Thermoplastic Resin Composition and Optical Films Made Therefrom
    1.
    发明申请
    Thermoplastic Resin Composition and Optical Films Made Therefrom 审中-公开
    热塑性树脂组合物和制造的光学膜

    公开(公告)号:US20080095955A1

    公开(公告)日:2008-04-24

    申请号:US11813054

    申请日:2005-12-22

    IPC分类号: C09K19/00 C08F8/00 C08L29/00

    摘要: The thermoplastic resin composition of the present invention comprises (A) a cycloolefin-based polymer and (B) a vinyl-based polymer having a polar group, has a glass transition temperature of not lower than 100° C. and has a difference in glass transition temperature between the polymers (A) and (B) of less than 50° C. The optical film of the present invention comprises the thermoplastic resin composition of the invention. According to the present invention, it is possible to improve development of retardation at a low stress in the film stretching while retaining excellent heat resistance and optical properties and maintaining wavelength dispersion properties. The optical film of the invention exhibits properties that the dependence of retardation of a transmitted light on wavelength, said retardation being obtained by stretch orientation of the film, becomes larger as the wavelength becomes longer (positive wavelength dispersion properties), has low water absorption and low coefficient of photoelasticity, and is excellent in adhesion or bonding properties to other materials.

    摘要翻译: 本发明的热塑性树脂组合物包含(A)环烯烃系聚合物和(B)具有极性基团的乙烯基系聚合物,玻璃化转变温度为100℃以上,玻璃化度不同 聚合物(A)和(B)之间的转变温度低于50℃。本发明的光学膜包含本发明的热塑性树脂组合物。 根据本发明,可以在保持优异的耐热性和光学性能并保持波长分散性的同时,改善膜拉伸中的低应力下的延迟的发展。 本发明的光学薄膜具有以下性质:随着波长越长(正波长色散特性),透射光的延迟与波长的拉伸取向相关的延迟越大,吸水率低, 光弹性系数低,与其他材料的粘合性或粘合性优异。

    Thermoplastic Resin Composition, Optical Film And Oriented Film
    2.
    发明申请
    Thermoplastic Resin Composition, Optical Film And Oriented Film 审中-公开
    热塑性树脂组合物,光学膜和定向膜

    公开(公告)号:US20070282077A1

    公开(公告)日:2007-12-06

    申请号:US11722931

    申请日:2005-12-27

    IPC分类号: C08L67/04

    摘要: The present invention is intended to provide a thermoplastic resin composition which exhibits excellent compatibility while retaining low birefringence and is excellent in weathering resistance and heat resistance, an optical film which is obtained from the thermoplastic resin composition and a retardation film which is excellent in weathering resistance and heat resistance and has reciprocal wavelength dispersion properties. The thermoplastic resin composition comprises a vinyl-based polymer (A) having a unit represented by the following formula (I) and a cycloolefin-based polymer (B). wherein R1 to R3 are each a hydrogen atom, a halogen atom, a substituted or unsubstituted hydrocarbon group of 1 to 30 carbon atoms which may have a linkage containing an oxygen atom, a sulfur atom, a nitrogen atom or a silicon atom, or a polar group, and n is 0 or a positive integer.

    摘要翻译: 本发明旨在提供一种热塑性树脂组合物,其具有优异的相容性,同时保持低双折射并且耐候性和耐热性优异,由热塑性树脂组合物获得的光学膜和耐候性优异的延迟膜 和耐热性并具有相互的波长分散性。 热塑性树脂组合物包含具有由下式(I)表示的单元的乙烯基类聚合物(A)和环烯烃系聚合物(B)。 其中R 1至R 3各自为氢原子,卤素原子,取代或未取代的可具有含氧键的1至30个碳原子的烃基 原子,硫原子,氮原子或硅原子或极性基团,n为0或正整数。

    Thermoplastic Resin Composition, Optical Film, And Process For Producing Film
    4.
    发明申请
    Thermoplastic Resin Composition, Optical Film, And Process For Producing Film 审中-公开
    热塑性树脂组合物,光学膜及其制造方法

