公开(公告)号：US20120256334A1

公开(公告)日：2012-10-11

申请号：US13412323

申请日：2012-03-05

申请人： Jiro YOSHINARI ,  Naoki HAYASHIDA ,  Shohei FUJII ,  Kazushi TANAKA

发明人： Jiro YOSHINARI ,  Naoki HAYASHIDA ,  Shohei FUJII ,  Kazushi TANAKA

IPC分类号： B29D11/00

CPC分类号： G03H1/02 ,  G03H1/30 ,  G03H2001/026 ,  G03H2240/52

摘要： An optimal recording exposure is determined by varying in the first to nth stages the recording exposure with a write laser beam to record a bright pattern image and a dark pattern image in each stage as the first to nth bright pattern images and the first to nth dark pattern images, respectively; irradiating the respective pattern images with a read beam to detect the intensity of a diffracted beam from the central portion of each image of the bright and dark patterns; calculating Sa1/Sb1=SNR1, . . . , and San/Sbn=SNRn, where Sa1 to San are the intensity of a diffracted beam from the first to nth bright pattern images and Sb1 to Sbn are the intensity of s diffracted beam from the first to nth dark pattern images; and determining a recording exposure which is given at the SNRmax being the maximum value of the resulting SNR1 to SNRn.

摘要翻译： 通过在写入激光束的第一至第n级变化记录曝光来确定最佳记录曝光，以将每个阶段中的亮图案图像和暗图案图像记录为第一至第n亮图案图像和第一至第n黑暗 图案图像; 用读取光束照射各图案图像，以检测来自亮和暗图案的每个图像的中心部分的衍射光束的强度; 计算Sa1 / Sb1 = SNR1， 。 。 ，San / Sbn = SNRn，其中Sa1至San是从第一至第n亮图案图像的衍射光束的强度，Sb1至Sbn是从第一至第n暗图案图像的衍射光束的强度; 并且确定以SNRmax给出的记录曝光是所得SNR1至SNRn的最大值。

公开(公告)号：US20120250123A1

公开(公告)日：2012-10-04

申请号：US13361352

申请日：2012-01-30

申请人： Naoki HAYASHIDA ,  Jiro YOSHINARI ,  Shohei FUJII ,  Kazushi TANAKA

发明人： Naoki HAYASHIDA ,  Jiro YOSHINARI ,  Shohei FUJII ,  Kazushi TANAKA

IPC分类号： G03H1/26

CPC分类号： G03H1/30 ,  G03H2001/026 ,  G03H2001/0415 ,  G03H2001/0439 ,  G03H2001/2247

摘要： A method for evaluating a hologram image recording medium includes: recording continuously a plurality of fine holograms, each being the same in size as an element hologram, on a hologram image recording medium to be evaluated, using either one of a two-beam interference between a reference beam and a signal beam both being a plane wave and a two-beam interference between a reference beam being a plane wave and a signal beam being a spherical wave; reproducing a diffraction image by irradiating the recorded fine hologram with a plane wave; from intensity distribution data based on a captured diffraction image, determining an intensity distribution data array and a diffracted beam intensity Is, the intensity distribution data array having the same shape and size as those of the fine hologram; and when the diffracted beam intensity Is takes on the maximum value Is(max), determining an SN ratio.

摘要翻译： 一种用于评估全息图像记录介质的方法包括：使用两个光束之间的干涉，在要评估的全息图像记录介质上连续记录各个与元件全息图尺寸相同的精细全息图， 参考光束和信号光束均为平面波和作为平面波的参考光束与作为球面波的信号光束之间的双光束干涉; 通过用平面波照射记录的精细全息图来再现衍射图像; 根据捕获的衍射图像的强度分布数据，确定强度分布数据阵列和衍射光束强度Is，所述强度分布数据阵列具有与所述精细全息图相同的形状和大小; 并且当衍射光束强度Is取最大值Is（max）时，确定SN比。

