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公开(公告)号：US3875126A
公开(公告)日：1975-04-01
申请号：US32308073
申请日：1973-01-12
摘要： An Alpha -olefin is polymerized with another monomer through the use of a catalyst system prepared by combining: (I) a solid composition prepared by milling titanium trichloride in the presence of modifier, which is a halohydrocarbon, a silicon compound represented by the general formula SiXm'' Y4 m'' , where X'' is a halogen, Y'' is hydrogen, an alkyl group, an aryl group, an aralkyl group, an alkaryl group, or an alkoxyl group, and m is zero or the integer 1, 2, 3, or 4 (exclusive of SiH4), or a halogen compound of a specific metal; (II) an organoaluminum compound; and (III) a cycloheptatriene compound, including salts of tropylium.
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公开(公告)号：US3769373A
公开(公告)日：1973-10-30
申请号：US3769373D
申请日：1959-05-27
申请人： ICI LTD
发明人： REED H , WILKINSON A
IPC分类号： C08F10/00 , C08F110/06 , C08F3/02 , C08F3/08
CPC分类号： C08F10/00 , C08F110/06 , Y10S526/906 , C08F4/655 , C08F4/646
摘要： A COMPONENT OF AN OLEFINE POLYMERISATION CATALYST IS PREPARED BY THE REACTION BETWEEN ALUMINUM AND TITANIUM TETRACHLORIDE PREFERABLY UNDER REFLUX CONDITIONS IN THE PRESENCE OF ALUMINUM CHLORIDE. THE PRODUCT HAS THE APPROXIMATE EMPIRICAL FORMULA ALTI3CL12 AND WHEN BALLMILLED FORMS A HIGHLY ACTIVE POLYMERISATION CATALYST IN COMBINATION WITH AN ORGANO-ALUMINUM COMPOUND.
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公开(公告)号：US3705139A
公开(公告)日：1972-12-05
申请号：US3705139D
申请日：1970-10-26
申请人： LION FAT OIL CO LTD
发明人： YAMANE IZUMI , NAGAYAMA MASUZO , TAKAI MAKOTO
CPC分类号： C08K5/0075 , Y10S260/15 , Y10S260/19 , Y10S524/913
摘要： A HIGH MOLECULAR COMPOSITION COMPRISING A HIGH MOLECULAR SUBSTANCE CONTAINING ONE MEMBER SELECTED FROM THE GROUP CONSISTING OF ALKYL SULFIDE COMPOUNDS AS AN ANTISTATIC AGENT, SAID COMPOUNDS BEING EXPRESSED BY THE FOLLOWING GENERAL FORMULAS A AND B:
(A) R1.S.R2.A(R3-O)NZ
(WHEREIN R1 REPRESENTS A HYDROCARBON RADICAL HAVING 622 CARBON ATOMS; R2 AND R3 EACH REPRESENTS A HYDROCARBON RADICAL HAVING 1-4CARBON ATOMS; A REPRESENTS OXYGEN OR NITROGEN, AND, IN CASE A REPRESENTS NITROGEN, SAID GENERAL FORMULA IS REPRESENTED BY
R1-S-R2-N((-R3-O)N-Z)2
N REPRESENTS AN INTEGER IN THE RANGE OF 0-100; AND Z REPRESENTS HYDROGEN OR COR4 WHEREIN R4 REPRESENTS A HYDROCARBON RADICAL HAVING 1-22 CARBON ATOMS); AND
R1-SO-R2-O-(R2-O)N-H
(WHEREIN R1 REPRESENTS A HYDROCARBON RADICAL HAVING 622 CARBON ATOMS; R2 AND R3 EACH REPRESENTS A HYDROCARBON RADICAL HAVING 1-4 CARBON ATOMS; AND N REPRESENTS AN INTEGER IN THE RANGE OF 0-100).-
公开(公告)号：US3678024A
公开(公告)日：1972-07-18
申请号：US3678024D
申请日：1970-01-05
申请人： DOW CHEMICAL CO
发明人： LIU GORDON Y T , STRANGE CARL P
CPC分类号： C08J3/24 , B29C47/0004 , B29C47/0014 , B29C47/0016 , B29K2023/00 , B29K2101/10 , B29K2105/20 , B29K2105/24 , C08J2323/02
摘要： Ethylene polymers are crosslinked in the absence of crosslinking agents by working the normally solid olefin polymer, e.g., polyethylene, at temperatures just above the melting point of the polymer and at higher than normal shear rates, e.g., greater than 3,000 sec 1.
