Abstract:
A method of producing a positive electrode active material for a nonaqueous electrolyte secondary battery, the method includes preparing nickel-containing composite oxide particles having a ratio 1D90/1D10 of a 90% particle size 1D90 to a 10% particle size 1D10 in volume-based cumulative particle size distribution of 3 or less; obtaining a raw material mixture containing the composite oxide particles and a lithium compound and having a ratio of a total number of moles of lithium to a total number of moles of metal elements contained in the composite oxide in a range of 1 to 1.3; subjecting the raw material mixture to a heat treatment to obtain a heat-treated material; subjecting the heat-treated material to a dry-dispersion treatment to obtain a first dispersion; and bringing the first dispersion into contact with a liquid medium to obtain a second dispersion.
Abstract:
A positive-electrode active material for a non-aqueous electrolyte secondary battery is provided. The positive-electrode active material contains a lithium transition metal composite oxide having a spinel structure and containing nickel and manganese. The lithium transition metal composite oxide has a surface region containing niobium as a solid solution. A mole ratio of an amount of niobium to a total amount of nickel and manganese in the surface region decreases according to a distance from a surface in a depth direction in a region from the surface to a distance of 0.3 nm in the depth direction.
Abstract:
A method of producing a positive electrode active material for a nonaqueous electrolyte secondary battery, the method includes preparing nickel-containing composite oxide particles having a ratio 1D90/1D10 of a 90% particle size 1D90 to a 10% particle size 1D10 in volume-based cumulative particle size distribution is 3 or less; mixing the composite oxide particles and a lithium compound to obtain a first mixture; subjecting the first mixture to a first heat treatment at a first temperature and a second heat treatment at a second temperature higher than the first temperature to obtain a first heat-treated product; and subjecting the first heat-treated material to a dispersion treatment.
Abstract:
Provided is a positive electrode active material which inhibits a decrease in discharge capacity while improving output in a low SOC region. The positive electrode active material includes: first particles that each consist of a first lithium transition metal composite oxide, the first lithium transition metal composite oxide having a layered structure and having a ratio of a number of moles of nickel to a total number of moles of metals other than lithium in a composition thereof being 0.7 or greater and smaller than 1; second particles that have a volume average particle diameter smaller than a volume average particle diameter of the first particles, the second particles each consisting of a second lithium transition metal composite oxide having a layered structure; and third particles that each consist of a third lithium transition metal composite oxide, the third lithium transition metal composite oxide having a layered structure, having a ratio of number of moles of nickel to total number of moles of metals other than lithium in a composition thereof being 0.4 to 0.6, and having a ratio of a number of moles of cobalt to the total number of moles being 0.35 to 0.55. The first particle content is 60 mass % or higher and lower than 100 mass %, and the third particle content is 10 mass % or lower, to a total content of the first particles, the second particles, and the third particles.
Abstract:
Provided is a positive electrode active material for a non-aqueous electrolyte secondary battery. Also provided is a method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery, comprising: providing a lithium transition metal composite oxide having a ratio D50/DSEM of 1 or more and 4 or less, having a layered structure, and having a ratio of a number of moles of nickel to a total number of moles of metals other than lithium of 0.3 or more and less than 1, and a ratio of a number of moles of cobalt to the total number of moles of metals other than lithium of 0 or more and less than 0.5; bringing the lithium transition metal composite oxide into contact with a cobalt compound to obtain an adhered material; and heat-treating the adhered material at a temperature higher than 700° C. and lower than 1100° C.
Abstract:
A positive electrode active material for a nonaqueous electrolyte secondary battery includes particles of a lithium-transition metal composite oxide that contains nickel in the composition thereof and has a layered structure. The particles have an average particle size DSEM based on electron microscopic observation in a range of 1 μm to 7 μm in which a ratio D50/DSEM of a 50% particle size D50 in volume-based cumulative particle size distribution to the average particle size based on electron microscopic observation is in a range of 1 to 4, and a ratio D90/D10 of a 90% particle size D90 to a 10% particle size D10 in volume-based cumulative particle size distribution is 4 or less.
Abstract:
A method of producing a positive electrode active material for a nonaqueous electrolyte secondary battery, the method includes preparing nickel-containing composite oxide particles having a ratio 1D90/1D10 of a 90% particle size 1D90 to a 10% particle size 1D10 in volume-based cumulative particle size distribution is 3 or less; mixing the composite oxide particles and a lithium compound to obtain a first mixture; subjecting the first mixture to a first heat treatment at a first temperature and a second heat treatment at a second temperature higher than the first temperature to obtain a first heat-treated product; and subjecting the first heat-treated material to a dispersion treatment.
Abstract:
The present disclosure provides a positive electrode active material for nonaqueous electrolyte secondary batteries including: a lithium transition metal composite oxide represented by general formula: Lia(Ni1-xCrx)a(Mn1-yTiy)2-α-β-γ-δMgβAlγMδO4 in which 1.00≦a≦1.30, 0.020≦x≦0.200, 0.006≦y≦0.070, 0.450≦α≦0.550, 0≦β≦0.015, 0≦γ≦0.035, and 0≦δ≦0.010, and M represents at least one element selected from the group consisting of Na, K, Ca, Sr, Ba, Ga, Co, Zn, Si, Ge, Zr, Hf, Sn, Ta, Nb, P, Bi, Mo, and W.
Abstract:
A positive electrode active material for a nonaqueous electrolyte secondary battery includes particles of a lithium-transition metal composite oxide that contains nickel in the composition thereof and has a layered structure. The particles have an average particle size DSEM based on electron microscopic observation in a range of 1 μm to 7 μm in which a ratio D50/DSEM of a 50% particle size D50 in volume-based cumulative particle size distribution to the average particle size based on electron microscopic observation is in a range of 1 to 4, and a ratio D90/D10 of a 90% particle size D90 to a 10% particle size D10 in volume-based cumulative particle size distribution is 4 or less.
Abstract:
A method of producing a cathode active material for a secondary battery is provided. The method includes preparing a mixture comprising a lithium source, a phosphate source, an iron source, a carbon source, a boron source comprising an oxo acid of boron, and a liquid medium; granulating the mixture to obtain a precursor; and heat-treating the precursor to obtain a lithium transition metal compound having an olivine structure, wherein in the mixture, a total molar amount of boron atoms contained in the boron source is more than 0% and less than 3% with respect to a total molar amount of iron atoms contained in the iron source as 100%.