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    Polymerization catalyst system additives
    1.
    发明授权
    Polymerization catalyst system additives 失效
    聚合催化剂体系添加剂

    公开(公告)号：US3625864A

    公开(公告)日：1971-12-07

    申请号：US3625864D

    申请日：1969-04-23

    申请人： PHILLIPS PETROLEUM CO

    发明人： HORVATH BERTALAN

    IPC分类号： C08F10/00 ,  C08D3/04

    CPC分类号： C08F10/00 ,  C08F4/18

    摘要： A method of preparing a polymerization catalyst which involves impregnating a catalyst support with chromium oxide and a titanium complex formed by reacting a titanium alkoxide a compound selected from the group consisting of R''xSn(OH)m and R''''pB(OH)q in which R'' and R'''' are selected from the group consisting of alkyl, aryl, and cycloalkyl radicals and combinations thereof.

    Polymerization catalyst
    2.
    发明授权
    Polymerization catalyst 失效

    公开(公告)号：US3622522A

    公开(公告)日：1971-11-23

    申请号：US3622522D

    申请日：1968-05-08

    申请人： PHILLIPS PETROLEUM CO

    发明人： HORVATH BERTALAN

    IPC分类号： C08F10/00 ,  C08D3/04 ,  C08D3/08

    CPC分类号： C08F10/00 ,  C08F4/22

    摘要： A catalyst is formed by combining a support material with (1) a chromium-containing compound such as chromium trioxide and (2) at least one of a gallium-containing compound such as gallium isopropoxide, and a tin-containing compound such as tin isopropoxide, and then activating the catalyst by heating at a temperature of at least 1,700* F. Polymers such as polyethylene formed using the catalyst of this invention have a narrow molecular weight distribution.

    Polymerization using a supported chromia activated with a tin on gallium compound
    3.
    发明授权
    Polymerization using a supported chromia activated with a tin on gallium compound 失效
    使用支持的羧基化合物进行聚合反应

    公开(公告)号：US3676417A

    公开(公告)日：1972-07-11

    申请号：US3676417D

    申请日：1971-02-25

    申请人： PHILLIPS PETROLEUM CO

    发明人： HORVATH BERTALAN

    IPC分类号： B01J23/26 ,  C08F10/00 ,  C08F1/66 ,  C08F3/06

    CPC分类号： B01J23/26 ,  C08F10/00 ,  C08F4/22

    摘要： A catalyst is formed by combining a support material with (1) a chromium-containing compound such as chromium trioxide and (2) at least one of a gallium-containing compound such as gallium isopropoxide, and a tin-containing compound such as tin isopropoxide, and then activating the catalyst by heating at a temperature of at least 1,700* F. Polymers such as polyethylene formed using the catalyst of this invention have a narrow molecular weight distribution.

    摘要翻译： 通过将载体材料与（1）含铬化合物如三氧化铬和（2）含镓化合物如异丙氧基镓中的至少一种以及含锡化合物如异丙醇锡组合来形成催化剂 ，然后在至少1700℃的温度下加热活化催化剂。使用本发明的催化剂形成的聚合物如聚乙烯具有窄的分子量分布。