摘要翻译： 乙烯聚合物在不存在交联剂的情况下通过在正好高于聚合物熔点的温度下操作常规固体烯烃聚合物，例如聚乙烯，并且高于正常剪切速率，例如大于3000秒-1 。
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公开(公告)号：US3661884A
公开(公告)日：1972-05-09
申请号：US3661884D
申请日：1969-07-07
发明人： SHELL FRANCIS J , ZETMEIR NORRIS D
摘要： CRUDE AMORPHOUS POLYOLEFINS, BY-PRODUCTS OF POLYOLEFIN PRODUCTION, CONTAIN QUANTITIES OF CATALYST RESIDUES INCLUDING DISCOLORING AGENTS SUCH THAT THE CRUDE MATERIAL IS DARK, HIGHLY VISCOUS-TO-SOLIDS, FLAMMABLE AND CORROSIVE WASTE. BY TREATING THE CRUDE PRODUCT IN A LIQUID TWOPHASE PURIFICATION PROCESS, THE AMORPHOUS POLYOLEFIN IS SEPARATED AND RECOVERED AS A USABLE, SAFE-TO-HANDLE, ESSENTIALLY COLOR FREE, MATERIAL. THE CATALYST RESIDUE ALSO IS RECOVERED.
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6.发明授权Vanadye compound having cyclic hydrocarbon substituent and polymerization catalyst containing said compound 失效具有环状烃取代基的挥发性化合物和含有化合物的聚合催化剂
公开(公告)号：US3655583A
公开(公告)日：1972-04-11
申请号：US3655583D
申请日：1969-07-23
申请人： SUMITOMO CHEMICAL CO
CPC分类号： C08F10/00 , Y10S526/905 , C08F4/68
摘要： NOVEL VANADYL COMPOUNDS OF THE FORMULA
VO(OR)MX3-M
WHERE R IS A GROUP CONTAINING A CYCLIC HYDROCARBON HAVING 5 TO 20 CARBON ATOMS, X IS A HALOGEN ATOM AND M IS AN INTEGER FROM 1 TO 3, ARE MIXED WITH ORGANOALUMINUM COMPOUNDS TO MAKE CATALYSTS USEFUL FOR HOMOPOLYMERIZING OR COPOLYMERIZING ALPHA-MONOOLEFINS IN SOLUTION, IF DESIRED WITH A POLYENE SUCH AS A CONJUGATED OR NON-CONJUGATED DIENE. EXAMPLE OF THE VANADIUM COMPOUNDS ARE VANADYL TRICYCLOHEXOXIDE, MONOCHLOROVANADYL DICYCLOHEXOXIDE, VANADYL, TRIBORNYLOXIDE AND MONOCHLOROVANADYL DINORBORNYLMETHOXIDE. CONJUGATED DIENES HAVE LESS RETARDING EFFECT ON THE CATALYST THAN ON CONVENTIONAL CATALYST.-
公开(公告)号：US3607853A
公开(公告)日：1971-09-21
申请号：US3607853D
申请日：1969-10-09
申请人： BAYER AG
发明人： OBERKIRCH WOLFGANG , GUNTHER PETER , WITTE JOSEF
CPC分类号： C08G61/08 , Y10S526/907
摘要： A process for the polymerization of cyclopentene with ringopening, in which cyclopentene dissolved in an inert organic solvent is polymerized in the presence of a catalyst, characterized in that an organometallic mixed catalyst of A. A MOLYBDENUM, TUNGSTEN OR TANTALUM SALT, B. TERTIARY BUTYL HYPOHALITE, C. AN ORGANIC ALUMINUM COMPOUND IN THE MOLAR RATIO OF A : B : C AS 1 : 0.1 TO 5 : 0.8 TO 15 IS USED.
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8.发明授权
公开(公告)号：US3458488A
公开(公告)日：1969-07-29
申请号：US3458488D
申请日：1966-10-24
申请人： INT SYNTHETIC RUBBER
IPC分类号： C08F236/04 , C08F3/02
CPC分类号： C08F236/04 , C08F4/7095
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公开(公告)号：US3442820A
公开(公告)日：1969-05-06
申请号：US3442820D
申请日：1966-03-30
申请人： HERCULES INC
发明人： DIECKMANN STEFFEN F
CPC分类号： C08F10/00 , Y10S526/904 , C08F4/655
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公开(公告)号：US3439057A
公开(公告)日：1969-04-15
申请号：US3439057D
申请日：1967-09-01
发明人： CALDERON NISSIM
CPC分类号： B01J31/0217 , B01J31/0202 , B01J31/143 , B01J31/34 , C07C6/04 , Y10S585/94 , C07C13/02
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