公开(公告)号：US20130034805A1

公开(公告)日：2013-02-07

申请号：US13566371

申请日：2012-08-03

申请人： Naoki HAYASHIDA ,  Shohei FUJII ,  Jiro YOSHINARI

发明人： Naoki HAYASHIDA ,  Shohei FUJII ,  Jiro YOSHINARI

IPC分类号： G03F7/004 ,  G03F7/028

CPC分类号： G03F7/001 ,  G03F7/027 ,  G03F7/033 ,  G03H1/0244 ,  G03H2001/0264 ,  G03H2260/12 ,  G11B7/24044 ,  G11B7/245

摘要： A hologram recording material includes a polymerizable monomer (A) that is active in radical polymerization but is substantially inactive in cationic polymerization, a polymerizable monomer (B) that is active in cationic polymerization but is substantially inactive in radical polymerization, and an initiator system (C) that polymerizes at least one of the polymerizable monomer (A) and the polymerizable monomer (B) through irradiation with light. The polymerizable monomer (A) and the polymerizable monomer (B) each have, in its structure, a moiety selected from the group consisting of aromatic rings, halogen atoms other than a fluorine atom, and sulfur atoms not derived from a cyclic sulfide or a mercapto group. A hologram recording medium includes a recording layer composed of the hologram recording material.

摘要翻译： 全息记录材料包括在自由基聚合中有活性但在阳离子聚合中基本上无活性的可聚合单体（A），在阳离子聚合中有活性但在自由基聚合中基本上无活性的可聚合单体（B）和引发剂体系 C）通过照射聚合聚合性单体（A）和聚合性单体（B）中的至少一种。 可聚合单体（A）和可聚合单体（B）在其结构中各自具有选自芳环，除氟原子以外的卤素原子的部分和不衍生自环硫醚的硫原子 巯基。 全息记录介质包括由全息图记录材料构成的记录层。

公开(公告)号：US20120086993A1

公开(公告)日：2012-04-12

申请号：US13226119

申请日：2011-09-06

申请人： Naoki HAYASHIDA ,  Kazushi TANAKA ,  Jiro YOSHINARI

发明人： Naoki HAYASHIDA ,  Kazushi TANAKA ,  Jiro YOSHINARI

IPC分类号： G03H1/02 ,  G03H1/26

CPC分类号： G11B7/245 ,  G03H2001/2271 ,  G03H2260/12 ,  G11B7/24044

摘要： A photopolymer medium 10 for color hologram image recording, which is formed so that a color image having a high diffraction efficiency can be obtained by exposing the same recording layer to light at a plurality of wavelengths, includes a recording layer 14 that has a recording sensitivity to light in two wavelength regions of a wavelength λ1 and a wavelength λ2. This recording layer 14 is formed from a material in which a transmittance T1 of light at the wavelength λ1 and a transmittance T2 of light at the wavelength λ2 of the recording layer before recording are both less than 80%, T1 T1, and 10%

摘要翻译： 用于彩色全息图像记录的光聚合物介质10被形成为使得通过将相同的记录层暴露于多个波长的光可以获得具有高衍射效率的彩色图像，该记录层具有记录灵敏度 以在波长λ1和波长λ2的两个波长区域中点亮。 该记录层14由在记录前记录层的波长λ1的光的透射率T1和记录层的波长λ2的光的透过率T2都小于80％，T1 T1，10％

公开(公告)号：US20090305146A1

公开(公告)日：2009-12-10

申请号：US12457094

申请日：2009-06-01

申请人： Naoki HAYASHIDA ,  Atsuko KOSUDA ,  Motohiro INOUE ,  Jiro YOSHINARI

发明人： Naoki HAYASHIDA ,  Atsuko KOSUDA ,  Motohiro INOUE ,  Jiro YOSHINARI

IPC分类号： G03F7/004

CPC分类号： G03F7/001 ,  G03F7/0043 ,  G03F7/11 ,  G03F7/168 ,  G11B7/0065 ,  G11B7/24044 ,  G11B7/245 ,  G11B7/26

摘要： An optical recording medium includes a support substrate and an information recording layer which is supported on the support substrate and made of a photosensitive material which is irradiated with light to be refractive index modulated and amplitude modulated, thereby recording information. The information recording layer has the shape of a coating which is formed by applying a photosensitive material reversibly dissolved or dispersed in an organic solvent onto the support substrate. The photosensitive material in the shape of a coating, as a photopolymer for hologram recording material, contains the cross-linked matrix to maintain the rigidity of the recording material. The optical recording medium is retained in shape with stability, and particularly prevented from being deformed due to shrinkage, thereby facilitating manufacturing of the optical recording medium.

