公开(公告)号：US20120295504A1

公开(公告)日：2012-11-22

申请号：US13512716

申请日：2010-11-25

Applicant: Masahiko Miyauchi ,  Takahisa Iwahara ,  Masato Kusakabe

Inventor： Masahiko Miyauchi ,  Takahisa Iwahara ,  Masato Kusakabe

IPC: C08K7/06 ,  C08L23/12 ,  B32B37/12 ,  B32B5/02

CPC classification number: C08J5/042 ,  B29C70/46 ,  C08J2351/06 ,  Y10T442/2984

Abstract: The invention provides a carbon fiber-reinforced composite material including reinforcing fibers which are continuous carbon fibers in the form of a unidirectional (UD) material, a woven fabric, or a knitted fabric, and a matrix resin including a modified polyolefin resin, thereby achieving better adhesion and mechanical strength. The matrix resin forms a polyphase structure having a sea-island structure which has an average island (independent phase) diameter of not greater than 0.5 μm. The composite material includes as a matrix resin a modified polyolefin resin obtained by, for example, graft-modifying a polyolefin resin with a monomer that contains an ethylenic double bond and a polar group in the same molecule; and includes as reinforcing fibers continuous carbon fibers. For example, the fiber-reinforced composite material is obtained by stacking the modified polyolefin resin and carbon fibers in a mold with a predetermined shape, and impregnating the carbon fibers with the modified polyolefin resin in a molten state under pressure, followed by cooling and curing.

Abstract translation: 本发明提供一种碳纤维增强复合材料，其包括作为单向（UD）材料，织造织物或针织物形式的连续碳纤维的增强纤维和包含改性聚烯烃树脂的基质树脂，从而实现 更好的附着力和机械强度。 基质树脂形成具有平均岛（独立相））不大于0.5μm的海岛结构的多相结构。 复合材料包括作为基质树脂的改性聚烯烃树脂，其通过例如在同一分子中用含有烯属双键和极性基团的单体接枝改性聚烯烃树脂而获得; 并且包括作为增强纤维的连续碳纤维。 例如，纤维增强复合材料通过将改性聚烯烃树脂和碳纤维堆叠在具有预定形状的模具中，并在压力下在熔融状态下用改性聚烯烃树脂浸渍碳纤维，然后冷却和固化 。

公开(公告)号：US07910681B2

公开(公告)日：2011-03-22

申请号：US11579587

申请日：2005-04-25

Applicant: Masayuki Wakioka ,  Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

Inventor： Masayuki Wakioka ,  Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

IPC: C08G77/08 ,  C08G77/46 ,  C08G77/48 ,  C08L83/14 ,  C08F283/06

CPC classification number: C08G65/336 ,  C08K3/014 ,  C08K5/0091 ,  C08K5/544 ,  C09D171/02 ,  C09J171/02 ,  C09K3/10 ,  C08L101/10 ,  C08L71/02

Abstract: There is provided a curable composition having good adhesion by using a non-organotin catalyst.The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.

Abstract translation: 通过使用非有机锡催化剂提供具有良好粘附性的可固化组合物。 可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种，​​其特征在于 在50％张力下的应力在0.01MPa至0.20MPa的范围内，当通过将1.5份辛酸锡，0.25重量份的月桂胺和0.6重量份的纯水加入并混合到100重量份的 组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中，不混合气泡，将混合物在23℃下老化1小时，再在70℃下老化20小时 ，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min）。

公开(公告)号：US20080287636A1

公开(公告)日：2008-11-20

申请号：US11579630

申请日：2005-04-25

Applicant: Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

Inventor： Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

IPC: C08G77/00

CPC classification number: C08G65/336 ,  C08K3/014 ,  C08K5/0091 ,  C08K5/544 ,  C09D171/02 ,  C09J171/02 ,  C09K3/10 ,  C08L101/10 ,  C08L71/02

Abstract: [PROBLEMS] There is provided a curable composition having good curability and adhesiveness. [MEANS FOR SOLVING] A curable composition by comprising (A) an reactive silicon group-containing organic polymer,(B) a titanium chelate represented by the general formula (1) or (2),(C) a high molecular weight plasticizer having a number average molecular weight of 1000 to 15000:General Formula (1): wherein each of n R1's is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2's is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1's and (4-n) A2's is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2, or 3. General Formula wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group havimg 1 to 20 carbon atoms.

