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公开(公告)号：US07699941B2
公开(公告)日：2010-04-20
申请号：US11608134
申请日：2006-12-07
CPC分类号： C11D11/0058 , C11D3/3773 , C11D3/3776 , C11D3/378 , C11D3/3784 , C11D11/0035
摘要： Treated articles with improved water sheeting and soap scum repellency result from forming hydroscopic films on the surfaces of hydrophobic polymeric substrates treated with compositions, kits and methods that employ water-soluble or water-dispersible copolymers having: (i) a first monomer that is capable of forming a cationic charge on protonation; (ii) a second monomer that is acidic and that is capable of forming an anionic charge in the compositions; (iii) optionally, a third monomer having an uncharged hydrophilic group; and (iv) optionally, a fourth monomer that is hydrophobic. Treated articles exhibit a Water Sheeting Index of greater than 6. Treated articles may further exhibit improved soap scum repellency behavior compared to untreated articles.
摘要翻译： 具有改进的水薄片和皂泡斥散性的处理制品是由使用水溶性或水分散性共聚物的组合物，试剂盒和方法处理的疏水聚合物基材表面上形成吸水膜导致的，所述水溶性或水分散性共聚物具有：（i）能够 在质子化时形成阳离子电荷; （ii）酸性并且能够在组合物中形成阴离子电荷的第二单体; （iii）任选的具有不带电荷的亲水基团的第三单体; 和（iv）任选的是疏水性的第四单体。 经处理的制品表现出大于6的水面指数。与未处理的制品相比，处理的制品可能进一步显示出改进的皂泡排斥性能。
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公开(公告)号：US07470290B2
公开(公告)日：2008-12-30
申请号：US11176472
申请日：2005-07-06
申请人： Klin A. Rodrigues , David R. Scheuing , Michael H. Robbins , Nicholas Pivonka , David L. Budd , Malcolm A. Deleo
发明人： Klin A. Rodrigues , David R. Scheuing , Michael H. Robbins , Nicholas Pivonka , David L. Budd , Malcolm A. Deleo
CPC分类号： C11D11/0058 , C11D3/3773 , C11D3/3776 , C11D3/378 , C11D3/3784 , C11D11/0035
摘要： Hydroscopic polymer gels can be formed by applying a polymer to a surface and allowing water to be sequestered from the atmosphere into the polymer. The polymer gels are formed using methods and compositions employing water soluble or water dispersible copolymers having: (i) a first monomer that is acidic and is capable of forming an anionic charge in the composition; (ii) a second monomer that is amphipathic; (iii) optionally, a third monomer that is hydrophobic; and (iv) optionally, a fourth monomer that that has a permanent cationic charge or that is capable of forming a cationic charge on protonation. The polymer gels are particularly substantive and effective at modifying surfaces such as glass and hydrophobic polymeric substrates to provide soap scum and soil resistance, and easier next time cleaning benefits.
摘要翻译： 可以通过将聚合物施加到表面并且允许水从大气中隔离到聚合物中来形成液体聚合物凝胶。 使用具有以下成分的水溶性或水分散性共聚物的方法和组合物形成聚合物凝胶：（i）第一单体为酸性且能够在组合物中形成阴离子电荷; （ii）两亲性的第二单体; （iii）任选的是疏水性的第三单体; 和（iv）任选地，具有永久阳离子电荷或能够在质子化上形成阳离子电荷的第四单体。 聚合物凝胶在改性表面如玻璃和疏水性聚合物基材上特别实用和有效，以提供肥皂浮渣和土壤抗性，并且更容易下次清洗益处。
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公开(公告)号：US20100160487A1
公开(公告)日：2010-06-24
申请号：US12714283
申请日：2010-02-26
IPC分类号： C08L33/12 , C09D177/00
CPC分类号： C11D11/0058 , C11D3/3773 , C11D3/3776 , C11D3/378 , C11D3/3784 , C11D11/0035
摘要： Treated articles with improved water sheeting and soap scum repellency result from forming hydroscopic films on the surfaces of hydrophobic polymeric substrates treated with compositions, kits and methods that employ water-soluble or water-dispersible copolymers having: (i) a first monomer that is capable of forming a cationic charge on protonation; (ii) a second monomer that is acidic and that is capable of forming an anionic charge in the compositions; (iii) optionally, a third monomer having an uncharged hydrophilic group; and (iv) optionally, a fourth monomer that is hydrophobic. Treated articles exhibit a Water Sheeting Index of greater than 6. Treated articles may further exhibit improved soap scum repellency behavior compared to untreated articles.
