公开(公告)号：US12076710B2

公开(公告)日：2024-09-03

申请号：US18174695

申请日：2023-02-27

申请人： Mitsubishi Chemical Corporation

发明人： Kazuharu Tazawa ,  Takanori Taniguchi ,  Takuya Nakamura

IPC分类号： B01J23/887 ,  B01J21/08 ,  B01J23/00 ,  B01J23/843 ,  B01J23/883 ,  B01J35/00 ,  B01J35/30 ,  B01J35/40 ,  B01J35/50 ,  B01J35/61 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/06 ,  B01J37/08 ,  C07C45/35 ,  C07C51/25

CPC分类号： B01J23/8877 ,  B01J21/08 ,  B01J23/002 ,  B01J23/8435 ,  B01J23/883 ,  B01J23/8876 ,  B01J35/00 ,  B01J35/30 ,  B01J35/40 ,  B01J35/50 ,  B01J35/613 ,  B01J37/0036 ,  B01J37/0221 ,  B01J37/0228 ,  B01J37/0236 ,  B01J37/0244 ,  B01J37/038 ,  B01J37/06 ,  B01J37/08 ,  C07C45/35 ,  C07C51/252 ,  B01J2523/00

摘要： A ring-shaped catalyst may have a straight body part and a hollow body part, which is used when a gas-phase catalytic oxidation reaction of a material substance is conducted to produce a target substance, wherein a length of the straight body part is shorter than a length of the hollow body part and at least at one end part, a region from an end part of the straight body part to an end part of the hollow body part is concavely curved.

公开(公告)号：US20160067681A1

公开(公告)日：2016-03-10

申请号：US14836292

申请日：2015-08-26

申请人： Kandaswamy Jothimurugesan

发明人： Kandaswamy Jothimurugesan

IPC分类号： B01J23/89 ,  B01J23/20 ,  B01J23/14 ,  B01J23/18 ,  B01J35/02 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  B01J35/10 ,  B01J23/28 ,  B01J23/10

CPC分类号： B01J23/8993 ,  B01J23/10 ,  B01J23/14 ,  B01J23/18 ,  B01J23/20 ,  B01J23/28 ,  B01J23/83 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8474 ,  B01J23/882 ,  B01J23/894 ,  B01J23/8966 ,  B01J23/8973 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/024 ,  B01J37/08 ,  B01J37/18 ,  C01B2203/062 ,  C10G2/33 ,  C10G2/331 ,  C10G2/333 ,  C10G2300/70

摘要： A process has been developed for preparing a Fischer-Tropsch catalyst precursor and a Fischer-Tropsch catalyst made from the precursor. The process includes contacting a gamma alumina catalyst support material with a first solution containing a compound containing an element selected from the group consisting of yttrium (Y), niobium (Nb), molybdenum (Mo), tin (Sn), antimony (Sb) and mixtures thereof to obtain a modified catalyst support material. The modified catalyst support material is calcined at a temperature of at least 700° C. The calcined modified catalyst support has a pore volume of at least 0.4 cc/g. The modified catalyst support is less soluble in acid solutions than an equivalent unmodified catalyst support. The modified catalyst support is contacted with a second solution which includes a precursor compound of an active cobalt catalyst component to obtain a catalyst precursor. The catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer-Tropsch catalyst. The catalyst has enhanced hydrothermal stability as measured by losing no more than 25% of its pore volume when exposed to water vapor.

公开(公告)号：US20160023995A1

公开(公告)日：2016-01-28

申请号：US14774783

申请日：2014-04-16

申请人： ECOLE CENTRALE DE LILLE ,  UNIVERSITE DES SCIENCES ET TECHNOLOGIES DE LILLE - LILLE 1

发明人： Sebastien Paul ,  Benjamin Katryniok ,  Franck Dumeignil ,  Carsten Liebig ,  Wolfgang Holderich ,  Cyrille Guillon

IPC分类号： C07C253/26 ,  B01J23/843

CPC分类号： C07C253/26 ,  B01J23/8435 ,  Y02P20/52 ,  C07C255/08

摘要： A compound of the formula SbxFe1Oy (1) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalysing the ammoxidation reaction of an alcohol of following formula (II) CH2═C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2═C(R1)—C≡N (III) in which R1 has the same meaning as in above formula (ii), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.

