公开(公告)号：US07695783B2

公开(公告)日：2010-04-13

申请号：US10622421

申请日：2003-07-18

申请人： Paul B. Merkel ,  Gary N. Barber ,  Alan R. Pitt ,  Trevor J. Wear

发明人： Paul B. Merkel ,  Gary N. Barber ,  Alan R. Pitt ,  Trevor J. Wear

IPC分类号： B41M5/50

CPC分类号： B41M5/52 ,  B41M5/5218 ,  B41M5/529

摘要： The invention relates to an image-recording element comprising a support and an image-receiving layer, wherein the image-receiving layer comprises anionic colloidal silica particles, hydrophilic polymeric binder, and fluorosurfactant, wherein the binder is present in an amount of between 2% and 15% weight of the image-receiving layer, the image-recording element has a 60-degree gloss of greater than 25, and a dry time of less than 1 minute.

摘要翻译： 本发明涉及一种图像记录元件，包括支撑体和图像接收层，其中图像接收层包括阴离子胶体二氧化硅颗粒，亲水性聚合物粘合剂和含氟表面活性剂，其中粘合剂的含量为2％ 和图像接收层的15重量％，图像记录元件具有大于25的60度光泽度和小于1分钟的干燥时间。

公开(公告)号：US06468727B2

公开(公告)日：2002-10-22

申请号：US09770129

申请日：2001-01-26

申请人： Alan R. Pitt ,  Trevor J. Wear ,  Danuta Gibson ,  Ian M. Newington ,  Mary C. Brick ,  John W. Boettcher ,  Gary N. Barber

发明人： Alan R. Pitt ,  Trevor J. Wear ,  Danuta Gibson ,  Ian M. Newington ,  Mary C. Brick ,  John W. Boettcher ,  Gary N. Barber

IPC分类号： G03C108

CPC分类号： B01F17/0057 ,  G03C1/005 ,  G03C7/3882 ,  G03C7/3885 ,  G03C2001/0854

摘要： A hydrophobically capped oligomeric acrylamide or pyrrolidone is employed as a dispersant for hydrophobic materials in an aqueous medium containing a hydrophilic colloid, e.g. gelatin. The hydrophobic materials include photographic addenda such as color couplers or solid particle dyes. Preferred dispersants have the general formula R—L—T   (1) or in which R, R1 and R2 are each independently selected from aliphatic hydrocarbyl, aryl-(aliphatic hydrocarbyl) and (aliphatic hydrocarbyl)-aryl groups, L is a sulphur atom or a linking group that contains a sulphur atom attached to the T group, and T is a hydrophilic oligomeric group obtained by the oligomerisation of one or more vinyl monomers having an amido function.

摘要翻译： 疏水封端的低聚丙烯酰胺或吡咯烷酮在含有亲水胶体的水性介质中用作疏水性材料的分散剂。 明胶。 疏水性材料包括照相附加物，如成色剂或固体颗粒染料。 优选的分散剂具有通式，其中R 1，R 2和R 2各自独立地选自脂族烃基，芳基 - （脂族烃基）和（脂族烃基） - 芳基，L是硫原子或连接基团， T基团，和T是通过一种或多种具有酰氨基官能团的乙烯基单体的低聚获得的亲水性低聚基团。

公开(公告)号：US08318853B2

公开(公告)日：2012-11-27

申请号：US12665040

申请日：2008-06-19

申请人： Andrew M. Howe ,  Trevor J. Wear ,  Alan R. Pitt ,  Ian M. Newington ,  John H. Hone

发明人： Andrew M. Howe ,  Trevor J. Wear ,  Alan R. Pitt ,  Ian M. Newington ,  John H. Hone

IPC分类号： C08L39/00 ,  B05D3/02 ,  B41J2/15

CPC分类号： B01F17/0057 ,  B41M5/52 ,  B41M5/5218 ,  C09D5/027 ,  C09D7/45 ,  C09D11/326

摘要： A thermally-responsive dispersant for an aqueous dispersion of positively- or negatively-charged or chargeable solid or liquid particulates, comprises a compound having an anchoring moiety linked to a thermally-responsive polymeric stabilizing moiety, other than a polyalkylene oxide, the polymeric moiety having a lower affinity for the surface than the anchoring group below the thermal transition temperature, the particulates being positively-charged or chargeable when the anchoring moiety contains an acid and/or hydroxy group and has a net acidity or neutrality and the particulates being negatively-charged or chargeable when the anchoring moiety has a basic group and has a net basicity, wherein the dispersion exhibits a change in sign from negative to positive and an increase in magnitude of a rheological property (viscosity at low shear and/or complex modulus at low amplitude oscillatory shear), on increasing the temperature from below to above the thermal transition temperature.

