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公开(公告)号：US20090171025A1
公开(公告)日：2009-07-02
申请号：US12088799
申请日：2006-10-02
IPC分类号： C08F283/12
CPC分类号： C09K3/1018 , C08G65/336 , C08K5/3462 , C08L71/02 , C08L101/10
摘要： The present invention has its object to provide, by using a non-organotin curing catalyst, a curable composition having a practical level of curability. Furthermore, the present invention has its object to provide a curable composition excellent in adhesiveness while it secures a practical level of curability.The present invention relates to a curable composition which comprises:(A) an organic polymer containing a silicon-containing group capable of crosslinking by siloxane bond formation and (B) a silanol condensation catalyst: and that the silanol condensation catalyst is an amine compound and that an aqueous solution prepared by adding 5 millimoles of the amine compound to 100 g of a mixed solvent composed of isopropyl alcohol and water in a weight ratio of 10:3 has a pH value of not lower than 13.4 as measured at 23° C. according to JIS Z 8802.
摘要翻译： 本发明的目的是通过使用非有机锡固化催化剂来提供具有实用的固化性水平的可固化组合物。 此外，本发明的目的是提供一种固化性优异的固化性组合物，同时确保了固化性的实用性。 本发明涉及一种可固化组合物，其包含：（A）含有能够通过硅氧烷键形成交联的含硅基团的有机聚合物和（B）硅烷醇缩合催化剂;所述硅烷醇缩合催化剂是胺化合物， 通过向100g由异丙醇和水组成的混合溶剂中加入5毫摩尔胺化合物而制备的水溶液，其重量比为10:3，在23℃下测得的pH值不低于13.4。 根据JIS Z 8802。
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公开(公告)号：US08013080B2
公开(公告)日：2011-09-06
申请号：US12088799
申请日：2006-10-02
IPC分类号： C08F283/00
CPC分类号： C09K3/1018 , C08G65/336 , C08K5/3462 , C08L71/02 , C08L101/10
摘要： The present invention has its object to provide, by using a non-organotin curing catalyst, a curable composition having a practical level of curability. Furthermore, the present invention has its object to provide a curable composition excellent in adhesiveness while it secures a practical level of curability. The present invention relates to a curable composition which comprises:(A) an organic polymer containing a silicon-containing group capable of crosslinking by siloxane bond formation and(B) a silanol condensation catalyst:and that the silanol condensation catalyst is an amine compound and that an aqueous solution prepared by adding 5 millimoles of the amine compound to 100 g of a mixed solvent composed of isopropyl alcohol and water in a weight ratio of 10:3 has a pH value of not lower than 13.4 as measured at 23° C. according to JIS Z 8802.
摘要翻译： 本发明的目的是通过使用非有机锡固化催化剂来提供具有实用的固化性水平的可固化组合物。 此外，本发明的目的是提供一种固化性优异的固化性组合物，同时确保了固化性的实用性。 本发明涉及一种可固化组合物，其包含：（A）含有能够通过硅氧烷键形成交联的含硅基团的有机聚合物和（B）硅烷醇缩合催化剂;所述硅烷醇缩合催化剂是胺化合物， 通过向100g由异丙醇和水组成的混合溶剂中加入5毫摩尔胺化合物而制备的水溶液，其重量比为10:3，在23℃下测得的pH值不低于13.4。 根据JIS Z 8802。
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公开(公告)号：US07807756B2
公开(公告)日：2010-10-05
申请号：US11667340
申请日：2005-11-09
IPC分类号： C08F8/30
CPC分类号： C08L101/10 , C08K5/16 , C08K5/57 , C08L75/08 , C09J175/08 , C09J201/10 , C09K3/1018 , C08L71/02
摘要： A problem of the present invention is to provide a curable composition which gives good curability, adhesiveness and storage stability by use of a catalyst other than organic tin catalysts. The above problem is solved by a curable composition, comprising: (A) one or more organic polymers having a reactive-silicon-containing group, and (B) a silanol condensation catalyst consisting of one or more compound(s) selected from organic tin compounds, carboxylic acids, and amine compounds, wherein at least one part of the reactive-silicon-containing group(s) of the organic polymer(s) (A) is represented by the following general formula (1): —(CR22)2—(SiR12-aXaO)m—SiX3 (1), and the silanol condensation catalyst (B) consists of amine compound(s) (B1) or consists of amine compound(s) (B1) and a carboxylic acid (B2), and when the mol number of the amine compound(s) is regarded as 1, the ratio by mol of the total amount of the carboxylic acid(s) to the amount of the amine compound(s) is 0.1 or less.