摘要翻译： 光学记录介质包括支撑基板和信息记录层，该信息记录层被支撑在支撑基板上并且被照射到被折射率调制和调幅的光的感光材料制成，从而记录信息。 信息记录层具有通过将可逆地溶解或分散在有机溶剂中的感光材料施加到支撑基板上而形成的涂层的形状。 作为全息记录材料的光聚合物的涂层形状的感光材料包含交联基质以保持记录材料的刚性。 光学记录介质保持稳定的形状，并且特别防止由于收缩而变形，从而有助于光学记录介质的制造。

公开(公告)号：US20090186281A1

公开(公告)日：2009-07-23

申请号：US12356979

申请日：2009-01-21

申请人： Atsuko KOSUDA ,  Naoki HAYASHIDA ,  Jiro YOSHINARI ,  Toshimi FUKUI ,  Junko NAKAMOTO ,  Saori YAMAKI ,  Heidy Hodex Visbal MENDOZA

发明人： Atsuko KOSUDA ,  Naoki HAYASHIDA ,  Jiro YOSHINARI ,  Toshimi FUKUI ,  Junko NAKAMOTO ,  Saori YAMAKI ,  Heidy Hodex Visbal MENDOZA

IPC分类号： G03F7/00

CPC分类号： G03F7/001 ,  G03F7/0047

摘要： The present invention provides a method for producing a homogeneous complex oxide sol comprising Si and a metal other than Si as metal elements, and a method for producing a Si-containing hologram recording material using a homogeneous complex oxide sol. A method for producing a complex oxide sol comprising Si and a metal other than Si as metal elements, the method comprising: mixing a silanol compound with an alkoxide compound of a metal other than Si so that the silanol compound is reacted with the alkoxide compound, thereby yielding a precursor of a complex oxide, and adding water to the complex oxide precursor so as to hydrolyze an alkoxyl group bonded to the metal other than Si, and then making the resulting hydrolysate undergo a condensation reaction, thereby forming a complex oxide. A hologram recording medium (11) having a hologram recording layer (21) comprising the hologram recording material obtained by the production method.

摘要翻译： 本发明提供一种均匀的复合氧化物溶胶的制造方法，其包含Si和除了Si之外的金属作为金属元素，以及使用均匀复合氧化物溶胶制备含Si全息图记录材料的方法。 一种制备包含Si和除Si之外的金属作为金属元素的复合氧化物溶胶的方法，所述方法包括：将硅烷醇化合物与Si之外的金属的醇盐化合物混合，使得硅烷醇化合物与烷氧基化合物反应， 从而得到复合氧化物的前体，并向复合氧化物前体加水以水解与Si以外的金属键合的烷氧基，然后使得到的水解产物发生缩合反应，从而形成复合氧化物。 具有全息图记录层（21）的全息记录介质（11）包括通过该制造方法获得的全息图记录材料。

公开(公告)号：US20100247839A1

公开(公告)日：2010-09-30

申请号：US12708052

申请日：2010-02-18

申请人： Naoki HAYASHIDA ,  Atsuko KOSUDA ,  Motohiro INOUE ,  Jiro YOSHINARI

发明人： Naoki HAYASHIDA ,  Atsuko KOSUDA ,  Motohiro INOUE ,  Jiro YOSHINARI

IPC分类号： B32B3/02

CPC分类号： G03F7/001 ,  G03F7/0043 ,  G03F7/0757

摘要： A hologram recording medium includes a glass substrate and an information recording layer supported on the glass substrate. The information recording layer is formed of a photosensitive material having a dynamic storage elastic modulus of 1.0×105 Pa or more as measured at 80° C. and a measurement frequency of 1 Hz after interference exposure or post-curing. The photosensitive material is dissolvable or dispersible in an organic solvent, and the information recording layer has sufficient storage stability that allows recorded signals to be stably held for at least 100 hours or longer at 80° C.