摘要翻译： 用于带正电荷或带负电荷或带电荷的固体或液体颗粒的水性分散体的热响应性分散剂包括具有与热响应性聚合物稳定化部分连接的锚定部分的化合物，而不是聚环氧烷，所述聚合物部分具有 当锚定部分含有酸和/或羟基并且具有净酸度或中性并且颗粒带负电荷时，对于表面的亲和力低于锚定基团低于热转变温度的亲和力，所述颗粒被带正电或带电 或者当锚定部分具有碱性基团并且具有净碱度时可带电，其中分散体显示从负到正的变化和流变特性的大小（低剪切时的粘度和/或低振幅下的复数模量） 振荡剪切），将温度从低到高于热转变温度。

公开(公告)号：US08202926B2

公开(公告)日：2012-06-19

申请号：US12097770

申请日：2006-12-19

申请人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe ,  Ian M. Newington

发明人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe ,  Ian M. Newington

IPC分类号： C08K3/10

CPC分类号： B01F17/0028 ,  B01F17/005 ,  C09B67/009

摘要： The invention provides a dispersant for an aqueous dispersion of negatively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one basic group and having an overall basicity and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The invention also provides a coating composition containing the dispersant, an inkjet recording element containing the dispersant and methods of coating or reducing viscosity using the dispersant.

摘要翻译： 本发明提供了一种用于带负电或可带电的固体颗粒的水分散体的分散剂，其包含具有与聚合亲水部分连接的锚定部分的化合物，所述锚定部分含有至少一个碱性基团并具有总碱性，并且聚合部分具有 对颗粒表面的亲和力比锚定部分低。 本发明还提供含有分散剂的涂料组合物，含有分散剂的喷墨记录元件和使用分散剂涂布或降低粘度的方法。

公开(公告)号：US06482975B1

公开(公告)日：2002-11-19

申请号：US09857877

申请日：2001-06-12

申请人： Alan R. Pitt ,  Trevor J. Wear

发明人： Alan R. Pitt ,  Trevor J. Wear

IPC分类号： C07C6934

CPC分类号： G03C1/895 ,  C07C69/34 ,  C07C69/63 ,  C07C323/52

摘要： Optionally fluorine-substituted alkyl or alkenyl poly(ethylene oxides) the compounds of the general formula in which R is an alkyl group with 10-20 carbon atoms, an alkenyl group with 10-20 carbon atoms or a fluoroalkyl or fluoroalkenyl group with f carbon atoms that each bear at least one fluorine atom and g carbon atoms that bear only hydrogen atoms, in which 1.5 f+g=10-20 and g may optionally be zero. R′ is an alkyl group with 1 to 4 carbon atoms, L is a linking group, a linking atom or a chemical bond, and p is at least 2, q is at least 2 and p+q=from 4 to 100, may be prepared by reacting maleic anhydride with a poly(ethylene glycol) alkyl. ether and reacting the resultant intermediate product with a compound of the formula RL′H in which L′ is a linking group or linking atom. Compounds of the formula (1) may also be prepared by reacting RL-substituted succinic anhydrides with a alkyl end-capped polyethylene glycol. The compounds of the formula (1) exhibit good solubility and surface activity and may be used as antistats, particularly in gelatin media, optionally in conjunction with lithium triflate or the like, in photographic coatings.

摘要翻译： 任选氟取代的烷基或烯基聚（环氧乙烷），其中R为具有10-20个碳原子的烷基，具有10-20个碳原子的烯基或具有f个碳原子的氟代烷基或氟烯基的通式化合物 各自承担至少一个仅含有氢原子的氟原子和g个碳原子，其中1.5f + g = 10-20，g可以任选地为0.R'是具有1至4个碳原子的烷基，L是 连接基团，连接原子或化学键，并且p为至少2，q为至少2且p + q = 4至100，可以通过使马来酸酐与聚（乙二醇）烷基反应来制备。 醚，并使所得中间产物与其中L'为连接基团或连接原子的式RL'H化合物反应。 式（1）化合物也可以通过使RL取代的琥珀酸酐与烷基封端的聚乙二醇反应来制备。 式（1）的化合物表现出良好的溶解性和表面活性，并且可以用作抗静电剂，特别是在明胶介质中，任选地与三氟甲磺酸锂等一起在照相涂料中使用。