摘要翻译： 具有改进的水薄片和皂泡斥散性的处理制品是由使用水溶性或水分散性共聚物的组合物，试剂盒和方法处理的疏水聚合物基材表面上形成吸水膜导致的，所述水溶性或水分散性共聚物具有：（i）能够 在质子化时形成阳离子电荷; （ii）酸性并且能够在组合物中形成阴离子电荷的第二单体; （iii）任选的具有不带电荷的亲水基团的第三单体; 和（iv）任选的是疏水性的第四单体。 经处理的制品表现出大于6的水面指数。与未处理的制品相比，处理的制品可以进一步显示出改善的皂泡排斥性能。
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公开(公告)号：US07511008B2
公开(公告)日：2009-03-31
申请号：US11854885
申请日：2007-09-13
CPC分类号： C11D3/378 , C11D1/004 , C11D3/222 , C11D3/227 , C11D3/3707 , C11D3/3723 , C11D3/3746 , C11D3/3757 , C11D3/3769 , C11D3/3776 , C11D3/3796 , C11D3/38
摘要： The present invention relates to associative complexes of water soluble and/or water dispersible polymers and polymeric fluorosurfactants, compositions and methods for modifying substrates to provide treated articles with surface protective properties including easier cleaning, increased stain and/or soil repellency, and increased resistance to bio-fouling and environmental contamination.
摘要翻译： 本发明涉及水溶性和/或水分散性聚合物和聚合氟表面活性剂的缔合复合物，用于改性基材以提供具有表面保护性质的处理制品的组合物和方法，包括更容易的清洁，增加的污渍和/或防污性，以及增加的抗性 生物污染和环境污染。
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公开(公告)号：US07288514B2
公开(公告)日：2007-10-30
申请号：US11105819
申请日：2005-04-14
CPC分类号： C11D3/378 , C11D1/004 , C11D3/222 , C11D3/227 , C11D3/3707 , C11D3/3723 , C11D3/3746 , C11D3/3757 , C11D3/3769 , C11D3/3776 , C11D3/3796 , C11D3/38
摘要： The present invention relates to associative complexes of water soluble and/or water dispersible polymers and polymeric fluorosurfactants, compositions and methods for modifying substrates to provide treated articles with surface protective properties including easier cleaning, increased stain and/or soil repellency, and increased resistance to bio-fouling and environmental contamination.
摘要翻译： 本发明涉及水溶性和/或水分散性聚合物和聚合氟表面活性剂的缔合复合物，用于改性基材以提供具有表面保护性质的处理制品的组合物和方法，包括更容易的清洁，增加的污渍和/或防污性，以及增加的抗性 生物污染和环境污染。
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公开(公告)号：US06245728B1
公开(公告)日：2001-06-12
申请号：US09427175
申请日：1999-10-25
申请人： Michael H. Robbins , Jennifer C. Julian , Suzanne M. Thompson , Gary L. Robinson , Clement K. Choy , Elizabeth A. Gossett
发明人： Michael H. Robbins , Jennifer C. Julian , Suzanne M. Thompson , Gary L. Robinson , Clement K. Choy , Elizabeth A. Gossett
IPC分类号： C11D129
CPC分类号： C11D1/94 , C11D1/02 , C11D1/14 , C11D1/22 , C11D1/62 , C11D1/66 , C11D1/72 , C11D1/75 , C11D1/755 , C11D1/79 , C11D1/835 , C11D1/88 , C11D3/10 , C11D3/33 , C11D3/43 , C11D11/0023 , C11D17/0043
摘要： An aqueous hard surface cleaner with improved soil removal is provided and has, as components, the following: (a) either an anionic, nonionic, amphoteric surfactant, and mixtures thereof with, optionally, a quaternary ammonium surfactant, the total amount of the surfactants being; present in a cleaning effective amount; (b) at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25° C., present in a solubilizing—or dispersion—effective airmount; (c) a combination of (i) an incompletely neutralized potassium ethylenediamine—tetraacetate (EDTA) and (ii) a precipitating co-builder as chelating agents present in an amount effective to enhance soil removal in said cleaner; and (d) the remainder, water.
