公开(公告)号：US3651092A

公开(公告)日：1972-03-21

申请号：US3651092D

申请日：1970-05-25

Applicant: PHILLIPS PETROLEUM CO

Inventor： STAPP PAUL R ,  NOWACK GERHARD P ,  JOHNSON MARVIN M

IPC: C07D307/28 ,  C07D309/18 ,  C07D5/10 ,  C07D7/10

CPC classification number: C07D307/28 ,  C07D309/18

Abstract: CYCLIC OLEFINICALLY UNSATURATED ETHERS CONTAINING 4 TO 5 RING CARBON ATOMS ARE ISOMERIZED BY CONTACT WITH A CATALYST CONTAINING NICKEL AND ARSENIC IN A HYDROGEN ATMOSPHERE. THE ISOMERIZATION REACTION IS FAVORABLY INFLUENCED BY THE PRESENCE OF CARBON MONOXIDE. THE ISOMERIZATION PRODUCTS ARE USEFUL SOLVENTS AND INTERMEDIATES FOR THE PREPARATION OF USEFUL CHEMICALS SUCH AS POLYMERS, POLYFUNCTIONAL ALCOHOLS AND THE LIKE.

公开(公告)号：US3912787A

公开(公告)日：1975-10-14

申请号：US48177474

申请日：1974-06-21

Applicant: PHILLIPS PETROLEUM CO

Inventor： NOWACK GERHARD P ,  JOHNSON MARVIN M

IPC: C07C5/11 ,  C07C5/10

CPC classification number: C07C5/11 ,  C07C2521/04 ,  C07C2523/06 ,  C07C2523/34 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2601/16 ,  C07C2602/10 ,  C07C13/20 ,  C07C13/48

Abstract: Aromatics are selectively partially hydrogenated to substantial amounts of cyclic olefins by contacting the aromatics under hydrogenation conditions with hydrogen and with an aqueous dispersion of a solid ruthenium-containing catalyst promoted with a modifying amount of a transition metal and wherein the aqueous dispersion is maintained at essentially neutral or acid pH conditions.

公开(公告)号：US3900526A

公开(公告)日：1975-08-19

申请号：US39079973

申请日：1973-08-23

Applicant: PHILLIPS PETROLEUM CO

Inventor： JOHNSON MARVIN M ,  TABLER DONALD C ,  NOWACK GERHARD P

IPC: B01J23/843 ,  C07C7/163 ,  C07C7/167 ,  C07C11/00

CPC classification number: C07C7/163 ,  B01J23/843 ,  C07C7/167 ,  C07C2521/04 ,  C07C2523/755 ,  C07C2523/843 ,  C07C2601/18 ,  C07C2601/20 ,  C07C11/167

Abstract: A method and catalysts for selective hydrogenation and isomerization which involves contacting a feedstream with hydrogen and with various supported catalysts of metallic arsenides and antimonides, with carbon monoxide being optionally introduced into the reaction as a modifier.

公开(公告)号：US3692853A

公开(公告)日：1972-09-19

申请号：US3692853D

申请日：1970-12-28

Applicant: PHILLIPS PETROLEUM CO

Inventor： NOWACK GERHARD P

IPC: B01J23/18 ,  C07C5/22 ,  C07C5/25

CPC classification number: C07C5/226 ,  B01J23/18 ,  C07C5/2226 ,  C07C5/2525 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2523/06 ,  C07C2523/18 ,  C07C13/20

Abstract: A method for isomerizing olefinic hydrocarbons which employs a zinc arsenide catalyst, the arsenide being present in relation to the zinc in a molal ratio between about 0.33 and 3.0.

Abstract translation: 使用砷化砷催化剂异构化烯烃的方法，所述砷以相对于锌的摩尔比在约0.33至3.0之间存在。

公开(公告)号：US3636175A

公开(公告)日：1972-01-18

申请号：US3636175D

申请日：1970-11-23

Applicant: PHILLIPS PETROLEUM CO

Inventor： NOWACK GERHARD P

IPC: C07C5/05 ,  C07C13/263 ,  C07C13/275 ,  C07C5/06 ,  C07C5/14 ,  C07C5/16

CPC classification number: C07C13/275 ,  C07C5/05 ,  C07C13/263 ,  C07C2523/843 ,  C07C2601/18 ,  C07C2601/20

Abstract: AN IMPROVED METHOD FOR SELECTIVE HYDROGENATION OF NON-CONJUGATED CYCLIC POLYENE TO THE CORRESPONDING CYCLIC MONOOLEFINS WITH METAL ARSENIDE AND METAL ANTIMONIDE HYDROGENATION CATALYSTS WHICH COMPRISES CONTACTING THE FEED POLYENES WITH A DOUBLE BOND ISOMERIZATION CATALYST PRIOR TO, WITH OR IN CONJUCTION WITH, CONTACT OF THE FEED.

公开(公告)号：US3697448A

公开(公告)日：1972-10-10

申请号：US3697448D

申请日：1970-06-08

Applicant: PHILLIPS PETROLEUM CO

Inventor： JOHNSON MARVIN M ,  TABLER DONALD C ,  NOWACK GERHARD P

IPC: B01J23/843 ,  C07C5/25 ,  B01J11/06 ,  B01J11/22

CPC classification number: C07C5/2525 ,  B01J23/843 ,  C07C5/2556 ,  C07C2521/04 ,  C07C2523/755 ,  C07C2523/843 ,  C07C2601/20 ,  Y10S585/906 ,  C07C11/02

Abstract: A METHOD AND CATALYSTS FOR SELECTIVE HYDROGENATION AND ISOMERIZATION WHICH INVOLVES CONTACTING A FEEDSTREAM WITH HYDROGEN AND WITH VARIOUS SUPPORTED CATALYSTS OF MATALLIC ARSENIDES AND ANTIMONIDES, WITH CARBON MONOXIDE BEING OPTIONALLY INTRODUCED INTO THE REACTION AS A MODIFIER.

公开(公告)号：US3637877A

公开(公告)日：1972-01-25

申请号：US3637877D

申请日：1970-06-03

Applicant: PHILLIPS PETROLEUM CO

Inventor： NOWACK GERHARD P ,  JOHNSON MARVIN M

IPC: B01J31/28 ,  C07C5/05 ,  C07C5/06 ,  C07C5/14 ,  C07C5/16

CPC classification number: C07C5/05 ,  B01J23/8973 ,  B01J31/0202 ,  B01J31/0207 ,  B01J31/0208 ,  B01J31/0237 ,  B01J31/04 ,  B01J31/28 ,  B01J2231/645 ,  C07C2523/843 ,  C07C2601/18 ,  C07C13/00 ,  C07C13/263

Abstract: A METHOD OF MODIFYING IRON, COBALT AND NICKEL-CONTAINING CATALYSTS EMPLOYED FOR THE HYDROGENATION OF DIOLEFINS AND TRIOLEFINS TO MONOOLEFINS WHICH INVOLVES INTRODUCING INTO CONTACT WITH THE REACTANTS A MATERIAL SELECTED FROM TRHE GROUP CONSISTING OF ORGANIC ACIDS, ALDEHYDES, KETONES, ANHYDROUS AMMONIA, AMINES AND METHANOL.