公开(公告)号：US06866902B2

公开(公告)日：2005-03-15

申请号：US10118723

申请日：2002-04-09

申请人： Jeanne E. Kaeding ,  Jeffrey W. Leon ,  Christine J. Landry-Coltrain ,  Alan R. Pitt ,  Trevor J. Wear ,  Gregory E. Missell ,  Dennis E. Smth

发明人： Jeanne E. Kaeding ,  Jeffrey W. Leon ,  Christine J. Landry-Coltrain ,  Alan R. Pitt ,  Trevor J. Wear ,  Gregory E. Missell ,  Dennis E. Smth

IPC分类号： B41J2/01 ,  B41M5/00 ,  B41M5/50 ,  B41M5/52 ,  C08F2/38 ,  C08F20/54 ,  B41M5/40

CPC分类号： B41M5/52 ,  B41M5/506 ,  B41M5/5218 ,  B41M5/5227 ,  B41M5/5254 ,  Y10T428/24802

摘要： An ink recording element is described comprising a support having thereon at least one image-receiving layer comprising polymeric particles in a polymeric binder, wherein the polymeric particle is stabilized by a hydrophobically-capped oligomeric acrylamide dispersant.

摘要翻译： 描述了一种墨水记录元件，其包括其上具有至少一个包含聚合物粘合剂中的聚合物颗粒的图像接收层的载体，其中聚合物颗粒通过疏水封端的低聚丙烯酰胺分散剂来稳定。

公开(公告)号：US5543555A

公开(公告)日：1996-08-06

申请号：US478624

申请日：1995-06-07

申请人： Alan R. Pitt ,  Julian C. Caesar ,  Danuta Gibson ,  Trevor J. Wear ,  David J. Young ,  Scott A. King

发明人： Alan R. Pitt ,  Julian C. Caesar ,  Danuta Gibson ,  Trevor J. Wear ,  David J. Young ,  Scott A. King

IPC分类号： B01F17/12 ,  G03C7/388 ,  C07C309/04 ,  B01F17/00 ,  G03C1/38

CPC分类号： G03C7/388 ,  Y10S516/01 ,  Y10S516/04

摘要： Surfactants useful as dispersing aids in the preparation of compositions comprising a hydrophilic colloid having hydrophobic particles dispersed therein have the structure ##STR1## wherein R is H or methyl provided that when each n=1, each R is methyl;M is a cation; and,n is an integer from 1 to 6.Such surfactants offer coating, photographic property and processing advantages when incorporated in photographic materials comprising a support bearing a plurality of hydrophilic colloid layers including at least one light-sensitive silver halide emulsion layer wherein at least one of the underlying hydrophilic colloid layers of the material contains hydrophobic particles dispersed therein with the aid of the surfactant.

摘要翻译： 可用作制备包含分散有疏水性颗粒的亲水胶体的组合物的分散助剂的表面活性剂具有其中R为H或甲基的结构，其中当n = 1时，每个R为甲基; M是阳离子; 并且n为1至6的整数。这些表面活性剂在掺入到包含支持多个亲水胶体层的载体的照相材料中时，具有涂层，照相性能和加工优点，所述亲水胶体层包括至少一种感光卤化银乳剂层，其中至少 材料的底层亲水胶体层之一借助表面活性剂包含分散在其中的疏水性颗粒。

公开(公告)号：US08063132B2

公开(公告)日：2011-11-22

申请号：US11722666

申请日：2005-12-22

申请人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe

发明人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe

IPC分类号： C04B26/06 ,  C08K3/10

CPC分类号： C09C1/407 ,  B01F17/0028 ,  B01F17/005 ,  B01F17/0057 ,  B01F17/0064 ,  C01F7/026 ,  C01P2004/64 ,  C01P2006/22

摘要： The invention provides a coating composition containing boehmite particles and a dispersant which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one acid and/or hydroxy group and having overall acidity or neutrality and the polymeric moiety having a lower affinity for a boehmite surface than the anchoring moiety. The anchoring moiety preferably contains at least two acid groups, preferably carboxylic acid groups, attached either in a [1,1], [1,2] or [1,3] relationship and is linked to the polymeric moiety, which is preferably derived from acrylamide or methacrylamide monomer units, preferably by a sulfur atom. The dispersant can reduce the viscosity of the boehmite dispersion and the tendency of the boehmite dispersion to increase in viscosity and/or form a gel or a yield stress material following periods of high shear stress.