摘要翻译： 提供了一种具有改进污物去除性能的水性硬表面清洁剂，并且具有以下成分：（a）阴离子，非离子，两性表面活性剂及其与任选的季铵表面活性剂的混合物，表面活性剂的总量 存在; 存在于清洁有效量中;（b）至少一种在25℃下具有至少0.001mm Hg的蒸汽压的水溶性或分散性有机溶剂，存在于增溶或分散有效的空气安装中;（c） （i）不完全中和的乙二胺四乙酸钾（EDTA）和（ii）作为螯合剂的沉淀共助洗剂的组合，其量以有效增强所述清洁剂中去除污垢的量存在; 和（d）余下的水。
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公开(公告)号：US07007338B2
公开(公告)日：2006-03-07
申请号：US10458031
申请日：2003-06-09
申请人： Aram Garabedian, Jr. , Michael J. Hall , Maria G. Ochomogo , Marcus Wang , Andrew Kilkenny , Kaj A. Johnson , Thomas Silk , Michael H. Robbins , Aaron R. London , Dennis Rich , Doug Walker
发明人： Aram Garabedian, Jr. , Michael J. Hall , Maria G. Ochomogo , Marcus Wang , Andrew Kilkenny , Kaj A. Johnson , Thomas Silk , Michael H. Robbins , Aaron R. London , Dennis Rich , Doug Walker
CPC分类号： A47L13/20 , A46B11/0017 , A47L13/12 , A47L13/22 , A47L13/256
摘要： An advanced cleaning system comprising cleaning compositions, pads, and implements provide effective cleaning of soft and hard surfaces. The system includes (a) a handle portion, the handle portion having a proximal end and a distal end, (b) a cleaning head portion that is attached to the distal end of the handle portion and that is adapted for use with a removable cleaning pad; (c) a cradle that is secured to the handle portion, and (d) a detachable cleaning aerosol reservoir for delivering cleaning fluid onto the surface to be cleaned adjacent the cleaning head portion, wherein the reservoir is positioned within the cradle.
摘要翻译： 包括清洁组合物，垫和器具的先进的清洁系统提供对软和硬表面的有效清洁。 所述系统包括（a）把手部分，所述把手部分具有近端和远端，（b）清洁头部分，其附接到所述把手部分的远端并适于与可移除清洁 垫; （c）固定到把手部分的支架，以及（d）可拆卸的清洁气溶胶储存器，用于将清洁流体递送到邻近清洁头部分的待清洁表面上，其中储存器位于支架内。
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公开(公告)号：US5972876A
公开(公告)日：1999-10-26
申请号：US731653
申请日：1996-10-17
IPC分类号： C11D17/08 , C11D1/14 , C11D1/22 , C11D1/62 , C11D1/72 , C11D1/75 , C11D1/755 , C11D1/79 , C11D1/835 , C11D1/94 , C11D3/04 , C11D3/30 , C11D3/33 , C11D3/43 , C11D17/00 , C11D1/83 , B08B3/04 , C11D3/26
CPC分类号： C11D1/94 , C11D1/835 , C11D17/0043 , C11D3/33 , C11D3/43 , C11D1/14 , C11D1/22 , C11D1/62 , C11D1/72 , C11D1/75 , C11D1/755 , C11D1/79
摘要： An aqueous hard surface cleaner with improved soil removal is provided and has, as components, the following:(a) either an anionic, nonionic, amphoteric surfactant, and mixtures thereof with optionally, a quaternary ammonium surfactant, the total amount of the surfactants being present in a cleaning effective amount;(b) at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25.degree. C., present in a solubilizing--or dispersion--effective amount;(c) Tetrapotassium ethylenediamine-tetraacetate (potassium EDTA) as a chelating agent, present in an amount effective to enhance soil removal in said cleaner; and(d) the remainder, water.
