has a group which promotes adsorption on silver halide; and(3) at least one compound selected from among the hydrazine derivatives which can be represented by the formula (II) below, which is included in the said emulsion layer or in another hydrophilic colloid layer, ##STR2## wherein A.sub.3 and A.sub.4 both represent hydrogen atoms or one represents a hydrogen atom and the other represents a sulfinic acid residual group or an acyl group, R.sub.3 represents an aliphatic group, an aromatic group or a heterocyclic group, R.sub.4 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group or an amino group, G.sub.2 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an iminomethylene group, and the total number of carbon atoms in R.sub.3 and R.sub.4 is at least 13.

    Silver halide photographic material
    4.
    发明授权
    Silver halide photographic material 失效

    公开(公告)号：US4971888A

    公开(公告)日：1990-11-20

    申请号：US349170

    申请日：1989-05-09

    申请人： Hisashi Okada ,  Morio Yagihara ,  Kazunobu Katoh

    发明人： Hisashi Okada ,  Morio Yagihara ,  Kazunobu Katoh

    IPC分类号： C07C271/28 ,  C07C275/36 ,  C07C275/40 ,  C07C275/42 ,  C07C311/08 ,  C07C311/24 ,  C07C311/47 ,  C07C311/49 ,  C07C323/60 ,  C07C333/08 ,  C07D209/48 ,  C07D213/77 ,  C07D213/82 ,  C07D251/20 ,  G03C1/06 ,  G03C1/485

    CPC分类号： C07D209/48 ,  C07C271/28 ,  C07C275/36 ,  C07C275/40 ,  C07C275/42 ,  C07C311/08 ,  C07C311/24 ,  C07C311/47 ,  C07C311/49 ,  C07C323/60 ,  C07C333/08 ,  C07D213/77 ,  C07D213/82 ,  C07D251/20 ,  G03C1/061

    摘要： A silver halide photographic material is disclosed, comprising a support having thereon at least one of silver halide photographic emulsion layers and other hydrophilic colloidal layers, wherein said at least one of photographic emulsion layers and other hydrophobic colloidal layers contains a compound represented by formula (I) ##STR1## wherein at least one of A.sub.1 and A.sub.2 represents a hydrogen atom and other represents a hydrogen atom, a sulfinic residual group or ##STR2## wherein R.sub.0 represents an alkyl group, an alkenyl group, an aryl grup, an alkoxy group or an aryloxy group, and l.sub.1 represents an integer of 1 or 2; G represents ##STR3## wherein m.sub.1 represents an integer of 1 or 2, a sulfonyl group, a sulfoxy group ##STR4## wherein R.sub.1 represents an alkoxy grup or an aryloxy group, a thiocarbonyl grup or an iminomethylene group; X represents an aliphatic group, an aromatic group or a heterocyclic group, substituted by the group represented by formula (a): ##STR5## wherein Y represents a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group; L represents ##STR6## wherein R.sub.a ' represents a hydrogen atom, an aliphatic group or an aromatic group; R.sub.a represents a hydrogen atom, an aliphatic group or an aromatic group; and R represents a group represented by formula (b): ##STR7## wherein R.sub.b.sup.1 to R.sub.b.sup.4 may be the same or different and each represents a hydrogen atom, an aliphatic group or an atomatic group; B represents a suitable atomic group for forming a 5- or 6-membered ring; Z represents a group capable of making a nucleophilic attach on G to separate the --G--R portion from the other portion of the formula; m.sub.b represents an integer of 0 or 1; n.sub.b represents an integer of 1 when Z is a hydroxy group, or n.sub.b represents an integer of 0 or 1 when Z represents a group other than a hydroxy group; and (m.sub.b +n.sub.b) represents an integer of 1 or 2.

    Silver halide photographic material
    6.
    发明授权
    Silver halide photographic material 失效
    卤化银照相材料

    公开(公告)号：US5006445A

    公开(公告)日：1991-04-09

    申请号：US343441

    申请日：1989-04-26

    申请人： Morio Yagihara ,  Hisashi Okada ,  Kazunobu Katoh

    发明人： Morio Yagihara ,  Hisashi Okada ,  Kazunobu Katoh

    IPC分类号： G03C1/06 ,  G03C1/485

    CPC分类号： G03C1/061

    摘要： A silver halide photographic material comprising a support having thereon at least one hydrophilic colloid layer, at least one of which is a silver halide photographic emulsion layer, is disclosed. At least one of the silver halide emulsion layers or other hydrophilic colloid layers of the photographic material contains a compound represented by formula (I): ##STR1## wherein, A.sub.1 and A.sub.2 both represent hydrogen atoms or one represents a hydrogen atom and the other a sulfonyl group or an acyl group, R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group, G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a ##STR2## group wherein R.sub.2 represents an alkoxy group or an aryloxy group, a ##STR3## group or an iminomethylene group, X.sub.1 is a moiety which instigates a ring-forming reaction by cleaving the --G.sub.1 --X.sub.1 moiety from the residual molecule and forms a cyclic structure containing the atoms of the --G.sub.1 --X.sub.1 moiety, and at least one of R.sub.1 and X.sub.1 has a silver halide adsorption accelerating group.

