公开(公告)号：US4016306A

公开(公告)日：1977-04-05

申请号：US592893

申请日：1975-07-03

申请人： Norio Miyagawa ,  Mitsuo Sato ,  Juichi Kobayashi ,  Takashi Kobayashi

发明人： Norio Miyagawa ,  Mitsuo Sato ,  Juichi Kobayashi ,  Takashi Kobayashi

IPC分类号： C08F265/04 ,  C09D4/06 ,  B05D3/06

CPC分类号： C08F265/04 ,  C09D4/06

摘要： An acrylic resin composition containing a thermoplastic acrylic polymer in combination with a specific ethylenically unsaturated diacrylate such as diacrylate of hydroxypivalyl hydroxypivalate is found to be cured by irradiation of active rays in an aqueous medium in the presence of a photo-sensitizer to form a cured film with excellent properties. This composition is especially suitable for coating a plastic tile.

摘要翻译： 发现含有热塑性丙烯酸类聚合物与特定的烯键式不饱和二丙烯酸酯如羟基新戊酰羟基新戊酸二丙烯酸酯组合的丙烯酸树脂组合物在光敏剂存在下通过在水性介质中照射活性射线而固化以形成固化膜 具有优良的性能。 该组合物特别适用于涂覆塑料瓦片。

公开(公告)号：US4112190A

公开(公告)日：1978-09-05

申请号：US807149

申请日：1977-06-16

申请人： Mitsuo Sato ,  Norio Miyagawa ,  Juichi Kobayashi

发明人： Mitsuo Sato ,  Norio Miyagawa ,  Juichi Kobayashi

IPC分类号： B05D7/24 ,  C08J7/04 ,  C23C14/20 ,  C23C18/20 ,  C25D5/56 ,  B32B15/08 ,  B32B27/00

CPC分类号： C23C14/20 ,  B05D5/067 ,  C08J7/047 ,  B05D2201/00 ,  Y10T428/31678

摘要： A metallized plastic molding comprises a plastic substrate, a primer layer having a gel percentage of at least 80% and a swelling degree of 20% or less deposited on said substrate and a metallic film deposited on the primer layer. The metallized plastic molding is prepared by coating a plastic substrate with a primer forming material containing at least one compound having a molecular weight of 150 - 2000 and containing at least two polymerizable unsaturated groups in one molecule, curing the primer forming material so that it has a gel percentage of at least 80% and a swelling degree of 20% or less to form a primer layer and then depositing a metallic film layer by a dry type method on the primer layer.

摘要翻译： 金属化塑料模制品包括塑料基材，沉积在所述基材上的凝胶百分比为至少80％和溶胀度为20％或更低的底漆层和沉积在底漆层上的金属膜。 金属化塑料模制品通过用包含至少一种分子量为150-2000的化合物的底漆形成材料涂覆塑料基材并在一分子中含有至少两个可聚合不饱和基团，使底漆形成材料固化， 凝胶百分比为至少80％，溶胀度为20％以下，以形成底漆层，然后通过干式方法在底漆层上沉积金属膜层。

公开(公告)号：US4148967A

公开(公告)日：1979-04-10

申请号：US895582

申请日：1978-04-12

申请人： Mitsuo Satoh ,  Norio Miyagawa ,  Juichi Kobayashi

发明人： Mitsuo Satoh ,  Norio Miyagawa ,  Juichi Kobayashi

IPC分类号： C09D4/00 ,  B05D3/06 ,  B05D7/24 ,  B32B15/04 ,  B32B15/08 ,  B32B15/082 ,  C09D4/06

CPC分类号： B05D5/068 ,  C09D4/06 ,  B05D3/067 ,  Y10T428/31511 ,  Y10T428/31522 ,  Y10T428/31529 ,  Y10T428/31554 ,  Y10T428/31605 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31699

摘要： A metallized plastic molded product is provided which comprises a plastic substrate, a base coat layer, a dry metallic film layer, an inter coat layer and a top coat layer, characterized in that said inter coat layer is a cured ultraviolet curing composition comprising 5-80% by weight of a resin containing 5-50% by weight of repeating unit represented by the formula I: ##STR1## wherein R.sub.1 is H or CH.sub.3, R.sub.2 is H or C.sub.1-8 alkyl, and R.sub.3 is C.sub.1-8 alkyl, and having a molecular weight of 4,000-200,000 and 20-95% by weight of a compound having polymerizable unsaturated groups and said top coat layer is a cured ultraviolet curing composition comprising 40-90% by weight of a urethane modified polyvinyl compound and 10-60% by weight of a polyvinyl compound having a molecular weight of 170-1,000 and having at least two polymerizable unsaturated groups in one molecule. A method for producing the product is also provided.

摘要翻译： 提供一种金属化塑料模制产品，其包括塑料基材，底涂层，干燥金属膜层，中间涂层和顶涂层，其特征在于所述涂层是固化的紫外线固化组合物，其包含5- 80重量％的含有5-50重量％的由式I表示的重复单元的树脂：其中R1是H或CH3，R2是H或C1-8烷基，R3是C1 -8烷基，并且分子量为4,000-200,000和20-95重量％的具有可聚合不饱和基团的化合物和所述面漆层是固化的紫外线固化组合物，其包含40-90重量％的氨基甲酸酯改性聚乙烯 化合物和10-60重量％的分子量为170-1,000的聚乙烯基化合物，并且在一个分子中具有至少两个可聚合的不饱和基团。 还提供了一种生产该产品的方法。