    公开(公告)号:US20080177002A1

    公开(公告)日:2008-07-24

    申请号:US11813382

    申请日:2005-12-27

    IPC分类号: C08L45/00 G02B1/04

    摘要: The present invention is intended to provide a thermoplastic resin composition which is inhibited from suffering phase separation and from which an optical film having excellent transparency is readily obtained, an optical film containing the composition as a main component, a retardation film which is a film obtained by stretching the optical film and exhibits positive wavelength dependence and has a small coefficient of photoelasticity and transparency, and a process for producing the retardation film. The thermoplastic resin composition contains (A) a cycloolefin-based polymer and (B) a vinyl-based polymer having a unit represented by the following formula (II): wherein at least one of R1 to R4 is a group represented by the formula (III), the remainder of R1 to R4 if any, and R5 and R6 are each a hydrogen atom, a halogen atom, a substituted) hydrocarbon group which may have a linkage containing a hetero atom, or a polar group, R5 and R6 may be bonded to each other to form a monocyclic or polycyclic group which may have a hetero atom, or may be united to form a divalent hydrocarbon group and Y is a divalent hydrocarbon group.

    摘要翻译: 本发明旨在提供一种热塑性树脂组合物,其被抑制相分离,容易获得具有优异透明性的光学膜,含有该组合物作为主要成分的光学膜,作为获得的膜的相位差膜 通过拉伸光学膜并呈现正的波长依赖性并且具有小的光弹性和透明度系数以及用于制造延迟膜的工艺。 该热塑性树脂组合物含有(A)环烯烃系聚合物和(B)具有下述式(II)所示的单元的乙烯基系聚合物,其中,R 1〜R 4中的至少1个 4是由式(III)表示的基团,R 1至R 4的剩余部分(如果有的话)和R 5 R 6和R 6各自为氢原子,卤素原子,可具有含杂原子键的取代的烃基或极性基团R 5, / SUP>和R 6可以彼此键合以形成可以具有杂原子的单环或多环基团,或可以一起形成二价烃基,Y是二价烃基 。

    NORBORNENE DERIVATIVE, NORBORNENE POLYMER PRODUCED BY RING-OPENING (CO)POLYMERIZATION, AND PROCESS FOR PRODUCING THE POLYMER BY RING-OPENING (CO)POLYMERIZATION
    5.
    发明申请
    NORBORNENE DERIVATIVE, NORBORNENE POLYMER PRODUCED BY RING-OPENING (CO)POLYMERIZATION, AND PROCESS FOR PRODUCING THE POLYMER BY RING-OPENING (CO)POLYMERIZATION 有权
    NORBORNENE衍生物,通过开环(CO)聚合制备的NORBENNENE聚合物,以及通过开环(CO)聚合制备聚合物的方法

    公开(公告)号:US20090247798A1

    公开(公告)日:2009-10-01

    申请号:US12416451

    申请日:2009-04-01

    IPC分类号: C07C13/567

    摘要: The norbornene derivative of the present invention is represented by the following formula (Im). According to the present invention, a novel norbornene derivative that is useful as a precursor monomer for preparing a cycloolefin polymer exhibiting excellent transparency, heat resistance and low-water absorption properties and having been freely controlled in the birefringence properties and the wavelength dispersion properties can be provided. According to the present invention, further, a norbornene ring-opened (co)polymer having excellent transparency and heat resistance, exhibiting high solubility in organic solvents and having specific birefringence properties and wavelength dependence, and a process for preparing the ring-opened (co)polymer can be provided.

    摘要翻译: 本发明的降冰片烯衍生物由下式(Im)表示。 根据本发明,作为用于制备具有优异的透明性,耐热性和低吸水性的环烯烃聚合物的前体单体的新型降冰片烯衍生物可以在双折射性和波长分散性中自由控制, 提供。 根据本发明,另外,具有优异的透明性和耐热性,在有机溶剂中显示出高溶解性并具有特定的双折射性和波长依赖性的降冰片烯开环(共)聚合物,以及制备开环(共 )聚合物。