摘要翻译： 本发明的问题是提供一种通过使用有机锡催化剂以外的催化剂而具有良好的固化性，粘合性和保存稳定性的固化性组合物。 上述问题由可固化组合物解决，其包括：（A）一种或多种具有反应性含硅基团的有机聚合物，和（B）由一种或多种选自有机锡的化合物组成的硅烷醇缩合催化剂 化合物，羧酸和胺化合物，其中有机聚合物（A）的至少一部分反应性含硅基团由以下通式（1）表示： - （CR 22） 2-（SiR12-aXaO）m-SiX3（1）和硅烷醇缩合催化剂（B）由胺化合物（B1）或胺化合物（B1）和羧酸（B2）组成， ，当胺化合物的摩尔数为1时，羧酸的总量与胺化合物的量的摩尔比为0.1以下。
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公开(公告)号：US20070299214A1
公开(公告)日：2007-12-27
申请号：US11667340
申请日：2005-11-09
IPC分类号： C08L101/10 , C08K5/09 , C08K5/17 , C09K3/10 , C09J201/10 , C08K5/57
CPC分类号： C08L101/10 , C08K5/16 , C08K5/57 , C08L75/08 , C09J175/08 , C09J201/10 , C09K3/1018 , C08L71/02
摘要： A problem of the present invention is to provide a curable composition which gives good curability, adhesiveness and storage stability by use of a catalyst other than organic tin catalysts. The above problem is solved by a curable composition, comprising: (A) one or more organic polymers having a reactive-silicon-containing group, and (B) a silanol condensation catalyst consisting of one or more compound(s) selected from organic tin compounds, carboxylic acids, and amine compounds, wherein at least one part of the reactive-silicon-containing group(s) of the organic polymer(s) (A) is represented by the following general formula (1): —(CR22)2—(SiR12-aXaO)m—SiX3 (1), and the silanol condensation catalyst (B) consists of amine compound(s) (B1) or consists of amine compound(s) (B1) and a carboxylic acid (B2), and when the mol number of the amine compound(s) is regarded as 1, the ratio by mol of the total amount of the carboxylic acid(s) to the amount of the amine compound(s) is 0.1 or less.
摘要翻译： 本发明的问题是提供一种通过使用有机锡催化剂以外的催化剂而具有良好的固化性，粘合性和保存稳定性的固化性组合物。 上述问题由可固化组合物解决，其包括：（A）一种或多种具有反应性含硅基团的有机聚合物，和（B）由一种或多种选自有机锡的化合物组成的硅烷醇缩合催化剂 化合物，羧酸和胺化合物，其中有机聚合物（A）的至少一部分反应性含硅基团由以下通式（1）表示： - （CR < 2 2 2 2 2 （1），硅烷醇缩合催化剂（B）由胺化合物（B1）组成或由胺组成的胺 化合物（B1）和羧酸（B2），当胺化合物的摩尔数被认为是1时，羧酸的总量的摩尔数相对于羧酸的总量 的胺化合物为0.1以下。
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公开(公告)号：US08013079B2
公开(公告)日：2011-09-06
申请号：US12088797
申请日：2006-10-02
IPC分类号： C08F283/00
CPC分类号： C09K3/1018 , C08K5/3442 , C08L101/10 , C09D201/10 , C09J201/10 , C08L71/02
摘要： The present invention has its object to provide a curable composition which allows slight bleedout of a liquid compound to occur to the cured product and shows good curability and adhesiveness using a non-organotin catalyst, an amine compound, as a silanol condensation catalyst.The present invention relates to a non-organotin-based curable composition which comprises: (A) an organic polymer having a silicon-containing group capable of crosslinking by siloxane bond formation, and (B) a specific amidine compound and/or a guanidine compound having a melting point of not lower than 23° C., as a silanol condensation catalyst.
摘要翻译： 本发明的目的是提供一种固化性组合物，其使固化物发生液体化合物的轻微渗出，并且使用非有机锡催化剂，胺化合物作为硅烷醇缩合催化剂显示良好的固化性和粘合性。 本发明涉及一种非有机锡基可固化组合物，其包含：（A）具有能够通过硅氧烷键形成交联的含硅基团的有机聚合物，和（B）特定的脒化合物和/或胍化合物 熔点不低于23℃，作为硅烷醇缩合催化剂。
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公开(公告)号：US20100036049A1
公开(公告)日：2010-02-11
申请号：US12088797
申请日：2006-10-02
CPC分类号： C09K3/1018 , C08K5/3442 , C08L101/10 , C09D201/10 , C09J201/10 , C08L71/02
摘要： The present invention has its object to provide a curable composition which allows slight bleedout of a liquid compound to occur to the cured product and shows good curability and adhesiveness using a non-organotin catalyst, an amine compound, as a silanol condensation catalyst.The present invention relates to a non-organotin-based curable composition which comprises: (A) an organic polymer having a silicon-containing group capable of crosslinking by siloxane bond formation, and (B) a specific amidine compound and/or a guanidine compound having a melting point of not lower than 23° C., as a silanol condensation catalyst.
