-
1.发明授权Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly 有权用于聚合物电解质燃料电池的电解质聚合物，其生产方法和膜 - 电极组装公开(公告)号：US07902311B2
公开(公告)日：2011-03-08
申请号：US12329119
申请日：2008-12-05
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。
-
2.发明授权Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly 有权用于聚合物电解质燃料电池的电解质聚合物，其生产方法和膜 - 电极组装公开(公告)号：US07488788B2
公开(公告)日：2009-02-10
申请号：US11271915
申请日：2005-11-14
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。
-
3.发明申请ELECTROLYTE POLYMER FOR POLYMER ELECTROLYTE FUEL CELLS, PROCESS FOR ITS PRODUCTION AND MEMBRANE-ELECTRODE ASSEMBLY 有权聚合物电解质燃料电池用电解聚合物及其生产工艺及膜电极组件公开(公告)号：US20110091791A1
公开(公告)日：2011-04-21
申请号：US12976446
申请日：2010-12-22
IPC分类号： H01M8/10
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。
-
4.发明授权Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly 有权用于聚合物电解质燃料电池的电解质聚合物，其生产方法和膜 - 电极组装公开(公告)号：US08658746B2
公开(公告)日：2014-02-25
申请号：US12976446
申请日：2010-12-22
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。
-
5.发明申请ELECTROLYTE POLYMER FOR POLYMER ELECTROLYTE FUEL CELLS, PROCESS FOR ITS PRODUCTION AND MEMBRANE-ELECTRODE ASSEMBLY 有权聚合物电解质燃料电池用电解聚合物及其生产工艺及膜电极组件公开(公告)号：US20090088539A1
公开(公告)日：2009-04-02
申请号：US12329119
申请日：2008-12-05
IPC分类号： C08F2/34
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译： 提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液 和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。 本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。
-
公开(公告)号：US20060063903A1
公开(公告)日：2006-03-23
申请号：US11271915
申请日：2005-11-14
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
-
7.发明申请Membrane-electrode assembly for polymer electrolyte fuel cells, and polymer electrolyte fuel cell 有权用于聚合物电解质燃料电池的膜 - 电极组件和聚合物电解质燃料电池公开(公告)号：US20060046121A1
公开(公告)日：2006-03-02
申请号：US11213888
申请日：2005-08-30
CPC分类号： H01M8/0271 , H01M8/0289 , H01M8/1016 , H01M8/1058 , H01M2008/1095
摘要： The present invention provides a membrane-electrode assembly for polymer electrolyte fuel cells and a polymer electrolyte fuel cell having excellent dimensional stability and mechanical strength, and having high durability at the time of a power generation. Each of polymer electrolyte membranes (111, 211, 311) have a region 1 having proton conductivity over the entirety in the thickness direction of the membrane and a region 2 located at the outer peripheral portion of the region 1 and having a non-porous sheet disposed so that the region 2 has no proton conductivity over the entirety in the thickness direction of the membrane, and outer edges of the catalyst layers (127, 128) are disposed so as to be located in the area 2.
摘要翻译： 本发明提供一种聚合物电解质燃料电池用的膜 - 电极组件和具有优异的尺寸稳定性和机械强度并且在发电时具有高耐久性的固体高分子型燃料电池。 高分子电解质膜（111,211,311）各自具有在膜的厚度方向上整体上具有质子传导性的区域1和位于区域1的外周部分的具有无孔片材的区域2 被设置为使得区域2在膜的厚度方向上整体上没有质子传导性，并且催化剂层（127,128）的外边缘被设置为位于区域2中。
-
8.发明授权Membrane-electrode assembly for polymer electrolyte fuel cells, and polymer electrolyte fuel cell 有权用于聚合物电解质燃料电池的膜 - 电极组件和聚合物电解质燃料电池公开(公告)号：US07521144B2
公开(公告)日：2009-04-21
申请号：US11213888
申请日：2005-08-30
CPC分类号： H01M8/0271 , H01M8/0289 , H01M8/1016 , H01M8/1058 , H01M2008/1095
摘要： The present invention provides a membrane-electrode assembly for polymer electrolyte fuel cells and a polymer electrolyte fuel cell having excellent dimensional stability and mechanical strength, and having high durability at the time of a power generation. Each of polymer electrolyte membranes (111, 211, 311) have a region 1 having proton conductivity over the entirety in the thickness direction of the membrane and a region 2 located at the outer peripheral portion of the region 1 and having a non-porous sheet disposed so that the region 2 has no proton conductivity over the entirety in the thickness direction of the membrane, and outer edges of the catalyst layers (127, 128) are disposed so as to be located in the area 2.