Abstract translation: [问题]提供了具有良好的固化性和粘合性的固化性组合物。 [解决方案]一种可固化组合物，其包含（A）含反应性硅基的有机聚合物，（B）由通式（1）或（2）表示的钛螯合物，（C）具有 数均分子量为1000〜15000：通式（1）：其中n R 1各自独立地为取代或未取代的碳原子数1〜20的烃基，（4 -n）R 2独立地为氢原子或取代或未取代的碳原子数1〜20的烃基，（4-n）A 1〜 和（4-n）A 2独立地为-R 3或-OR 3，其中R 3为 是具有1至20个碳原子的取代或未取代的烃基，n为1,2或3.其中R 2，A 1和A 2的通式为 2 与上述定义相同，R 4是取代或未取代的2至20碳a的二价烃基 手铐

公开(公告)号：US20080076878A1

公开(公告)日：2008-03-27

申请号：US11579551

申请日：2005-04-25

Applicant: Masayuki Wakioka ,  Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

Inventor： Masayuki Wakioka ,  Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

IPC: C08L43/04 ,  C08L31/02

CPC classification number: C08G65/336 ,  C08K3/014 ,  C08K5/0091 ,  C08K5/544 ,  C09D171/02 ,  C09J171/02 ,  C09K3/10 ,  C08L101/10 ,  C08L71/02

Abstract: [Problems] There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.

Abstract translation: [问题]提供了通过使用非有机锡催化剂具有良好的固化性和粘合性的固化性组合物。 [解决问题的方法]可固化组合物包含（A）具有通过形成硅氧烷键而能够交联的具有反应性硅基团的含硅基团的有机聚合物，（B）选自钛催化剂， 铝催化剂和锆催化剂，和（C）含有可水解硅基并且分子量为100〜1000的低分子量化合物，其特征在于钛的总摩尔（a）的比（a / b） 组分（B）的原子，铝原子和锆原子与组分（c）的硅原子的总摩尔数（b）大于0.08。

公开(公告)号：US20080033087A1

公开(公告)日：2008-02-07

申请号：US11579405

申请日：2005-04-25

Applicant: Toshihiko Okamoto ,  Masato Kusakabe

Inventor： Toshihiko Okamoto ,  Masato Kusakabe

IPC: C08J3/24

CPC classification number: C08G65/336 ,  C08K3/014 ,  C08K5/0091 ,  C08K5/544 ,  C09D171/02 ,  C09J171/02 ,  C09K3/10 ,  C08L101/10 ,  C08L71/02

Abstract: [Problem] There is provided a curable composition having high thixotropy and satisfactory curability by use of a non-organotin catalyst. [Means to Solve] A curable composition comprising (A) a polyoxyalkylene polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and/or a (meth)acrylate polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) a titanium chelate, and (C) an amide wax type thixotropy-imparting agent.

Abstract translation: [问题]提供了通过使用非有机锡催化剂具有高触变性和令人满意的固化性的可固化组合物。 [解决方案]一种可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的聚氧化烯聚合物和/或具有含硅基团的（甲基）丙烯酸酯聚合物，其可以通过形成 硅氧烷键，（B）钛螯合物和（C）酰胺蜡型触变性赋予剂。

公开(公告)号：US20070203297A1

公开(公告)日：2007-08-30

申请号：US11547028

申请日：2005-03-18

Applicant: Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

Inventor： Katsuyu Wakabayashi ,  Toshihiko Okamoto ,  Masato Kusakabe

IPC: C08L71/02

CPC classification number: C08F293/005 ,  C08K5/09 ,  C08L43/04 ,  C08L53/00 ,  C08L71/02 ,  C09D153/00 ,  C08L83/12 ,  C08L2666/22 ,  C08L2666/02

Abstract: The present invention has its object to provide a curable composition which has good curability and adhesiveness while containing an organotin-free catalyst. The present invention provides a one package curable composition which comprises (A) a polyoxyalkylene polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a (meth)acrylic ester polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond and compatible with the component (A), and (C) (c1) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and/or (c2) a metal carboxylate of which the carbon atom adjacent to a carbonyl group is a quaternary carbon.

Abstract translation: 本发明的目的是提供一种含有无机锡催化剂的固化性和粘合性优异的固化性组合物。 本发明提供一种包装可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的聚氧化烯聚合物，（B）具有含硅基团的（甲基）丙烯酸酯聚合物， 通过形成硅氧烷键并与组分（A）相容的交联，和（C）（c1）与羰基相邻的碳原子为季碳的羧酸和/或（c2）羧酸金属的 其中与羰基相邻的碳原子是季碳。

