公开(公告)号：US08318853B2

公开(公告)日：2012-11-27

申请号：US12665040

申请日：2008-06-19

Applicant: Andrew M. Howe ,  Trevor J. Wear ,  Alan R. Pitt ,  Ian M. Newington ,  John H. Hone

Inventor： Andrew M. Howe ,  Trevor J. Wear ,  Alan R. Pitt ,  Ian M. Newington ,  John H. Hone

IPC: C08L39/00 ,  B05D3/02 ,  B41J2/15

CPC classification number: B01F17/0057 ,  B41M5/52 ,  B41M5/5218 ,  C09D5/027 ,  C09D7/45 ,  C09D11/326

Abstract: A thermally-responsive dispersant for an aqueous dispersion of positively- or negatively-charged or chargeable solid or liquid particulates, comprises a compound having an anchoring moiety linked to a thermally-responsive polymeric stabilizing moiety, other than a polyalkylene oxide, the polymeric moiety having a lower affinity for the surface than the anchoring group below the thermal transition temperature, the particulates being positively-charged or chargeable when the anchoring moiety contains an acid and/or hydroxy group and has a net acidity or neutrality and the particulates being negatively-charged or chargeable when the anchoring moiety has a basic group and has a net basicity, wherein the dispersion exhibits a change in sign from negative to positive and an increase in magnitude of a rheological property (viscosity at low shear and/or complex modulus at low amplitude oscillatory shear), on increasing the temperature from below to above the thermal transition temperature.

Abstract translation: 用于带正电荷或带负电荷或带电荷的固体或液体颗粒的水性分散体的热响应性分散剂包括具有与热响应性聚合物稳定化部分连接的锚定部分的化合物，而不是聚环氧烷，所述聚合物部分具有 当锚定部分含有酸和/或羟基并且具有净酸度或中性并且颗粒带负电荷时，对于表面的亲和力低于锚定基团低于热转变温度的亲和力，所述颗粒被带正电或带电 或者当锚定部分具有碱性基团并且具有净碱度时可带电，其中分散体显示从负到正的变化和流变特性的大小（低剪切时的粘度和/或低振幅下的复数模量） 振荡剪切），将温度从低到高于热转变温度。

公开(公告)号：US08202926B2

公开(公告)日：2012-06-19

申请号：US12097770

申请日：2006-12-19

Applicant: Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe ,  Ian M. Newington

Inventor： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe ,  Ian M. Newington

IPC: C08K3/10

CPC classification number: B01F17/0028 ,  B01F17/005 ,  C09B67/009

Abstract: The invention provides a dispersant for an aqueous dispersion of negatively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one basic group and having an overall basicity and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The invention also provides a coating composition containing the dispersant, an inkjet recording element containing the dispersant and methods of coating or reducing viscosity using the dispersant.

Abstract translation: 本发明提供了一种用于带负电或可带电的固体颗粒的水分散体的分散剂，其包含具有与聚合亲水部分连接的锚定部分的化合物，所述锚定部分含有至少一个碱性基团并具有总碱性，并且聚合部分具有 对颗粒表面的亲和力比锚定部分低。 本发明还提供含有分散剂的涂料组合物，含有分散剂的喷墨记录元件和使用分散剂涂布或降低粘度的方法。

公开(公告)号：US06538048B1

公开(公告)日：2003-03-25

申请号：US09710323

申请日：2000-11-09

Applicant: David Erdtmann ,  Ian M. Newington ,  Alan R. Pitt

Inventor： David Erdtmann ,  Ian M. Newington ,  Alan R. Pitt

IPC: C09D1110

CPC classification number: C09D11/326

Abstract: An ink jet printing method, comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements; C) loading the printer with an ink jet ink composition comprising from about 0.5% to about 30% by weight of a pigment, a carrier and a dispersant, the dispersant comprising an anionic derivative of an ethoxylated alkylphenol-formaldehyde resin, the ratio of dispersant:pigment being from about 0.1:1 to about 5:1; and D) printing on the ink jet recording element using the ink jet ink in response to the digital data signals.

