公开(公告)号：US20130310560A1

公开(公告)日：2013-11-21

申请号：US13671995

申请日：2012-11-08

申请人： PETR KUBANEK ,  WOLFGANG MÄRGELEIN ,  EKKEHARD SCHWAB ,  JOHANN-PETER MELDER ,  MANFRED JULIUS

发明人： PETR KUBANEK ,  WOLFGANG MÄRGELEIN ,  EKKEHARD SCHWAB ,  JOHANN-PETER MELDER ,  MANFRED JULIUS

IPC分类号： C07D295/023 ,  C07C209/16 ,  C07C209/78 ,  B01J27/055 ,  B01J23/755 ,  B01J23/843 ,  B01J23/835 ,  B01J23/847 ,  B01J23/825 ,  C07C213/02 ,  B01J27/185

CPC分类号： B01J27/1853 ,  B01J23/002 ,  B01J23/755 ,  B01J23/825 ,  B01J23/835 ,  B01J23/84 ,  B01J23/8435 ,  B01J23/8474 ,  B01J27/055 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/78 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/44 ,  B01J2523/53 ,  C07C211/10 ,  C07C217/08

摘要： Processes for preparing an amine are described which comprise reacting a primary or secondary alcohol, aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of ammonia, primary and secondary amines, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst. The catalytically active composition of the catalyst, before its reduction with hydrogen, comprises oxygen compounds of zirconium, of copper, of nickel, in the range from 1.0 to 5.0% by weight of oxygen compounds of cobalt, calculated as CoO, and in the range from 0.2 to 5.0% by weight of oxygen compounds of sulfur, of phosphorus, of gallium, of lead and/or of antimony, calculated in each case as H2SO4, H3PO4, Ga203, PbO and Sb203 respectively.

摘要翻译： 描述了制备胺的方法，其包括使伯醇或仲醇，醛和/或酮与氢和选自氨，伯胺和仲胺的氮化合物在二氧化锆，铜 - 和含镍催化剂。 催化剂的催化活性组合物在用氢还原之前，包括锆的镍氧化合物，镍的氧化合物为1.0至5.0重量％，钴的氧化合物（以CoO计），范围为 0.2至5.0重量％的硫，磷，镓，铅和/或锑的氧化合物，分别计算为H 2 SO 4，H 3 PO 4，Ga 2 O 3，PbO和Sb 2 O 3。