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    Process for the preparation of supported catalysts for the polymerization of olefins
    1.
    发明授权
    Process for the preparation of supported catalysts for the polymerization of olefins 失效
    制备用于烯烃聚合的负载催化剂的方法

    公开(公告)号：US4426315A

    公开(公告)日：1984-01-17

    申请号：US338812

    申请日：1982-01-11

    申请人： Mufit Bahadir ,  Wolfgang Payer ,  Ingrid Forster ,  Hans-Albert Lummen

    发明人： Mufit Bahadir ,  Wolfgang Payer ,  Ingrid Forster ,  Hans-Albert Lummen

    IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/16 ,  C08F4/48 ,  C08F4/50 ,  C08F4/60 ,  C08F4/62 ,  C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： In a process for the preparation of a supported catalyst for the preparation of polyolefins which have a component A and a component B, wherein component A consists essentially of a reaction product ofa compound of a first metal of sub groups IV to VI of the Periodic Table of the Elements with an organic compound of a second metal of main groups I to III of the Periodic Table of the Elements, said reaction being carried out at a temperature of from -60.degree. C. to +40.degree. C., andan inorganic carrier,component B being an organo metallic compound,the improvement comprising suspending the carrier in an agent which is oxygen, sulfur, and moisture free, simultaneously and separately adding to the carrier and the agent the compounds of the first and second metals in liquid or dissolved form, excluding oxygen and moisture from the reaction, and maintaining a molar ratio of the compound of the first metal to the compound of the second metal of 1:3 to 3:1.The use of the catalyst in the polymerization of ethylene both with and without the presence of .alpha. olefins is also disclosed.

    摘要翻译： 在制备具有组分A和组分B的聚烯烃的负载型催化剂的制备方法中，其中组分A基本上由周期化合物的第IV族至第Ⅵ族的第一种金属的化合物的反应产物组成 具有元素周期表的主要I〜III族的第二金属的有机化合物的元素表，所述反应在-60℃至+ 40℃的温度下进行， 无机载体，组分B是有机金属化合物，其改进包括将载体悬浮在氧，硫和无水的试剂中，同时并分别地向载体和试剂中加入液体中的第一和第二金属的化合物 或溶解形式，不包括反应中的氧和水分，并保持第一金属化合物与第二金属化合物的摩尔比为1:3至3:1。 还公开了在具有和不具有α-烯烃的情况下乙烯聚合中催化剂的用途。

    Process for the manufacture of polyolefins
    2.
    发明授权
    Process for the manufacture of polyolefins 失效
    制造聚烯烃的方法

    公开(公告)号：US4370458A

    公开(公告)日：1983-01-25

    申请号：US954021

    申请日：1978-10-23

    申请人： Jurgen Falbe ,  Peter Schneller ,  Wolfgang Payer ,  Ingrid Forster ,  Boy Cornils ,  Hans-Walter Birnkraut ,  Siegfried Lutze ,  Karl Otterbein

    发明人： Jurgen Falbe ,  Peter Schneller ,  Wolfgang Payer ,  Ingrid Forster ,  Boy Cornils ,  Hans-Walter Birnkraut ,  Siegfried Lutze ,  Karl Otterbein

    IPC分类号： C08F2/00 ,  C08F2/38 ,  C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/02

    CPC分类号： C08F10/02 ,  Y10S526/905

    摘要： An improvement in a process for the preparation of an ethylene homopolymer or a copolymer of ethylene with an .alpha.-olefin containing 3 to 15 carbon atoms by contacting the monomer or mixture of monomers in solution, suspension or in gas phase at 20.degree. to 250.degree. C. at a pressure of 1 to 50 bar with a mixed catalyst comprising a chlorine containing titanium (III) compound and an organoaluminum compound in the presence of hydrogen, the improvement residing in employing as the organoaluminum compound a trialkylaluminum compound in an amount of 0.1 to 20 mol per mol titanium (III) compound and including in the polymerization mixture oxygen at a concentration of 0.001 to 0.1 volume percent based upon the amount of ethylene. By carrying out the polymerization by including oxygen in the polymerization reaction mixture and employing trialkylaluminum compound as the organoaluminum compound the mean molecular weight of the polymer can be regulated while obtaining a desired molecular weight distribution.

    摘要翻译： 乙烯均聚物或乙烯与含有3至15个碳原子的α-烯烃的共聚物的制备方法的改进通过在20℃至250℃的溶液，悬浮液或气相中使单体或单体混合物接触。 在含氢的钛（III）化合物和有机铝化合物的混合催化剂的氢气存在下，在1至50巴的压力下，该改进剂用于作为有机铝化合物的三烷基铝化合物的用量为0.1 至20mol / mol钛（III）化合物，并且在聚合混合物中包含基于乙烯量的0.001至0.1体积％浓度的氧气。 通过在聚合反应混合物中包含氧并使用三烷基铝化合物作为有机铝化合物进行聚合，可以调节聚合物的平均分子量，同时获得所需的分子量分布。