    摘要翻译： 公开了一种卤化银照相材料，其包含其上具有至少一个亲水胶体层的载体，其中至少一个是卤化银照相乳剂层。 照相材料的卤化银乳剂层或其他亲水胶体层中的至少一种含有由式（I）表示的化合物：其中，A1和A2均代表氢原子或一个表示氢原子， 另一个是磺酰基或酰基，R 1表示脂族基团，芳族基团或杂环基团，G 1表示羰基，磺酰基，磺基氧基，其中R 2表示烷氧基或 一个芳氧基，一个“IMAGE”基团或一亚氨基亚甲基，X 1是通过从残留分子中切割-G1-X1部分并形成含有-G1-的原子的环状结构来引发成环反应的部分， X1部分，并且R1和X1中的至少一个具有卤化银吸附促进基团。

    Superhigh contrast negative-type silver halide photographic material
    7.
    发明授权
    Superhigh contrast negative-type silver halide photographic material 失效
    超高对比度负型卤化银照相材料

    公开(公告)号：US4851321A

    公开(公告)日：1989-07-25

    申请号：US117724

    申请日：1987-11-06

    申请人： Yoshihiro Takagi ,  Hisashi Okada ,  Morio Yagihara ,  Kazunobu Katoh

    发明人： Yoshihiro Takagi ,  Hisashi Okada ,  Morio Yagihara ,  Kazunobu Katoh

    IPC分类号： G03C1/06

    CPC分类号： G03C1/061 ,  G03C1/36 ,  G03C2001/094 ,  G03C5/16 ,  Y10S430/15

    摘要： A superhigh contrast negative type silver halide photographic material comprising a support having provided thereon at least one silver halide emulsion layer, the emulsion layer or at least one other hydrophilic colloid layer containing at least one hydrazine derivative and at least one compound of formula (I):Y[(X).sub.n A-B].sub.m (I)wherein Y represents a group capable of adsorbing to silver halide; X represents a divalent linking group comprising an atom or atoms selected from a hydrogen atom, a carbon atom, a nitrogen atom, an oxygen atom and a sulfur atom or an atomic group comprised of the atoms; A represents a divalent linking group; B represents a substituted or unsubstituted amino group, an ammonium group or a nitrogen-containing heterocyclic group; m represents 1, 2 or 3; and n represents 0 or 1. The photographic material may contain an organic desensitizer and a water-soluble rhodium salt, and the material has a low sensitivity and can be handled in a bright room.

    摘要翻译： 一种超高对比度负型卤化银照相材料，包括其上提供有至少一个卤化银乳剂层的支撑体，所述乳剂层或至少一种含有至少一种肼衍生物和至少一种式（I）化合物的其它亲水胶体层， ：Y [（X）nA-B] m（I）其中Y表示能够吸收卤化银的基团; X表示包含选自氢原子，碳原子，氮原子，氧原子和硫原子的原子或原子或由原子构成的原子团的二价连接基团; A表示二价连接基团; B表示取代或未取代的氨基，铵基或含氮杂环基; m表示1,2或3; 并且n表示0或1.照相材料可以含有有机脱敏剂和水溶性铑盐，并且该材料具有低灵敏度并且可以在明亮的房间中处理。

    Silver halide photographic material
    10.
    发明授权
    Silver halide photographic material 失效
    卤化银照相材料

    公开(公告)号：US4914002A

    公开(公告)日：1990-04-03

    申请号：US267469

    申请日：1988-11-04

    申请人： Nobuaki Inoue ,  Hisashi Okada ,  Shigeo Hirano ,  Kimitaka Kameoka ,  Tetsuo Yoshida ,  Morio Yagihara

    发明人： Nobuaki Inoue ,  Hisashi Okada ,  Shigeo Hirano ,  Kimitaka Kameoka ,  Tetsuo Yoshida ,  Morio Yagihara

    IPC分类号： G03C1/06 ,  G03C1/16

    CPC分类号： G03C1/061 ,  G03C1/16

    摘要： A silver halide negative photographic material comprising a support having thereon at least one silver halide emulsion layer, at least one hydrophilic colloidal layer thereof containing (1) a hydrazine derivative, (2) a compound substantially having no absorption maximum in the visible light region represented by formula (I): ##STR1## wherein Z.sup.11, Z.sup.12, R.sup.11, R.sup.12 X and n are as defined in the specification, and (3) at least one compound represented by formula (II) or (III): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and Q are as defined in the specification; and ##STR3## wherein R.sub.21, R.sub.22, R.sub.23, and R.sub.24, are as defined in the specification. The photographic material can be processed with a stable developer to provide an ultra-high contrast image without reduction in sensitivity, gamma or maximum density or the appearance of black pepper. The photographic material is excellent in pressure properties and anti-blocking properties.

    摘要翻译： 一种卤化银负型照相材料，其包含其上具有至少一个卤化银乳剂层的载体，至少一种亲水性胶体层，其含有（1）肼衍生物，（2）在可见光区域中基本上不具有最大吸收的化合物 通式（I）：其中Z11，Z12，R11，R12X和n如说明书中所定义，其中（I）至少一种由式（II）或（III）表示的化合物： （II）其中R1，R2，R3和Q如说明书中所定义; 和（III）其中R 21，R 22，R 23和R 24如说明书中所定义。 可以用稳定的显影剂处理照相材料以提供超高对比度图像，而不降低灵敏度，γ或最大密度或黑胡椒的外观。 照相材料的压力特性和防粘连性优异。