Abstract translation: 一种喷墨打印方法，包括以下步骤：A）提供响应于数字数据信号的喷墨打印机; B）用喷墨记录元件装载打印机; C）用喷墨油墨组合物装载打印机， 约0.5重量％至约30重量％的颜料，载体和分散剂，所述分散剂包含乙氧基化烷基酚 - 甲醛树脂的阴离子衍生物，分散剂：颜料的比例为约0.1:1至约5:1 ; 和D）响应于数字数据信号，使用喷墨油墨在喷墨记录元件上进行打印。

公开(公告)号：US06482975B1

公开(公告)日：2002-11-19

申请号：US09857877

申请日：2001-06-12

Applicant: Alan R. Pitt ,  Trevor J. Wear

Inventor： Alan R. Pitt ,  Trevor J. Wear

IPC: C07C6934

CPC classification number: G03C1/895 ,  C07C69/34 ,  C07C69/63 ,  C07C323/52

Abstract: Optionally fluorine-substituted alkyl or alkenyl poly(ethylene oxides) the compounds of the general formula in which R is an alkyl group with 10-20 carbon atoms, an alkenyl group with 10-20 carbon atoms or a fluoroalkyl or fluoroalkenyl group with f carbon atoms that each bear at least one fluorine atom and g carbon atoms that bear only hydrogen atoms, in which 1.5 f+g=10-20 and g may optionally be zero. R′ is an alkyl group with 1 to 4 carbon atoms, L is a linking group, a linking atom or a chemical bond, and p is at least 2, q is at least 2 and p+q=from 4 to 100, may be prepared by reacting maleic anhydride with a poly(ethylene glycol) alkyl. ether and reacting the resultant intermediate product with a compound of the formula RL′H in which L′ is a linking group or linking atom. Compounds of the formula (1) may also be prepared by reacting RL-substituted succinic anhydrides with a alkyl end-capped polyethylene glycol. The compounds of the formula (1) exhibit good solubility and surface activity and may be used as antistats, particularly in gelatin media, optionally in conjunction with lithium triflate or the like, in photographic coatings.

Abstract translation: 任选氟取代的烷基或烯基聚（环氧乙烷），其中R为具有10-20个碳原子的烷基，具有10-20个碳原子的烯基或具有f个碳原子的氟代烷基或氟烯基的通式化合物 各自承担至少一个仅含有氢原子的氟原子和g个碳原子，其中1.5f + g = 10-20，g可以任选地为0.R'是具有1至4个碳原子的烷基，L是 连接基团，连接原子或化学键，并且p为至少2，q为至少2且p + q = 4至100，可以通过使马来酸酐与聚（乙二醇）烷基反应来制备。 醚，并使所得中间产物与其中L'为连接基团或连接原子的式RL'H化合物反应。 式（1）化合物也可以通过使RL取代的琥珀酸酐与烷基封端的聚乙二醇反应来制备。 式（1）的化合物表现出良好的溶解性和表面活性，并且可以用作抗静电剂，特别是在明胶介质中，任选地与三氟甲磺酸锂等一起在照相涂料中使用。

公开(公告)号：US06468727B2

公开(公告)日：2002-10-22

申请号：US09770129

申请日：2001-01-26

Applicant: Alan R. Pitt ,  Trevor J. Wear ,  Danuta Gibson ,  Ian M. Newington ,  Mary C. Brick ,  John W. Boettcher ,  Gary N. Barber

Inventor： Alan R. Pitt ,  Trevor J. Wear ,  Danuta Gibson ,  Ian M. Newington ,  Mary C. Brick ,  John W. Boettcher ,  Gary N. Barber

IPC: G03C108

CPC classification number: B01F17/0057 ,  G03C1/005 ,  G03C7/3882 ,  G03C7/3885 ,  G03C2001/0854

Abstract: A hydrophobically capped oligomeric acrylamide or pyrrolidone is employed as a dispersant for hydrophobic materials in an aqueous medium containing a hydrophilic colloid, e.g. gelatin. The hydrophobic materials include photographic addenda such as color couplers or solid particle dyes. Preferred dispersants have the general formula R—L—T   (1) or in which R, R1 and R2 are each independently selected from aliphatic hydrocarbyl, aryl-(aliphatic hydrocarbyl) and (aliphatic hydrocarbyl)-aryl groups, L is a sulphur atom or a linking group that contains a sulphur atom attached to the T group, and T is a hydrophilic oligomeric group obtained by the oligomerisation of one or more vinyl monomers having an amido function.

