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公开(公告)号:US20240128440A1
公开(公告)日:2024-04-18
申请号:US18277868
申请日:2022-01-24
Inventor: Nobuhiro Hirano , Yusuke Fukumoto , Masanori Sugimori , Yuji Yokoyama
CPC classification number: H01M4/364 , H01M4/0404 , H01M4/386 , H01M4/583 , H01M4/625 , H01M10/0525 , H01M2004/027
Abstract: This negative electrode for a lithium ion secondary battery is characterized by comprising a negative electrode mixture layer containing a carbon-based negative electrode active material, a Si-based negative electrode active material, and carbon nanotubes, wherein when 100 is the ratio at which the carbon nanotubes coat the surface of the Si-based negative electrode active material, the ratio at which the carbon nanotubes coat the surface of the carbon-based negative electrode active material is at least 20 but no higher than 50.
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公开(公告)号:US20240055613A1
公开(公告)日:2024-02-15
申请号:US18267304
申请日:2021-11-26
Inventor: Yusuke Fukumoto , Nobuhiro Hirano , Masanori Sugimori , Yuji Yokoyama
IPC: H01M4/62 , C01B32/174 , C09D5/24 , C09D7/61 , C09D101/28 , H01M4/587 , H01M4/38 , H01M4/133 , H01M4/134 , H01M4/36
CPC classification number: H01M4/625 , C01B32/174 , C09D5/24 , C09D7/61 , C09D101/286 , H01M4/587 , H01M4/386 , H01M4/133 , H01M4/134 , H01M4/364 , C01B2202/22 , C01P2006/22 , C01B2202/28 , C01P2004/62 , C01P2004/61 , C01P2004/53
Abstract: Provided is an electrode slurry carbon nanotube liquid dispersion which improves charge/discharge cycle characteristics. An electrode slurry carbon nanotube liquid dispersion which is one aspect of the present disclosure and contains 0.1-1.5 mass % of carbon nanotubes, a dispersion medium, and carboxymethyl cellulose, the viscosity of which at 100 s−1 in a 3% aqueous solution is 2-200 mPa·s, wherein: the carboxymethyl cellulose content constitutes 50-250 parts by mass relative to 100 parts by mass of carbon nanotubes; the viscosity at 100 s−1 is 50-200 mPa·s in a state in which the carbon nanotubes are dispersed; and the particle distribution according to the laser diffraction method exhibits a D10 of 0.3-1.0 μm, a D50 of 3-10 μm and a D90 of 60 μm or less in a state in which the carbon nanotubes are dispersed.
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公开(公告)号:US20240105958A1
公开(公告)日:2024-03-28
申请号:US18267234
申请日:2021-12-06
Inventor: Masanori Sugimori , Yusuke Fukumoto , Yuji Yokoyama , Nobuhiro Hirano
IPC: H01M4/62 , B82Y30/00 , H01M4/1393 , H01M4/38 , H01M10/0525
CPC classification number: H01M4/625 , B82Y30/00 , H01M4/1393 , H01M4/386 , H01M10/0525 , H01M2004/027
Abstract: Provided is a carbon nanotube dispersion liquid for an electrode slurry such that it is possible to inhibit a decrease in a charge-discharge cycle characteristic. A carbon nanotube dispersion liquid for an electrode slurry according to one aspect of the present disclosure includes carbon nanotubes having a diameter of 0.4 to 2 nm, a dispersant, and a dispersion medium. In a Raman spectroscopy spectrum, the carbon nanotubes have a G/D ratio, which is the ratio of the peak intensities of the G-band (1560 to 1600 cm−1) and the D-band (1310 to 1350 cm−1), within the range of 50 to 200, and in a volume-based particle size distribution via a laser diffraction method, the carbon nanotubes have 3 to 5 peaks, and if the peaks are, from the small particle diameter side, P1, P2, . . . , Pn, the greatest frequency peak is in the range pf P2 to Pn-1.
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