公开(公告)号：US06441101B1

公开(公告)日：2002-08-27

申请号：US09583106

申请日：1999-09-15

Applicant: Masato Kusakabe ,  Kenichi Kitano

Inventor： Masato Kusakabe ,  Kenichi Kitano

IPC: C08F842

CPC classification number: C08F8/26 ,  C08F8/42 ,  C08F20/00

Abstract: (Meth)acrylic polymers having alkenyl or curable silyl groups at the chain ends in high functionality ratios are prepared by a process which comprises (i) preparing a (meth)acrylic polymer having halogen atoms at the chain ends, using an organohalogenated compound or a halosulfonyl compound as an initiator and a metal complex catalyst wherein the central metal atom is selected from the group consisting of the elements of Groups 8, 9, 10 and 11 of the periodic table; and (ii) transforming the halogen atom into an alkenyl group- or a curable silyl group-containing substituent. The obtained (meth)acrylic polymers form homogeneous curing materials.

Abstract translation: 通过包括（i）使用有机卤化化合物或其制备具有卤素原子的（甲基）丙烯酸聚合物的方法制备具有高官能度比的链末端具有烯基或可固化甲硅烷基的（甲基）丙烯酸聚合物 卤代磺酰基化合物作为引发剂和金属配合物催化剂，其中中心金属原子选自周期表第8,9,10和11族的元素; 和（ii）将卤素原子转化为烯基或含可固化的含甲硅烷基的取代基。所得的（甲基）丙烯酸聚合物形成均匀的固化材料。

公开(公告)号：US09601780B2

公开(公告)日：2017-03-21

申请号：US14119290

申请日：2012-05-22

Applicant: Yusuke Kato ,  Masahiro Kojima ,  Ryutaro Mukai ,  Masato Kusakabe ,  Hiroyuki Ogino ,  Takashi Kikuchi ,  Takashi Ito ,  Satoshi Oku ,  Akiko Waki ,  Shiho Inoue ,  Yuji Muroya ,  Norihisa Waki ,  Yasuyuki Tanaka ,  Shigeo Ibuka ,  Yoshio Shimoida

Inventor： Yusuke Kato ,  Masahiro Kojima ,  Ryutaro Mukai ,  Masato Kusakabe ,  Hiroyuki Ogino ,  Takashi Kikuchi ,  Takashi Ito ,  Satoshi Oku ,  Akiko Waki ,  Shiho Inoue ,  Yuji Muroya ,  Norihisa Waki ,  Yasuyuki Tanaka ,  Shigeo Ibuka ,  Yoshio Shimoida

IPC: H01M4/66 ,  H01M10/0525 ,  C08K3/04 ,  C08J7/04 ,  B32B27/08 ,  B32B27/20 ,  B32B27/28 ,  B32B27/32 ,  H01M4/02

CPC classification number: H01M4/668 ,  B32B27/08 ,  B32B27/20 ,  B32B27/281 ,  B32B27/325 ,  B32B2264/10 ,  B32B2264/105 ,  B32B2307/202 ,  B32B2307/206 ,  B32B2457/10 ,  C08G2261/3324 ,  C08G2261/418 ,  C08J7/047 ,  C08J2379/08 ,  C08J2465/00 ,  C08K3/04 ,  C08K2201/001 ,  H01M4/661 ,  H01M4/663 ,  H01M4/666 ,  H01M4/667 ,  H01M10/0525 ,  H01M2004/029 ,  Y02E60/122 ,  C08L65/00

Abstract: A multilayer conductive film includes a layer 1 including a conductive material containing a polymer material 1 having an alicyclic structure and conductive particles 1 and a layer 2 including a material having durability against positive electrode potential. The multilayer conductive film has stability in an equilibrium potential environment in a negative electrode and stability in an equilibrium potential environment in a positive electrode, has low electric resistance per unit area in the thickness direction, and has excellent barrier properties for a solvent of an electrolytic solution. A battery including a current collector employing the multilayer conductive film can achieve both weight reduction and durability.

公开(公告)号：US20140186699A1

公开(公告)日：2014-07-03

申请号：US14119290

申请日：2012-05-22

Applicant: Yusuke Kato ,  Masahiro Kojima ,  Ryutaro Mukai ,  Masato Kusakabe ,  Hiroyuki Ogino ,  Takashi Kikuchi ,  Takashi Ito ,  Satoshi Oku ,  Akiko Waki ,  Shiho Inoue ,  Yuji Muroya ,  Norihisa Waki ,  Yasuyuki Tanaka ,  Shigeo Ibuka ,  Yoshio Shimoida

Inventor： Yusuke Kato ,  Masahiro Kojima ,  Ryutaro Mukai ,  Masato Kusakabe ,  Hiroyuki Ogino ,  Takashi Kikuchi ,  Takashi Ito ,  Satoshi Oku ,  Akiko Waki ,  Shiho Inoue ,  Yuji Muroya ,  Norihisa Waki ,  Yasuyuki Tanaka ,  Shigeo Ibuka ,  Yoshio Shimoida

