摘要:
The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high-density polyethylene composition according to instant invention includes a first component, a second component, and a third component. The first component is a high-density polyethylene polymer having a density in the range of 0.940 to 0.980 g/cm3. The second component is polyethylene glycol, and the third component is octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate. The high-density polyethylene composition of the instant invention has a Yellowness Index of less than about −2.5 at 0 hour of accelerated aging at 100° C. according to ASTM D-6290. The process for producing the high-density polyethylene composition according to instant invention includes the following steps: (1) providing a first component, wherein the first component is a high-density polyethylene polymer having a density in the range of 0.940 to 0.980 g/cm3; (2) providing a second component, wherein the second component is polyethylene glycol; (3) providing a third component, wherein the third component is octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate; (4) blending the second and third components into the first component thereby forming a blend; (5) pelletizing the blend; and (6) thereby forming pellets of the high-density polyethylene composition having a Yellowness Index of less than about −2.5 at 0 hour of accelerated aging at 100° C. according to ASTM D-6290. Articles according to instant invention comprises the above-described inventive high-density polyethylene composition.
摘要:
A polyethylene composition comprising a granular polyethylene resin characterized by a resin solid density of from 0.91 to 0.97 g/cm3, a ratio of intraparticle void volume to interparticle void volume of from 0.33 to 0.67, and a total resin porosity, Φtotal, of equal to or greater than 0.45 is provided. Further provided are articles made from the polyethylene composition.
摘要:
The invention provides an ethylene-based interpolymer comprising the following features: a) density from 0.910 to 0.930 g/cc; b) melt index (I2) from 0.1 to 0.5 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a hollow tube comprising at least one component formed from a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area; and wherein the tube has a hydrostatic design basis (HDB) of at least 1000-psi at 23° C. per ASTM D-2837 regression method.
摘要:
The invention provides an ethylene-based interpolymer comprising the following features: a) density from 0.910 to 0.930 g/cc; b) melt index (I2) from 0.1 to 0.5 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a hollow tube comprising at least one component formed from a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area; and wherein the tube has a hydrostatic design basis (HDB) of at least 1000-psi at 23° C. per ASTM D-2837 regression method.
摘要:
A process for polymerizing polyethylene with chromium-based catalysts wherein one or more supported chromium-based catalysts is mixed with mineral oil to form a slurry and the slurry is then introduced into a polymerization reactor, especially a gas-phase polymerization reactor.