Abstract:
THE PROCESS FOR PREPARING AN ORGANIC ISOCYANATE BY REACTING AN ORGANIC AZO AND/OR AN ORGANIC AZOXY COMPOUND WITH CARBON MONOXIDE IN THE PRESENCE OF A NOBLE METAL BASED CATALYST AT AN ELEVATED TEMPERATURE AND ELEVATED PRESSURE.
Abstract:
THE PROCESS FOR PREPARING AN ORGAINC ISOCYANATE BY REACTING AN ORGANIC NITRO COMPOUND WITH CARBON MONOXIDE IN THE PRESENCE OF A CATALYST SYSTEM COMPRISING A HALIDE OF A NOBLE METAL AND AN AMINE COMPOSITION. USEFUL AMINE COMPOSITION INCLUDE COMPOUNDS OF THE FORMULA:
RR''R"N
WHEREIN R, R'' AND R" ARE EACH SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, ALKYL, CYCLOALKYL, ARALKYL, AND
R"''-BENZENE
AND WHEREIN NOT MORE THAN TWO OF THE R, R'' AND R" SUBSTITUENTS ARE HYDROGEN. PREFERRED AMINES INCLUDE TRI-NBUTYL AMINE, ANILINE, ANILINE-2-SULFONIC ACID, O-PHENYLENE DIAMINE, ANTHRANILIC ACID, N-PHENYL ANTHRANILIC ACID, ANTHRANILAMIDE, O-AMINOPHENOL, O-AMINOBENZENE THIOL, BENZYL AMINE, DIPHENYL AMINE, AND TRIPHENYL AMINE. THE NOBLE METAL HALIDE IS PREFERABLY A HALIDE OF PALLADIUM, RODIUM, IRIDIUM, RHENIUM, PATINUM, AND MIXTURES THEREOF. THE CATALST SYSTEM MAY ALSO INCLUDE MOLYBDENUM TRIOXIDE OR ANOTHER METAL OXIDE.
Abstract:
FLURONAILINES ARE PREPARED BY THE DEOXGENATION AND HYDROFLURINATION OF THE CORRESPONDIGN NITROBENZENES WHICH ARE REACTED IN ANHYDROUS HYDROGEN FLUORIDE AT 0* TO 230*C. UNDER PESSURE OF FROM 15 TO 1500 P.S.I.A. IN THE PRESENCE OF CARBON MONOXIDE AND A NOBLE METAL CATALYST.
Abstract:
THE PROCESS FOR PREPARING N,N''-DIARYLTHIOUREAS BY REACTING: (A) CARBON DISULFIDE AND/OR CARBONYL SULFIDE, (B) WATER, (C) A COMPOUND SELECTED FROM THE GROUP CONSISTING OF (1) AN AROMATIC NITRO COMPOUND, (2) AN AROMATIC NITROSO COMPOUND, (3) AND MIXTURES OF (1) AND (2), (D) AND A BASE, AND RECOVERING THE N,N''-DIARYLTHIOUREAS PRODUCED THEREBY.