Abstract translation: 疏水封端的低聚丙烯酰胺或吡咯烷酮在含有亲水胶体的水性介质中用作疏水性材料的分散剂。 明胶。 疏水性材料包括照相附加物，如成色剂或固体颗粒染料。 优选的分散剂具有通式，其中R 1，R 2和R 2各自独立地选自脂族烃基，芳基 - （脂族烃基）和（脂族烃基） - 芳基，L是硫原子或连接基团， T基团，和T是通过一种或多种具有酰氨基官能团的乙烯基单体的低聚获得的亲水性低聚基团。

公开(公告)号：US5529897A

公开(公告)日：1996-06-25

申请号：US485892

申请日：1995-06-07

Applicant: Katie E. Adams ,  Ian M. Newington ,  Alan R. Pitt

Inventor： Katie E. Adams ,  Ian M. Newington ,  Alan R. Pitt

IPC: B01F17/56 ,  C07H15/04 ,  C07H15/12 ,  G03C1/38

CPC classification number: C07H15/04 ,  G03C1/38

Abstract: A water-soluble or water-dispersible, non-ionic surface active compound has the formulaZNHQNHZ (I)whereineach Z independently is a polysaccharide group linked to the remainder of the molecule through one of its ketone groups; and,Q together with the two NH groups to which it is attached represents the atoms necessary to complete a polyalkyleneamine unit wherein at least one of the amine nitrogen atoms has a hydrophobic, substituted or unsubstituted hydrocarbon group linked thereto. Such surfactants can be used in hydrophilic colloid compositions in the manufacture of photographic materials.

Abstract translation: 水溶性或水分散性非离子表面活性化合物具有式ZNHQNHZ（I），其中每个Z独立地是通过其酮基之一与分子的其余部分连接的多糖基团; 并且Q与连接的两个NH基团一起代表完成聚亚烷基亚烷基单元所需的原子，其中至少一个胺氮原子具有与其连接的疏水性，取代或未取代的烃基。 这种表面活性剂可以用于制造照相材料的亲水胶体组合物中。

公开(公告)号：US5457023A

公开(公告)日：1995-10-10

申请号：US170562

申请日：1993-12-20

Applicant: Catherine B. Briggs ,  Ian M. Newington ,  Alan R. Pitt

Inventor： Catherine B. Briggs ,  Ian M. Newington ,  Alan R. Pitt

IPC: C07C235/06 ,  C07C235/10 ,  C07C237/22 ,  C07C275/14 ,  C07C275/28 ,  C07C311/05 ,  C07C311/18 ,  C07C335/08 ,  C07C335/16 ,  G03C1/38

CPC classification number: C07C235/10 ,  G03C1/38

Abstract: A water-soluble or water-dispersible, non-ionic surface active compound is provided having the formula ##STR1## wherein each Y independently is a hydrophilic polyhydroxyalkyl group;each X independently is ##STR2## each R independently is a hydrophobic substituted or unsubstituted alkyl group or a hydrophobic substituted or unsubstituted aryl group;each n independently is an integer from 2 to 6; and,each m is an integer from 2 to 4.Such surfactants can be used in hydrophilic colloid compositions in the manufacture of photographic materials.

Abstract translation: 提供具有式（1）的水溶性或水分散性非离子表面活性化合物，其中每个Y独立地是亲水性聚羟烷基; 每个X独立地是每个R独立地是疏水性取代或未取代的烷基或疏水性取代或未取代的芳基; 每个n独立地是2至6的整数; 并且每个m是2至4的整数。这种表面活性剂可用于制造照相材料的亲水胶体组合物中。

公开(公告)号：US5270161A

公开(公告)日：1993-12-14

申请号：US730965

申请日：1991-07-29

Applicant: Alan R. Pitt ,  Ian M. Newington

Inventor： Alan R. Pitt ,  Ian M. Newington

IPC: B01F17/46 ,  B01F17/00 ,  C07C217/28 ,  C07C217/32 ,  C07C217/34 ,  C07C235/08 ,  C07C235/10 ,  G03C1/38 ,  G03C1/005 ,  C07C215/10

CPC classification number: C07C217/34 ,  B01F17/0042 ,  C07C217/28 ,  C07C235/08 ,  G03C1/38

Abstract: Water-soluble, non-ionic surface active compounds are provided having the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently hydrogen or an alkyl group having from 1 to 4 carbon atoms;X is a hydrophobic substituted or unsubstituted arylene group or a hydrophobic substituted or unsubstituted alkylene group;Y.sup.1 and Y.sup.2 are each independently a chemical bond, --CO-- or --(CH.sub.2).sub.m NR.sup.3 CO--;m is an integer from 1 to 6;R.sup.3 is as defined for R.sup.1 and R.sup.2 ; and,Z.sup.1 and Z.sup.2 are each independently a hydrophilic polyhydroxyalkyl group. The compounds are particularly useful as coating aids for the coating of hydrophilic colloid layers in the preparation of photographic materials.