摘要翻译： 可以使用式Sb x Fe 1 O y（1）的化合物，其中x从0.4包括1到1，并且y从1.6到4包括在内），可以用作催化下式（II）的醇的氨氧化反应的催化剂：CH2 = C （R 1）-CH 2 -OH（II），其中R 1表示氢原子或甲基，得到下式（III）的腈：其中R 1具有相同的CH 2 = C（R 1）-C≡N（III） 如上述式（ⅱ）所示，所述反应在气相中进行，所述气相至少包含氧和氨。 本发明还涉及使用式（I）化合物作为催化剂使式（II）的醇进行氨氧化的方法。

公开(公告)号：US20150314274A1

公开(公告)日：2015-11-05

申请号：US14267948

申请日：2014-05-02

申请人： CLARIANT CORPORATION

发明人： Wenqin SHEN ,  Franz PETZOLD ,  Karen LIBBY ,  Wayne TURBEVILLE ,  Matthew PURCELL ,  Marc K. BORN

IPC分类号： B01J23/89 ,  B01J23/755 ,  B01J23/745 ,  B01J23/06 ,  C07C29/00 ,  B01J23/843 ,  B01J23/83 ,  C07C29/60 ,  C07C29/141 ,  B01J23/75 ,  B01J23/72

CPC分类号： C07C29/132 ,  B01J21/066 ,  B01J23/06 ,  B01J23/40 ,  B01J23/44 ,  B01J23/48 ,  B01J23/72 ,  B01J23/74 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/83 ,  B01J23/8435 ,  B01J23/892 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0009 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/088 ,  B01J37/18 ,  B01J2523/00 ,  C01G3/02 ,  C01G25/00 ,  C01G25/02 ,  C01G51/04 ,  C01G53/04 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/21 ,  C04B35/486 ,  C04B35/488 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3232 ,  C04B2235/3251 ,  C04B2235/3258 ,  C04B2235/3262 ,  C04B2235/327 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3277 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3293 ,  C04B2235/3294 ,  C04B2235/3409 ,  C04B2235/6021 ,  C04B2235/72 ,  C04B2235/721 ,  C04B2235/765 ,  C07C29/00 ,  C07C29/141 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/205 ,  C07C31/18 ,  C07C31/202 ,  C07C31/225 ,  B01J2523/3706 ,  B01J2523/48 ,  B01J2523/847

摘要： The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder or additional stabilizing agent.

摘要翻译： 本公开一般涉及适合用作催化剂载体材料的陶瓷材料，使用这种材料的催化剂及其使用方法，例如将糖，糖醇，甘油和生物可再生有机酸转化为商业上有价值的化学品的方法，以及 中间体。 本发明的一个方面是包括氧化锆和一种或多种选自氧化镍，氧化铜，氧化钴，氧化铁和氧化锌的金属氧化物的陶瓷材料，所述陶瓷材料为至少约50wt。 ％的氧化锆。 在某些实施方案中，陶瓷材料基本上不含任何粘合剂或其它稳定剂。

公开(公告)号：US09132418B2

公开(公告)日：2015-09-15

申请号：US14306332

申请日：2014-06-17

申请人： CLARIANT CORPORATION

发明人： Wenqin Shen ,  Franz G. Petzold ,  Karen Libby ,  Wayne Turbeville

IPC分类号： C07C29/00 ,  B01J21/00 ,  B01J23/889 ,  B01J37/03 ,  B01J37/08 ,  B01J21/06 ,  B01J23/34 ,  B01J23/46 ,  B01J23/72 ,  B01J23/755 ,  B01J23/843 ,  B01J35/00 ,  B01J35/10 ,  C12P19/02 ,  B01J23/656 ,  C07C29/17 ,  C07C29/60 ,  C07C29/132 ,  C07C29/149

CPC分类号： B01J23/8892 ,  B01J21/066 ,  B01J23/34 ,  B01J23/462 ,  B01J23/6562 ,  B01J23/72 ,  B01J23/755 ,  B01J23/8435 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/031 ,  B01J37/08 ,  C07C29/00 ,  C07C29/132 ,  C07C29/149 ,  C07C29/172 ,  C07C29/60 ,  C12P19/02 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/225 ,  C07C31/26

摘要： The present disclosure relates generally to catalyst support materials, catalysts and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is catalyst support material including ZrO2 and one or more oxides of manganese (MnOx), the catalyst support material being at least about 50 wt % ZrO2 and MnOx. In certain embodiments, the weight ratio of ZrO2 to MnOx is within the range of about 1:1 to about 30:1; and/or the catalyst support material is substantially free of any binder, extrusion aid or additional stabilizing agent.