摘要翻译： 本发明提供一种聚合物电解质燃料电池用的膜 - 电极组件和具有优异的尺寸稳定性和机械强度并且在发电时具有高耐久性的固体高分子型燃料电池。 高分子电解质膜（111,211,311）各自具有在膜的厚度方向上整体上具有质子传导性的区域1和位于区域1的外周部分的具有无孔片材的区域2 被设置为使得区域2在膜的厚度方向上整体上没有质子传导性，并且催化剂层（127,128）的外边缘被设置为位于区域2中。
-
9.发明授权公开(公告)号：US07582713B2
公开(公告)日：2009-09-01
申请号：US11030295
申请日：2005-01-07
申请人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
发明人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
IPC分类号： C08F12/30
CPC分类号： C08J5/2293 , C08F30/04 , C08F130/04 , C08F230/04 , C08J3/05 , C08J5/20 , C08J2327/12 , C08J2327/18 , H01M4/8605 , H01M4/8803 , H01M4/8828 , H01M4/921 , H01M4/96 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/1081 , Y02P70/56 , Y10T428/24802
摘要： A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25° C. at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.
摘要翻译： 通过对具有磺酸基的氟化聚合物作为离子交换聚合物均匀分散在分散介质中的离子交换聚合物分散体施加超声波振动或剪切力，使得分散体在25℃下的粘度 在10（1 / s）的剪切速率下，在增稠步骤中增加2-2000次。 当形成膜时，分散体可以形成具有均匀且小的厚度，高强度的离子交换膜，其没有破裂并且在水和蒸汽中显示恒定的溶胀。 此外，可以使用通过将含有该分散体的涂布溶液和包含催化剂金属颗粒的催化剂粉末和负载有催化剂金属颗粒的碳载体的催化剂粉末涂布到基板上而形成的层，以制备作为催化剂层的膜 - 电极组件 通过相对于离子交换膜提供催化剂层，阴极和阳极中的至少一个。 由于催化剂层强度高，缺点少，光滑性好，因此可以得到固体高分子电解质燃料电池用高性能膜 - 电极组件。
-
10.发明申请公开(公告)号：US20050143540A1
公开(公告)日：2005-06-30
申请号：US11030295
申请日：2005-01-07
申请人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
发明人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
IPC分类号： C08F30/04 , C08F130/04 , C08F230/04 , C08J3/03 , C08J5/20 , H01M4/86 , H01M4/88 , H01M4/92 , H01M4/96
CPC分类号： C08J5/2293 , C08F30/04 , C08F130/04 , C08F230/04 , C08J3/05 , C08J5/20 , C08J2327/12 , C08J2327/18 , H01M4/8605 , H01M4/8803 , H01M4/8828 , H01M4/921 , H01M4/96 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/1081 , Y02P70/56 , Y10T428/24802
摘要： A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25° C. at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.
摘要翻译： 通过对具有磺酸基的氟化聚合物作为离子交换聚合物均匀分散在分散介质中的离子交换聚合物分散体施加超声波振动或剪切力，使得分散体在25℃下的粘度 在10（1 / s）的剪切速率下，在增稠步骤中增加2-2000次。 当形成膜时，分散体可以形成具有均匀且小的厚度，高强度的离子交换膜，其没有破裂并且在水和蒸汽中显示恒定的溶胀。 此外，可以使用通过将含有该分散体的涂布溶液和包含催化剂金属颗粒的催化剂粉末和负载有催化剂金属颗粒的碳载体的催化剂粉末涂布到基板上形成的层来制备作为催化剂层的膜 - 电极组件 通过相对于离子交换膜提供催化剂层，阴极和阳极中的至少一个。 由于催化剂层强度高，缺点少，光滑性好，因此可以得到固体高分子电解质燃料电池用高性能膜 - 电极组件。
-
-
-
-
-
-
-
-
-
搜索结果
36 条记录 (耗时 0.026 秒)
