Abstract:
A polycarbonate resin film of the present invention is formed from a polycarbonate resin which contains at least a constitutional unit derived from a dihydroxy compound having a bonded structure represented by the following structural formula (1) and satisfies the following expression (2) when subjected to a tensile test at a standard stretching temperature for the polycarbonate resin and at a pulling speed (strain rate) of 1,000%/min. [Chem. 1] CH2—O (1) (No hydrogen atom is bonded to the oxygen atom contained in the structural formula (1).) 0.9≦[(lower yield stress in tension)/(upper yield stress in tension)]≦1 (2)
Abstract:
The retardation film of the present invention contains a resin having positive refractive index anisotropy and containing at least one bonding group of a carbonate bond and an ester bond and one or more structural units selected from the group consisting of a structural unit represented by the general formula (1) and a structural unit represented by the general formula (2), in which the value of wavelength dispersion (R450/R550) as a ratio of retardation R450 at a wavelength of 450 nm to retardation R550 at a wavelength of 550 nm is more than 0.5 and less than 1.0: (in formula (1) and formula (2), definitions of R1 to R9 are the same as in the description).
Abstract:
Provided is a method by which a retardation film suppressed in biaxiality, having a small Nz coefficient, and having a slow axis in an oblique direction can be produced with high production efficiency. The production method for a retardation film of the present invention includes: holding left and right end portions of a film with left and right variable pitch-type clips configured to have clip pitches changing in a longitudinal direction, respectively; preheating the film; reducing, under a state in which the clip pitch of the clips on one side out of the left and right clips is kept constant, the clip pitch of the clips on another side to obliquely stretch the film; and releasing the film from being held with the clips.
Abstract:
The present invention provides a method capable of producing a retardation film having an elongated shape, having high uniaxiality and a high in-plane alignment property, and having a slow axis in an oblique direction with high production efficiency. The production method for a retardation film of the present invention includes: holding left and right end portions of a film with left and right variable pitch-type clips configured to have clip pitches changing in a longitudinal direction, respectively; preheating the film; increasing the clip pitch of the clips on one side and reducing the clip pitch of the clips on another side, while extending a distance between the left and right clips, to obliquely stretch the film; maintaining or reducing the clip pitch of the clips on the one side and increasing the clip pitch of the clips on the another side so that the clip pitches of the left and right clips are equal to each other, while extending the distance between the left and right clips, to obliquely stretch the film; and releasing the film from being held with the clips.
Abstract:
A plastic optical fiber suitable for reducing interfacial delamination between a clad and a coating layer. The plastic optical fiber includes: a core; a clad disposed on an outer circumference of the core and including a fluorine-containing resin; and a coating layer disposed on an outer circumference of the clad, the coating layer consisting of a material. The material has an elongation, as measured by a given test, of 0.05% or less.
Abstract:
The retardation film of the present invention contains a thermoplastic resin and is constituted of a single layer. A value of wavelength dispersion (R450/R550) that is a ratio of a retardation R450 at a wavelength of 450 nm and a retardation R550 at a wavelength of 550 nm is 0.70 or more and 0.85 or less; and a photoelastic coefficient is 14×10−12 Pa−1 or less.
Abstract:
One aspect of the present invention is a fluorine resin refining method. The method includes refining a fluorine resin by bringing the fluorine resin into contact with a fluorinating agent at a temperature of (Tg1−35)° C. or higher, where Tg1 is the glass transition temperature of the fluorine resin, and the fluorine resin includes a first fluorine-containing aliphatic ring structure in a molecular chain. The present invention makes it possible to produce a fluorine resin suitable for use in a plastic optical fiber. The first fluorine-containing aliphatic ring structure may have a dioxolane skeleton.
Abstract:
A retardation film insusceptible to color dropout or color shift even under environment of severe temperature or humidity conditions and capable of being produced by a melt film-forming method. The retardation film is obtained by molding at least one polymer selected from polycarbonate and polyester carbonate each having a glass transition temperature of 110 to 180° C. and satisfies the relationships of the following formulae (A) and (B): 0.7
Abstract:
A plastic optical fiber includes a core and a clad disposed on an outer circumference of the core. The core includes a first resin, and the clad includes a second resin. The first resin has a first glass transition temperature Tg1 of 120° C. or higher. The second resin has a second glass transition temperature Tg2 of 120° C. or higher. When the plastic optical fiber bent once 180 degrees at 25° C. has a curvature radius R and a minimum of the curvature radius R is defined as a curvature radius at which a crack does not occur in a bent portion of the plastic optical fiber, the minimum is 5 mm or less.
Abstract:
An object of the present invention is to provide a retardation film excellent in various properties such as optical properties, heat resistance, mechanical properties, and reliability. The present invention relates to a retardation film containing a thermoplastic resin and composed of a single layer, in which the retardation film has a value of wavelength dispersion that is a ratio of retardations at a wavelength of 450 nm and at a wavelength of 550 nm being 0.75 or more and 0.92 or less; a birefringence at a wavelength of 550 nm and the wavelength dispersion satisfy a relationship of Δn≧0.0140×(R450/R550)−0.0082; and a photoelastic coefficient is 25×10−12 Pa−1 or less.