摘要翻译： 本公开一般涉及催化剂载体材料，催化剂和使用它们的方法，例如将糖，糖醇，甘油和生物可再生有机酸转化成商业上有价值的化学品和中间体的方法。 本发明的一个方面是包括ZrO 2和一种或多种锰氧化物（MnO x）的催化剂载体材料，催化剂载体材料为至少约50重量％的ZrO 2和MnO x。 在某些实施方案中，ZrO 2与MnO x的重量比在约1:1至约30:1的范围内; 和/或催化剂载体材料基本上不含任何粘合剂，挤出助剂或其它稳定剂。

公开(公告)号：US08575063B2

公开(公告)日：2013-11-05

申请号：US12606459

申请日：2009-10-27

申请人： Wen-Qing Xu ,  David Beijia Xu

发明人： Wen-Qing Xu ,  David Beijia Xu

IPC分类号： B01J23/00 ,  B01J21/00

CPC分类号： B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J23/8474 ,  B01J23/883 ,  B01J23/888 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J35/109 ,  B01J37/031 ,  B01J37/04 ,  C01B3/40 ,  C01B2203/0227 ,  C01B2203/1058 ,  Y02P20/52

摘要： The present invention relates unique pore structures in nickel supported on alumina with the negligible formation of macropores. Incorporation of additional elements stabilizes the pore structure of the nickel supported on alumina. Additional element(s) were then further added into the nickel-supported materials. These additional element(s) further stabilize the pore structures under heating conditions. The improvements of pore structure stability under heating conditions and negligible presence of macropores limit the sintering of nickel metal to a mechanism of impeded diffusion. The negligible presence of macropores also limits the deposition of alkali metal hydroxide(s)/carbonate(s) on the outer shell of the catalyst pellet in the molten carbonate fuel cells. Both the negligible presence of macropores and improvement in pore structure stability allow for prolonging the catalyst life of these nickel supported on alumina catalysts of the present invention for reforming hydrocarbons.

摘要翻译： 本发明涉及在负载在氧化铝上的镍中的独特的孔结构，可以忽略大孔的形成。 附加元素的结合稳定了负载在氧化铝上的镍的孔结构。 然后将另外的元素加入到镍负载的材料中。 这些附加元件在加热条件下进一步稳定孔结构。 加热条件下孔结构稳定性的改善和大孔存在的微不足道限制了镍金属的烧结成阻碍扩散的机理。 大孔的可忽略的存在也限制了熔融碳酸盐燃料电池中催化剂颗粒的外壳上的碱金属氢氧化物/碳酸盐的沉积。 微孔存在的微不足道和孔结构稳定性的改善使得延长本发明用于重整烃的氧化铝催化剂上的这些镍的催化剂寿命。

公开(公告)号：US08324430B2

公开(公告)日：2012-12-04

申请号：US12809657

申请日：2008-12-10

申请人： Petr Kubanek ,  Wolfgang Mägerlein ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Manfred Julius

发明人： Petr Kubanek ,  Wolfgang Mägerlein ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Manfred Julius

IPC分类号： C07C209/16 ,  C07D241/04 ,  C07D265/30 ,  C07D295/03 ,  B01J23/835 ,  B01J23/84 ,  B01J23/843 ,  B01J23/847 ,  B01J23/825 ,  B01J37/03

CPC分类号： B01J27/1853 ,  B01J23/002 ,  B01J23/755 ,  B01J23/825 ,  B01J23/835 ,  B01J23/84 ,  B01J23/8435 ,  B01J23/8474 ,  B01J27/055 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/78 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/44 ,  B01J2523/53 ,  C07C211/10 ,  C07C217/08

摘要： Processes for preparing an amine, the processes comprising: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, and nickel, 1.5 to 4.5% by weight of an oxygen compound of cobalt, calculated as CoO, and 0.2 to 5.0% by weight of at least one oxygen compound of niobium, sulfur, phosphorus, gallium, boron, lead or antimony, calculated in each case as Nb2O5, H2SO4, H3PO4, Ga2O3, B2O3, PbO and Sb2O3 respectively, and wherein the catalytically active composition does not comprise any molybdenum.