IPC: H01M4/66

CPC classification number: H01M4/668 ,  B32B27/08 ,  B32B27/20 ,  B32B27/281 ,  B32B27/325 ,  B32B2264/10 ,  B32B2264/105 ,  B32B2307/202 ,  B32B2307/206 ,  B32B2457/10 ,  C08G2261/3324 ,  C08G2261/418 ,  C08J7/047 ,  C08J2379/08 ,  C08J2465/00 ,  C08K3/04 ,  C08K2201/001 ,  H01M4/661 ,  H01M4/663 ,  H01M4/666 ,  H01M4/667 ,  H01M10/0525 ,  H01M2004/029 ,  Y02E60/122 ,  C08L65/00

Abstract: A multilayer conductive film includes a layer 1 including a conductive material containing a polymer material 1 having an alicyclic structure and conductive particles 1 and a layer 2 including a material having durability against positive electrode potential. The multilayer conductive film has stability in an equilibrium potential environment in a negative electrode and stability in an equilibrium potential environment in a positive electrode, has low electric resistance per unit area in the thickness direction, and has excellent barrier properties for a solvent of an electrolytic solution. A battery including a current collector employing the multilayer conductive film can achieve both weight reduction and durability.

Abstract translation: 多层导电膜包括含有包含具有脂环结构的聚合物材料1和导电粒子1的导电材料的层1和包含具有对正极电位具有耐久性的材料的层2。 多层导电膜在负极中的平衡势环境中具有稳定性，并且在正极中的平衡势环境中的稳定性，在厚度方向上的每单位面积的电阻低，并且对于电解质的溶剂具有优异的阻隔性 解。 包括使用多层导电膜的集电体的电池可以实现重量减轻和耐久性。

公开(公告)号：US20140099537A1

公开(公告)日：2014-04-10

申请号：US14119308

申请日：2012-05-22

Applicant: Yusuke Kato ,  Takashi Ito ,  Masami Yanagida ,  Satoshi Oku ,  Hiroyuki Ogino ,  Masato Kusakabe ,  Ryutaro Mukai ,  Masahiro Kojima ,  Takashi Kikuchi ,  Akiko Waki ,  Shiho Inoue ,  Shigeo Ibuka ,  Yasuyuki Tanaka ,  Yoshio Shimoida ,  Yuji Muroya ,  Norihisa Waki

Inventor： Yusuke Kato ,  Takashi Ito ,  Masami Yanagida ,  Satoshi Oku ,  Hiroyuki Ogino ,  Masato Kusakabe ,  Ryutaro Mukai ,  Masahiro Kojima ,  Takashi Kikuchi ,  Akiko Waki ,  Shiho Inoue ,  Shigeo Ibuka ,  Yasuyuki Tanaka ,  Yoshio Shimoida ,  Yuji Muroya ,  Norihisa Waki

IPC: H01M4/66

CPC classification number: H01M4/667 ,  H01M4/668 ,  H01M10/052 ,  H01M2004/029

Abstract: A conductive film includes a layer 1 formed by a conductive material 1 that includes a polymer material 1 containing any of (1) an amine and an epoxy resin (where the epoxy resin and the amine are mixed in a ratio of 1.0 or more in terms of the ratio of the number of active hydrogen atoms in the amine with respect to the number of functional groups in the epoxy resin), (2) a phenoxy resin and an epoxy resin, (3) a saturated hydrocarbon polymer having a hydroxyl group, and (4) a curable resin and an elastomer and conductive particles 1. The conductive film has excellent stability in an equilibrium potential environment in a negative electrode and low electric resistance per unit area in the thickness direction. A multilayer conductive film including the conductive film achieves excellent interlayer adhesion, and using them as a current collector enables the production of a battery satisfying both weight reduction and durability.

Abstract translation: 导电膜包括由导电材料1形成的层1，其包括聚合物材料1，其包含（1）胺和环氧树脂（其中环氧树脂和胺以1.0或更大的比例混合 （2）苯氧基树脂和环氧树脂，（3）具有羟基的饱和烃聚合物，（3）具有羟基的饱和烃聚合物， 和（4）可固化树脂和弹性体和导电颗粒1.导电膜在负极中的平衡电位环境中具有优异的稳定性，并且在厚度方向上具有每单位面积的低电阻。 包括导电膜的多层导电膜具有优异的层间粘合性，并且作为集电体使用它们能够制造满足重量减轻和耐久性的电池。