摘要翻译： 全息记录介质包括玻璃基板和支撑在玻璃基板上的信息记录层。 信息记录层由在80℃下测得的动态储能弹性模量为1.0×10 5 Pa或更高的感光材料和干涉曝光或后固化后的1Hz测量频率形成。 感光材料可溶于或分散在有机溶剂中，信息记录层具有足够的储存稳定性，使记录信号在80℃下稳定保持至少100小时或更长时间。

公开(公告)号：US20080193857A1

公开(公告)日：2008-08-14

申请号：US12021686

申请日：2008-01-29

申请人： Atsuko KOSUDA ,  Naoki HAYASHIDA ,  Jiro YOSHINARI

发明人： Atsuko KOSUDA ,  Naoki HAYASHIDA ,  Jiro YOSHINARI

IPC分类号： G03F1/14

CPC分类号： G03F7/001 ,  C08G65/18 ,  C08G65/3322 ,  G03F7/032 ,  G03F7/0757 ,  G03H1/02 ,  G03H2001/0264 ,  G03H2250/43 ,  G03H2260/12 ,  G11B7/24044 ,  G11B7/245 ,  G11B7/2492

摘要： The present invention provides a hologram recording material which is suitable for volume hologram record and attains high refractive index change, flexibility, high sensitivity, low scattering, environment resistance, durability, low shrinkage and high multiplicity in holographic memory record using not only a green laser but also a blue laser; a process for producing the same; and a hologram recording medium having the hologram recording material. A hologram recording material comprising: a metal oxide containing at least Si and Zr as metals wherein a β-dicarbonyl compound is coordinated to Zr; and a photopolymerizable compound, wherein a mole ratio of the β-dicarbonyl compound to the Zr atom (β-dicarbonyl compound/Zr ratio) is 2/1 or more and 3/1 or less, and a mole ratio of the Si atom to the Zr atom (Si/Zr ratio) is more than 1/1 and 1.15/1 or less in the metal oxide. A hologram recording medium (11) comprising the hologram recording material layer (21).

摘要翻译： 本发明提供一种全息记录材料，其适用于体积全息记录，并且在全息记录记录中不仅使用绿色激光，而且获得高折射率变化，柔性，高灵敏度，低散射，环境耐久性，耐久性，低收缩率和高倍数 也是一个蓝色激光; 其制造方法; 以及具有全息图记录材料的全息图记录介质。 一种全息记录材料，包括：至少含有Si和Zr作为金属的金属氧化物，其中β-二羰基化合物与Zr配位; 和β-二羰基化合物与Zr原子的摩尔比（β-二羰基化合物/ Zr比）为2/1以上3/1以下的光聚合性化合物，Si原子与 Zr原子（Si / Zr比）在金属氧化物中大于1/1和1.15 / 1以下。 包括全息记录材料层（21）的全息记录介质（11）。

公开(公告)号：US20080057405A1

公开(公告)日：2008-03-06

申请号：US11847819

申请日：2007-08-30

申请人： Jiro YOSHINARI ,  Atsuko Kosuda ,  Naoki Hayashida

发明人： Jiro YOSHINARI ,  Atsuko Kosuda ,  Naoki Hayashida

IPC分类号： G03F7/00

CPC分类号： G03F7/001 ,  G03F7/0043

摘要： The present invention provides a hologram recording medium which can attain high refractive index change, flexibility, high sensitivity, low scattering, environment resistance, durability, low dimension change (low shrinkage) and high multiplicity in holographic memory record using a blue laser. A hologram recording medium (11) comprising at least a hologram recording material layer, wherein the hologram recording material layer (21) comprises at least a metal oxide and a photopolymerizable compound; and said hologram recording medium has a light transmittance of 50% or more at a wavelength of 405 nm, or a light reflectance of 25% or more at a wavelength of 405 nm.

摘要翻译： 本发明提供一种全息图记录介质，其能够使用蓝色激光获得全息记录记录中的高折射率变化，柔性，高灵敏度，低散射性，耐环境性，耐久性，低尺寸变化（低收缩）和高倍数。 包括至少全息记录材料层的全息记录介质（11），其中全息记录材料层（21）至少包含金属氧化物和可光聚合化合物; 并且所述全息记录介质的波长为405nm时的透光率为50％以上，波长405nm的光反射率为25％以上。