摘要翻译： 用于制备胺的方法，所述方法包括：使选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺， 仲胺及其混合物，在二氧化锆，含铜和镍的催化剂存在下; 其中所述催化剂包含催化活性组合物，其在用氢还原之前包括锆，铜和镍的氧化合物，1.5至4.5重量％的作为CoO计算的氧化合物钴和0.2至5.0重量％ 的铌，硫，磷，镓，硼，铅或锑的至少一种氧化合物，分别以Nb 2 O 5，H 2 SO 4，H 3 PO 4，Ga 2 O 3，B 2 O 3，PbO和Sb 2 O 3计算，其中催化活性组合物不包含 任何钼。

公开(公告)号：US20100274011A1

公开(公告)日：2010-10-28

申请号：US12809657

申请日：2008-12-10

申请人： Petr Kubanek ,  Wolfgang Mägerlein ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Manfred Julius

发明人： Petr Kubanek ,  Wolfgang Mägerlein ,  Ekkehard Schwab ,  Johann-Peter Melder ,  Manfred Julius

IPC分类号： C07D265/30 ,  C07C209/68 ,  C07C209/78 ,  C07D241/04 ,  B01J23/72

CPC分类号： B01J27/1853 ,  B01J23/002 ,  B01J23/755 ,  B01J23/825 ,  B01J23/835 ,  B01J23/84 ,  B01J23/8435 ,  B01J23/8474 ,  B01J27/055 ,  B01J37/03 ,  B01J37/18 ,  B01J2523/00 ,  C07C209/16 ,  C07C209/78 ,  C07C213/02 ,  C07D295/023 ,  Y02P20/582 ,  B01J2523/17 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/44 ,  B01J2523/53 ,  C07C211/10 ,  C07C217/08

摘要： Processes for preparing an amine, the processes comprising: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, and nickel, 1.5 to 4.5% by weight of an oxygen compound of cobalt, calculated as CoO, and 0.2 to 5.0% by weight of at least one oxygen compound of niobium, sulfur, phosphorus, gallium, boron, lead or antimony, calculated in each case as Nb2O5, H2SO4, H3PO4, Ga2O3, B2O3, PbO and Sb2O3 respectively, and wherein the catalytically active composition does not comprise any molybdenum.

摘要翻译： 用于制备胺的方法，所述方法包括：使选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺， 仲胺及其混合物，在二氧化锆，含铜和镍的催化剂存在下; 其中所述催化剂包含催化活性组合物，其在用氢还原之前包括锆，铜和镍的氧化合物，1.5至4.5重量％的作为CoO计算的氧化合物钴和0.2至5.0重量％ 的铌，硫，磷，镓，硼，铅或锑的至少一种氧化合物，分别以Nb 2 O 5，H 2 SO 4，H 3 PO 4，Ga 2 O 3，B 2 O 3，PbO和Sb 2 O 3计算，其中催化活性组合物不包含 任何钼。

公开(公告)号：US20100105546A1

公开(公告)日：2010-04-29

申请号：US12606459

申请日：2009-10-27

申请人： Wen-Qing Xu ,  David Beijia Xu

发明人： Wen-Qing Xu ,  David Beijia Xu

IPC分类号： B01J23/755 ,  B01J23/10 ,  B01J21/06 ,  B01J21/04

CPC分类号： B01J23/755 ,  B01J23/78 ,  B01J23/83 ,  B01J23/835 ,  B01J23/8435 ,  B01J23/8437 ,  B01J23/8474 ,  B01J23/883 ,  B01J23/888 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/108 ,  B01J35/109 ,  B01J37/031 ,  B01J37/04 ,  C01B3/40 ,  C01B2203/0227 ,  C01B2203/1058 ,  Y02P20/52