摘要翻译： 本发明提供一种包含勃姆石颗粒和分散剂的涂料组合物，其包含具有与聚合亲水部分连接的锚定部分的化合物，所述锚定部分含有至少一个酸和/或羟基并具有总酸性或中性， 对勃姆石表面的亲和力比锚定部分低。 锚定部分优选包含至少两个以[1,1]，[1,2]或[1,3]关系连接的酸基，优选羧酸基，并且与聚合部分连接，优选衍生自 来自丙烯酰胺或甲基丙烯酰胺单体单元，优选为硫原子。 分散剂可以降低勃姆石分散体的粘度，并且在高剪切应力下，勃姆石分散体的粘度增加和/或形成凝胶或屈服应力材料的趋势。

公开(公告)号：US20080317960A1

公开(公告)日：2008-12-25

申请号：US12097770

申请日：2006-12-19

申请人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe ,  Ian M. Newington

发明人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe ,  Ian M. Newington

IPC分类号： B05D3/02 ,  C09D7/12

CPC分类号： B01F17/0028 ,  B01F17/005 ,  C09B67/009

摘要： The invention provides a dispersant for an aqueous dispersion of negatively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one basic group and having an overall basicity and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The invention also provides a coating composition containing the dispersant, an inkjet recording element containing the dispersant and methods of coating or reducing viscosity using the dispersant.

摘要翻译： 本发明提供了一种用于带负电或可带电的固体颗粒的水分散体的分散剂，其包含具有与聚合亲水部分连接的锚定部分的化合物，所述锚定部分含有至少一个碱性基团并具有总碱性，并且聚合部分具有 对颗粒表面的亲和力比锚定部分低。 本发明还提供含有分散剂的涂料组合物，含有分散剂的喷墨记录元件和使用分散剂涂布或降低粘度的方法。

公开(公告)号：US08153716B2

公开(公告)日：2012-04-10

申请号：US11722674

申请日：2005-12-22

申请人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe

发明人： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe

IPC分类号： C08K3/10

CPC分类号： B01F17/0028 ,  B01F17/005 ,  C01P2006/22 ,  C09C1/043 ,  C09C1/346 ,  C09C1/407 ,  C09C3/08 ,  C09D5/027 ,  C09D11/326 ,  C09D17/004

摘要： The invention provides a dispersant for an aqueous dispersion of positively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one acid and/or hydroxy group and having an overall acidity or neutrality and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The anchoring moiety preferably contains at least two acid groups, preferably carboxylic acid groups, attached either in a [1,1], [1,2] or [1,3] relationship and is linked to the polymeric moiety, which is preferably derived from acrylamide or methacrylamide monomer units, preferably by a sulfur atom. The dispersant can reduce the viscosity of an aqueous dispersion of positively charged or chargeable solid particulates and can reduce the tendency of the resulting dispersion to form a gel or a yield stress material. The dispersant facilitates the processing of the resulting compositions in manufacturing operations and it may be used, for example, as a component of a coating material, a ceramic, paint, refractory material, filler or in an inkjet recording paper or film. Additionally, the dispersant can allow the use of higher concentrations of solid particulates and enable control of the yield stress, as some yield is often beneficial in helping prevent or reduce sedimentation.

摘要翻译： 本发明提供了一种用于带正电或可带电的固体颗粒的水分散体的分散剂，其包含具有与聚合亲水部分连接的锚定部分的化合物，所述锚定部分含有至少一个酸和/或羟基并具有总酸性或 中性和聚合物部分对颗粒表面的亲和力低于锚定部分。 锚定部分优选包含至少两个以[1,1]，[1,2]或[1,3]关系连接的酸基，优选羧酸基，并且与聚合部分连接，优选衍生自 来自丙烯酰胺或甲基丙烯酰胺单体单元，优选为硫原子。 分散剂可以降低带正电或可带电的固体颗粒的水性分散体的粘度，并且可以降低所得分散体形成凝胶或屈服应力材料的倾向。 分散剂有助于在制造操作中对所得组合物的加工，并且其可以用作例如涂料，陶瓷，油漆，耐火材料，填料或喷墨记录纸或膜中的组分。 此外，分散剂可以允许使用较高浓度的固体颗粒并且能够控制屈服应力，因为一些产率通常有助于防止或减少沉降。