摘要翻译： 本发明的目的是提供一种固化性组合物，其使固化物发生液体化合物的轻微渗出，并且使用非有机锡催化剂，胺化合物作为硅烷醇缩合催化剂显示良好的固化性和粘合性。 本发明涉及一种非有机锡基可固化组合物，其包含：（A）具有能够通过硅氧烷键形成交联的含硅基团的有机聚合物，和（B）特定的脒化合物和/或胍化合物 熔点不低于23℃，作为硅烷醇缩合催化剂。
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公开(公告)号：US07973108B2
公开(公告)日：2011-07-05
申请号：US11579553
申请日：2005-04-25
IPC分类号： C08G77/08 , C08G77/46 , C08G77/48 , C08L83/14 , C08F283/06
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problem] There is provided a curable composition having good curability and adhesion by use of a non-organotin catalyst.[Means to Solve] A curable composition comprising (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of from 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) in the composition to the total mole (b) of silicon atoms of the component (C) in the composition is more than 0.4.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好固化性和粘合性的可固化组合物。 [解决方案]一种可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种 和（C）含有水解性硅基且分子量为100〜1000的低分子量化合物，其特征在于钛原子，铝原子和锆的总摩尔数（a）的比（a / b） 组合物中组分（B）的原子与组合物中组分（C）的硅原子的总摩尔数（b）大于0.4。
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公开(公告)号：US20090281253A1
公开(公告)日：2009-11-12
申请号：US12088814
申请日：2006-09-26
IPC分类号： C08L83/06
CPC分类号： C08K5/42 , C08K5/098 , C08L101/10
摘要： The present invention has its object to provide a curable composition excellent in curability and storage stability.The present invention relates to a curable composition which comprises, for instance,(A) an organic polymer having a silicon-containing group capable of crosslinking under siloxane bond formation, (B) a carboxylic acid metal salt (b1) and/or a carboxylic acid (b2), and (C) an organic sulfonic acid ester represented by the general formula (1): R1SO3R2 (1) (wherein R1 and R2 each independently represents a substituted or unsubstituted hydrocarbon group).
摘要翻译： 本发明的目的是提供固化性和保存稳定性优异的固化性组合物。 本发明涉及一种可固化组合物，其包含例如（A）具有在硅氧烷键形成下能够交联的含硅基团的有机聚合物，（B）羧酸金属盐（b1）和/或羧酸 酸（b2）和（C）由通式（1）表示的有机磺酸酯：R1SO3R2（1）（其中R1和R2各自独立地表示取代或未取代的烃基）。
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公开(公告)号：US07550547B2
公开(公告)日：2009-06-23
申请号：US11091509
申请日：2005-03-29
IPC分类号： C08G77/08
CPC分类号： C08L83/04 , C08K5/09 , C09K3/1018
摘要： The present invention provides a curable composition which has a high recovery ratio, a high creep resistance, a practical curability and storage stability. The present invention relates to a curable composition comprising a reactive silicon group containing organic polymer (A) and a carboxylic acid (B), wherein the composition comprises (I), as the carboxylic acid (B), a carboxylic acid (C) in which the carbon adjacent to the carbonyl group is a quaternary carbon atoms and/or the composition comprises (II) a metal carboxylate (D) formed between a carboxylic acid in which the carbon atoms adjacent to the carbonyl group is a quaternary carbon atoms and a metal atom of 208 or less in atomic weight.
摘要翻译： 本发明提供了具有高回收率，高抗蠕变性，实用的固化性和储存稳定性的可固化组合物。 本发明涉及包含含有有机聚合物（A）和羧酸（B）的反应性硅基团的可固化组合物，其中组合物包含（I）作为羧酸（B）的羧酸（C） 其中与羰基相邻的碳是季碳原子和/或组合物包含（II）在其中与羰基相邻的碳原子是季碳原子的羧酸之间形成的金属羧酸盐（D）和 原子量为208以下的金属原子。
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公开(公告)号：US20080269405A1
公开(公告)日：2008-10-30
申请号：US11547030
申请日：2005-03-18
IPC分类号： C08L83/04
CPC分类号： C08K5/0025 , C08K5/098 , C08K5/544 , C08L71/02
摘要： The present invention has its object to provide a one package curable composition which has good adhesion while containing an organotin-free catalyst.The present invention provides a one package curable composition which comprises (A) an organic polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a carboxylic acid metal salt (b1) and/or a carboxylic acid (b2), (C) a filler, and (D) an amino group-containing silane coupling agent: and has the total amount of carbonyl group composing an acid group in the component (B) per 100 g of the component (A) of 12 mmol or lower; contains substantially no organotin compound; and has the water content of 2,000 ppm or lower.
摘要翻译： 本发明的目的是提供一种包含无机锡催化剂的粘合性良好的一包装可固化组合物。 本发明提供一种包装可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）羧酸金属盐（b1）和/或羧酸（ b2），（C）填料和（D）含氨基的硅烷偶联剂，并且组合物（B）中的每100克组分（A）中构成酸基的羰基的总量为 12 mmol或更低; 基本上不含有机锡化合物; 水含量为2000ppm以下。
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