摘要:
A polymeric solid electrolyte is composed of a polymer that contains an electrolyte salt and an organic solvent. The organic solvent is composed of a fluorinated organic solvent. The polymer solid electrolyte can retain a sufficiently high ion conductivity and provides excellent safety by exhibiting flame retardancy when heated.
摘要:
A lithium secondary battery which comprises: a negative electrode comprising as an active material a carbonaceous material capable of electrochemically holding/releasing lithium; a positive electrode comprising as an active material a lithium chalcogenide; and polymer electrolyte layers united respectively with the negative electrode and the positive electrode. The polymer electrolyte layers comprise an ionically conductive polymer matrix holding a nonaqueous electrolytic solution. They are obtained by crosslinking and polymerizing a liquid mixture of a monomeric precursor for the ionically conductive polymer and the nonaqueous electrolytic solution respectively on the negative electrode and the positive electrode using different polymerization initiators.
摘要:
A lithium polymer secondary cell having a negative electrode, a positive electrode and, arranged between the electrodes, a polymer electrolyte layer, characterized in that the cell has been subjected to a heat treatment at a temperature of 40 to 60° C. after the assembly thereof. The polymer cell is freed of or is reduced in the adverse effect of a residual monomer and initiator on the performance of the cell. The polymer electrolyte is formed by cross-linking polymerization of a precursor monomer for an ion conducting polymer in a non-aqueous electrolyte, and the residual monomer and initiator contained therein is consumed by the heat treatment.
摘要:
A lithium secondary battery which comprises a negative electrode, a positive electrode, and disposed therebetween a polymer electrolyte comprising an ionically conductive polymer. The polymer electrolyte has a two-layer structure composed of a positive-electrode-side layer and a negative-electrode-side layer. The polymer electrolyte on the positive-electrode side contains a nonaqueous electrolytic solution containing a lithium salt in a higher concentration than that in the polymer electrolyte on the negative-electrode side. The battery is improved in charge/discharge cycling characteristics and high-load discharge characteristics.
摘要:
A lithium polymer secondary battery which comprises a negative electrode, a positive electrode, and polymer electrolyte layers united respectively with the two electrodes and differing in viscoelastic behavior. In this battery, conformation to the expansion and shrinkage accompanying charge/discharge is easy and the interfacial resistance between each electrode and the polymer electrolyte is kept low.
摘要:
A polymer battery which comprises a negative electrode comprising a carbon material as an active material, an electrolyte layer and a positive electrode comprising a chalcogenide containing lithium as an active material, characterized in that the electrolyte layer comprises an ion-conducting compound and a polymer fiber, and the carbon material comprises the graphite particles having amorphous carbon adhered on the surface thereof. The polymer battery is capable of preventing the decomposition of the ion-conductive material by graphite particles.
摘要:
In a lithium secondary cell having a negative electrode, a positive electrode and, arranged between the electrodes, a polymer electrolyte layer, the internal resistance of the cell and the interfacial resistance between the electrode and the polymer electrolyte can be reduced by incorporating into the electrode, in advance, a polymer electrolyte precursor solution in a manner such that the electrode has a higher content of the precursor monomer and/or an oligomer thereof than that in the polymer electrolyte layer formed on the electrode.
摘要:
In a lithium secondary cell having a negative electrode, a positive electrode and, arranged between the electrodes, a polymer electrolyte layer, the internal resistance of the cell and the interfacial resistance between the electrode and the polymer electrolyte can be reduced by incorporating into the electrode, in advance, a polymer electrolyte precursor solution in a manner such that the electrode has a higher content of the precursor monomer and/or an oligomer thereof than that in the polymer electrolyte layer formed on the electrode.
摘要:
A lithium secondary battery includes a positive electrode containing a first solid electrolyte; a negative electrode containing a second solid electrolyte; and a layer of a third solid electrolyte between the positive and negative electrodes.
摘要:
A process of preparing lithium nickel oxide as a positive electrode active material comprising: dissolving a water-soluble lithium compound and a water-soluble nickel compound in water to prepare a homogeneous aqueous solution; co-precipitating, from the aqueous solution, a lithium salt and a nickel salt which are slightly soluble in water; isolating the resulting co-precipitate and calcining the co-precipitate to obtain lithium nickel oxide.