摘要： The present invention relates unique pore structures in nickel supported on alumina with the negligible formation of macropores. Incorporation of additional elements stabilizes the pore structure of the nickel supported on alumina. Additional element(s) were then further added into the nickel-supported materials. These additional element(s) further stabilize the pore structures under heating conditions. The improvements of pore structure stability under heating conditions and negligible presence of macropores limit the sintering of nickel metal to a mechanism of impeded diffusion. The negligible presence of macropores also limits the deposition of alkali metal hydroxide(s)/carbonate(s) on the outer shell of the catalyst pellet in the molten carbonate fuel cells. Both the negligible presence of macropores and improvement in pore structure stability allow for prolonging the catalyst life of these nickel supported on alumina catalysts of the present invention for reforming hydrocarbons.

摘要翻译： 本发明涉及在负载在氧化铝上的镍中的独特的孔结构，可以忽略大孔的形成。 附加元素的结合稳定了负载在氧化铝上的镍的孔结构。 然后将另外的元素加入到镍负载的材料中。 这些附加元件在加热条件下进一步稳定孔结构。 加热条件下孔结构稳定性的改善和大孔存在的微不足道限制了镍金属的烧结成阻碍扩散的机理。 大孔的可忽略的存在也限制了熔融碳酸盐燃料电池中催化剂颗粒的外壳上的碱金属氢氧化物/碳酸盐的沉积。 微孔存在的微不足道和孔结构稳定性的改善使得延长本发明用于重整烃的氧化铝催化剂上的这些镍的催化剂寿命。

公开(公告)号：US20020088964A1

公开(公告)日：2002-07-11

申请号：US09770088

申请日：2001-01-25

发明人： Jeffery L. Tallon ,  Robert G. Buckley ,  Murray R. Presland

IPC分类号： H01B001/00 ,  H01C001/00

CPC分类号： H01M8/1246 ,  B01J23/002 ,  B01J23/76 ,  B01J23/83 ,  B01J23/8435 ,  B01J23/8437 ,  B01J35/0033 ,  B01J2523/00 ,  C04B35/4504 ,  C04B35/4521 ,  C04B35/4525 ,  H01L39/12 ,  H01L39/126 ,  H01L39/2464 ,  H01M4/9016 ,  H01M6/185 ,  Y02E60/525 ,  Y02P70/56 ,  Y10S505/742 ,  B01J2523/17 ,  B01J2523/23 ,  B01J2523/24 ,  B01J2523/36 ,  B01J2523/44 ,  B01J2523/54 ,  B01J2523/12

摘要： The invention provides certain novel metal oxide materials which exhibit superconductivity at elevated temperatures and/or which are useful in electrode, electrolyte, cell and sensor applications, or as electrochemical catalysts. The metal oxide materials are generally within the formulaRnnull1nullunullsAuMmnulleCun0wnullnull(1)where nnull0 and n is an integer or a non-integer, 1nullmnull2, 0nullsnull0.4, 0nullenull4, and 2nnull(1/2) 0 and distorted or undistorted substantially square sheets of R for n>1.

摘要翻译： 本发明提供某些新颖的金属氧化物材料，其在升高的温度下表现出超导性和/或可用于电极，电解质，电池和传感器应用，或用作电化学催化剂。 金属氧化物材料通常在式（1）中，其中n> = 0，并且其中n> 0和 n是整数或非整数，1 <= m <= 2,0 <= s <= 0.4,0 <= e <= 4和2n +（1/2） = 1，u为2，对于0 <= n <1，u为n + 1，其中R和A各自为Y，La，Ce，Pr，Nd中的任意一种或任意组合 ，Sm，Eu，Gd，Dy，Ho，Er，Tm，Yb，Lu，Ca，Sr，Ba，Li，Na，K，Rb或Cs; M是Cu，Bi，Sb，Pb，Tl或任何其它过渡金属中的任何一种或任何组合; Cu是由Bi，Sb，Pb，Tl或任何其它过渡金属中的任何一种或任何组合部分取代的Cu或Cu; 0为0或0，部分被N，P，S，Se或F中的任一个取代; 并且其中当n> 0时，材料的结构的特征在于变形或未失真的基本上正方形的CuO 2片状片，并且对于n> 1，失真或未失真的大致正方形的R片。