摘要:
A process for the preparation of bromine and hydrogen bromide, which comprises reacting ammonium bromide with an oxygen containing gas at temperatures of from 200.degree. to 800.degree. C in the presence of oxidation catalysts is disclosed. Catalysts based on platinum group metals favor formation of HBr. Most other metal catalysts cause chiefly formation of bromine.
摘要:
DISCLOSED IN A PROCESS FOR THE RECOVERY OF BROMINE VALUES AS BR2 FROM ORGANIC BROMIDES. THE PROCESS INVOLVES REACTING THE ORGANIC BROMIDE WITH OXYGEN AT AN ELEVATED TEMPERATURE IN THE PRESENCE OF A CATALYST. THE CATALYST IS SELECTED FROM ONE OR MORE OF THE OXIDES OF CHROMIUM, VANADIUM, TUNGSTEN, MOLYBDENUM, CERIUM, URANIUM OR ALUMINUM.
摘要:
A method of recovering bromine as hydrogen bromide from aromatic bromides. The method involves reacting the aromatic bromide with hydrogen at a temperature within the range of from about 200* to about 600* C in the presence of a palladium activated catalyst.
摘要:
Aqueous hydrogen iodide is prepared by the reaction of iodine, water and carbon monoxide in a reaction medium containing a strong acid at temperatures in the range from about 75* to about 200* C and pressures from about 25 to about 500 psig employing a rhodium- or iridium-containing catalyst.
摘要:
A flame reactor burner is provided for reacting hydrogen and bromine to produce hydrogen bromide. Flame stability is enhanced by producing a helical flow of well mixed reactants within the burner, whereby the reactants in intimate contact with each other are propelled in an outward spiral path as they exit from the burner producing a hemispherical flame of high stability.
摘要:
A method of recovering in highly pure states heavy metals such as cobalt, manganese, etc., and bromine without the contamination of organic impurities and heavy metal impurities from the residue of the reaction mother liquor, which is obtained by removing a solvent from the reaction mother liquor remained after recovering terephthalic acid from the oxidation reaction product obtained in the method of producing terephthalic acid by subjecting an alkylbenzene such as p-xylene to a liquid phase oxidation with oxygen or oxygen-containing gas in the presence of a catalyst containing the heavy metals and bromine using a lower aliphatic monocarboxylic acid as the solvent, said method comprising: stirring the residue of the reaction mother liquor with water as solvent in the presence of molecular oxygen and a sulfur compound, removing solid impurities from the extracted mixtures thus treated by solid-liquid separation to provide an aqueous catalyst extract solution, passing the aqueous solution through a column packed with a strongly acidic cation-exchange resin to adsorb thereon the heavy metal catalyst, distilling the solution thus passed through the ion-exchange resin to recover bromine contained in the aqueous extract solution as hydrobromic acid, and, on the other hand, passing hydrobromic acid through the column of the ion exchange resin having adsorbed thereon the heavy metal catalyst to desorb the heavy metal catalyst, whereby the heavy metal catalyst is recovered as the bromide of it.
摘要:
1. A PROCESS FOR RECOVERING BROMINE FROM A 2,3,3-TRIBROMO-2-ALKYLALKANE WHICH COMPRISES HEATING A CHARGE CONSISTING ESSENTIALLY OF SAID 2,3,3-TRIBROMO-2-ALKYLALKANE AND ATER, WHEREIN THE MOLAR RATIO OF WATER TO SAID 2,3,3TRIBROMO-2-ALKYLALKANE IS IN THE RANGE OF ABOUT 10:1 TO ABOUT 50:1 AT A TEMPERATURE OF ABOUT 80* TO ABOUT 200* C. AND A PRESSURE OF ABOUT 50 TO ABOUT 200 POUNDS PER SQURE INCH GUAGE, SUFFICIENT TO MAINTAIN THE WATER IN LIQUID PHASE, FOR ABOUT 15 MINUTES TO ABOUT FIVE HOURS TO OBTAIN A REACTION MIXTURE HAVING AN UPPER ORGANIC PHASE AND A LOWER AQUEOUS PHASE, SAID UPPER ORGANIC PHASE BEING SUBSTANTIALLY DEPLEDTED OF BROMINE AND HAVING THE APPEARANCE OF A POLYMER AND SAID LOWER AQUEOUS PHASE CONTAINING HBR DISSOLVED THEREIN, AND THEREAFTER SEPARATING SAID PHASES FROM EACH OTHER.