Abstract translation: PCT No.PCT / EP90 / 00606 Sec。 371日期1991年7月29日 102（e）日期1991年7月29日PCT 1990年4月13日提交PCT公布。 出版物WO90 / 12782 日本1990年11月1日提供了具有下式的水溶性非离子表面活性化合物：其中R 1和R 2各自独立地为氢或具有1至4个碳原子的烷基; X是疏水性取代或未取代的亚芳基或疏水性取代或未取代的亚烷基; Y1和Y2各自独立地为化学键，-CO-或 - （CH2）mNR3CO-; m是1至6的整数; R3如R1和R2所定义; 且Z 1和Z 2各自独立地为亲水性聚羟烷基。 该化合物特别可用作在制备照相材料中涂布亲水胶体层的涂料助剂。

公开(公告)号：US08063132B2

公开(公告)日：2011-11-22

申请号：US11722666

申请日：2005-12-22

Applicant: Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe

Inventor： Alan R. Pitt ,  Trevor J. Wear ,  John H. Hone ,  Andrew M. Howe

IPC: C04B26/06 ,  C08K3/10

CPC classification number: C09C1/407 ,  B01F17/0028 ,  B01F17/005 ,  B01F17/0057 ,  B01F17/0064 ,  C01F7/026 ,  C01P2004/64 ,  C01P2006/22

Abstract: The invention provides a coating composition containing boehmite particles and a dispersant which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one acid and/or hydroxy group and having overall acidity or neutrality and the polymeric moiety having a lower affinity for a boehmite surface than the anchoring moiety. The anchoring moiety preferably contains at least two acid groups, preferably carboxylic acid groups, attached either in a [1,1], [1,2] or [1,3] relationship and is linked to the polymeric moiety, which is preferably derived from acrylamide or methacrylamide monomer units, preferably by a sulfur atom. The dispersant can reduce the viscosity of the boehmite dispersion and the tendency of the boehmite dispersion to increase in viscosity and/or form a gel or a yield stress material following periods of high shear stress.

Abstract translation: 本发明提供一种包含勃姆石颗粒和分散剂的涂料组合物，其包含具有与聚合亲水部分连接的锚定部分的化合物，所述锚定部分含有至少一个酸和/或羟基并具有总酸性或中性， 对勃姆石表面的亲和力比锚定部分低。 锚定部分优选包含至少两个以[1,1]，[1,2]或[1,3]关系连接的酸基，优选羧酸基，并且与聚合部分连接，优选衍生自 来自丙烯酰胺或甲基丙烯酰胺单体单元，优选为硫原子。 分散剂可以降低勃姆石分散体的粘度，并且在高剪切应力下，勃姆石分散体的粘度增加和/或形成凝胶或屈服应力材料的趋势。

公开(公告)号：US20100129550A1

公开(公告)日：2010-05-27

申请号：US11815498

申请日：2005-12-22

Applicant: John D. Goddard ,  Alan R. Pitt ,  Elizabeth A. Simister ,  Mark Bradley ,  Anais F. Ronot

Inventor： John D. Goddard ,  Alan R. Pitt ,  Elizabeth A. Simister ,  Mark Bradley ,  Anais F. Ronot

IPC: B05D5/00 ,  C08F2/46 ,  C08F20/56 ,  C08F120/06 ,  C08F120/10 ,  C09D11/10

CPC classification number: C09C3/048 ,  C01P2004/84 ,  C01P2006/12 ,  C01P2006/22 ,  C01P2006/90 ,  C09C1/565 ,  C09C3/04 ,  C09D11/322 ,  C09D11/324

Abstract: Pigments for inkjet inks are controllably functionalised to improve water-dispersibility, ozone resistance, etc., by irradiation of the pigment particle with high energy radiation, such as gamma radiation in air or by plasma activation, to form a stable functionalisable intermediate pigment particle, then activating the stable functionalisable intermediate, e.g. by heating, in the presence of a functionalising precursor (e.g. a polymer or polymerisable monomer) to form a modified pigment particle having one or more functionalising group grafted onto the pigment particle.

Abstract translation: 通过用空气中的γ射线或等离子体激活等高能量辐射照射颜料颗粒，可以可控地使用喷墨油墨的颜料来改善水分散性，耐臭氧性等，以形成稳定的可官能的中间颜料颗粒， 然后激活稳定的可功能中间体，例如 通过在官能化前体（例如聚合物或可聚合单体）的存在下加热以形成具有接枝到颜料颗粒上的一个或多个官能化基团的改性颜料颗粒。