摘要翻译： 提供了一种具有改善污垢去除性的水性硬表面清洁剂，并且具有以下成分：（a）阴离子，非离子，两性表面活性剂及其与任选的季铵表面活性剂的混合物，表面活性剂的总量为 存在清洁有效量; （b）至少一种在25℃下蒸气压至少为0.001毫米汞柱的水溶性或分散性有机溶剂，以增溶或分散有效的量存在; （c）作为螯合剂的乙二胺四乙酸四钾（EDTA EDTA），以有效增强所述清洁剂去除污垢的量存在; 和（d）余下的水。
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公开(公告)号：US06399555B2
公开(公告)日：2002-06-04
申请号：US09861049
申请日：2001-05-18
申请人： Michael H. Robbins , Jennifer C. Julian , Suzanne M. Thompson , Gary L. Robinson , Clement K. Choy , Elizabeth A. Gossett
发明人： Michael H. Robbins , Jennifer C. Julian , Suzanne M. Thompson , Gary L. Robinson , Clement K. Choy , Elizabeth A. Gossett
IPC分类号： C11D129
CPC分类号： C11D1/94 , C11D1/02 , C11D1/14 , C11D1/22 , C11D1/62 , C11D1/66 , C11D1/72 , C11D1/75 , C11D1/755 , C11D1/79 , C11D1/835 , C11D1/88 , C11D3/10 , C11D3/33 , C11D3/43 , C11D11/0023 , C11D17/0043
摘要： An aqueous hard surface cleaner with improved soil removal is provided and has, as components, the following: (a) either an anionic, nonionic, amphoteric surfactant, and mixtures thereof with optionally, a quaternary ammonium surfactant, the total amount of the surfactants being present in a cleaning effective amount; (b) at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25° C., present in a solubilizing—or dispersion—effective amount (c) a combination of (i) an incompletely neutralized potassium ethylenediamine—tetraacetate (EDTA) and (ii) a precipitating co-builder as chelating agents present in an amount effective to enhance soil removal in said cleaner; and (d) the remainder, water.
摘要翻译： 提供了一种具有改善污垢去除性的水性硬表面清洁剂，并且具有以下成分：（a）阴离子，非离子，两性表面活性剂及其与任选的季铵表面活性剂的混合物，表面活性剂的总量为 存在于清洁有效量中;（b）至少一种在25℃下蒸气压至少为0.001mm Hg的水溶性或分散性有机溶剂，以增溶或分散有效量存在（c） （i）不完全中和的乙二胺四乙酸钾（EDTA）的组合和（ii）作为螯合剂的沉淀共助洗剂，其用量有效地增强所述清洁剂中的去污; 和（d）余下的水。
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公开(公告)号：US6147047A
公开(公告)日：2000-11-14
申请号：US75805
申请日：1998-05-11
IPC分类号： C11D17/08 , C11D1/02 , C11D1/62 , C11D1/72 , C11D1/83 , C11D1/835 , C11D1/86 , C11D3/20 , C11D3/43 , C11D3/44 , C11D17/00
CPC分类号： C11D1/83 , C11D1/72 , C11D1/835 , C11D17/0021 , C11D3/2003 , C11D3/2068 , C11D3/43 , C11D1/02 , C11D1/62 , C11D3/2006 , C11D3/2041
摘要： A concentrated, dilutable cleaning composition is provided which comprises a microemulsion comprising an oil phase of which the "oil" is a nonionic surfactant, a predominant aqueous continuous phase, a polar organic solvent coupling agent, and a combination of surfactants different from the surfactant oil phase as the dispersing agent facilitating formation of said microemulsion, the cleaning composition dilutable with water for use as an all purpose cleaner and characterized by exhibiting the feature of blooming upon such dilution even in the absence of a lipophilic oil (or solvent). The blooming phenomenon is associated with the formation of a liquid crystal dispersion, which liquid crystal state is found to greatly enhance the cleaning effectiveness of the composition. In one aspect of the invention, one of the dispersing agent surfactants is a cationic surfactant which may be a quaternary ammonium compound capable of imparting an antimicrobial effect to the composition.
摘要翻译： 提供浓缩的可稀释的清洁组合物，其包括微乳液，其包含油相，其中“油”是非离子表面活性剂，主要水性连续相，极性有机溶剂偶联剂和与表面活性剂油不同的表面活性剂的组合 作为促进所述微乳液形成的分散剂，所述清洁组合物可用水稀释，用作全能清洁剂，并且其特征在于即使在不存在亲油性油（或溶剂）的情况下也显示出这种稀释时的起霜特征。 发光现象与液晶分散体的形成有关，发现液晶状态大大提高了组合物的清洁效果。 在本发明的一个方面，分散剂表面活性剂之一是阳离子表面活性剂，其可以是能够赋予组合物抗微生物效果的季铵化合物。
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