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    Polymerization catalyst
    2.
    发明授权
    Polymerization catalyst 失效
    聚合催化剂

    公开(公告)号：US5292700A

    公开(公告)日：1994-03-08

    申请号：US008381

    申请日：1993-01-25

    申请人： Peter A. A. Klusener ,  Johannes J. M. Snel ,  Hans A. Stil

    发明人： Peter A. A. Klusener ,  Johannes J. M. Snel ,  Hans A. Stil

    IPC分类号： C08G67/00 ,  C08G67/02 ,  B01J31/04

    CPC分类号： C08G67/02

    摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, preferably propylene, includes an aromatic amine in the catalyst composition formed from a palladium salt, the anion of a strong non-hydrohalogenic acid and a bidentate ligand of phosphorus. The presence of the aromatic amine reduces the proportion of 3-alkyl-2,5-furandiyl moieties present in the polymer chain.

    摘要翻译： 用于生产一氧化碳和至少一种烯属不饱和烃（优选丙烯）的线性交替聚合物的改进方法包括由钯盐形成的催化剂组合物中的芳族胺，强非氢卤酸的阴离子和二齿 磷配体 芳族胺的存在降低了存在于聚合物链中的3-烷基-2,5-呋喃二基部分的比例。

    Catalyst system and copolymerization process
    3.
    发明授权
    Catalyst system and copolymerization process 失效
    催化剂体系和共聚方法

    公开(公告)号：US5434117A

    公开(公告)日：1995-07-18

    申请号：US167689

    申请日：1993-12-15

    申请人： Peter A. A. Klusener ,  Hans A. Stil

    发明人： Peter A. A. Klusener ,  Hans A. Stil

    IPC分类号： C08F4/649 ,  C08F210/02 ,  C08G67/02 ,  B01J31/18 ,  B01J27/185

    CPC分类号： C08G67/02 ,  C08F10/00 ,  C08F210/02

    摘要： It is herein disclosed a novel catalyst systems comprising:a) a source of cations of Group VIII metals, selected from palladium, cobalt and nickel;b) a source of anions andc) a source of bidentate ligands of the formulaR.sup.1 R.sup.2 M.sup.1 --R--M.sup.2 R.sup.3 R.sup.4 wherein each of M.sup.1 and M.sup.2 independently represents a phosphorus, arsenic, antimony or nitrogen atom, R represents a bivalent organic bridging group containing at least two atoms in the bridge and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently represent substituted or non-substituted hydrocarbyl groups with the proviso that at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represents an aryl group at least containing as substituents (i) at one or both ortho positions with respect to M.sup.1 or M.sup.2 to which the aryl group is linked, a hydrocarbyloxy group and (ii) at a meta position, adjacent to a substituted ortho position, a hydrocarbyl group or at the para position a halogen atom.It is further disclosed a process for preparing copolymer comprising carbon monoxide and at least one ethylenically unsaturated hydrocarbon by reacting the monomers under polymerization conditions in the presence of the novel catalyst systems.

    摘要翻译： 本文公开了一种新的催化剂体系，其包含：a）选自钯，钴和镍的第Ⅷ族金属的阳离子源; b）阴离子源，c）式R1R2M1-R-M2R3R4的双齿配体源，其中M1和M2各自独立地表示磷，砷，锑或氮原子，R表示至少含有二价有机桥连基团 桥中的两个原子和R 1，R 2，R 3和R 4独立地表示取代或未取代的烃基，条件是R 1，R 2，R 3和R 4中的至少一个表示至少含有取代基（ⅰ） 相对于连接有芳基的M1或M2的一个或两个邻位，烃氧基和（ii）在与取代的邻位相邻的间位，烃基或在对位处为卤素原子的间位。 还公开了一种通过在新型催化剂体系的存在下在聚合条件下使单体反应来制备包含一氧化碳和至少一种烯属不饱和烃的共聚物的方法。

    Preparation of copolymers
    4.
    发明授权
    Preparation of copolymers 失效
    共聚物的制备

    公开(公告)号：US5408031A

    公开(公告)日：1995-04-18

    申请号：US227843

    申请日：1994-04-14

    申请人： Peter A. A. Klusener ,  Hans A. Stil

    发明人： Peter A. A. Klusener ,  Hans A. Stil

    IPC分类号： C08F4/42 ,  C08G67/00 ,  C08G67/02

    CPC分类号： C08G67/02

    摘要： A process for the preparation of copolymers of carbon monoxide and one or more ethylenically unsaturated non-aromatic compounds by contacting the monomers, under polymerization conditions, with a catalyst system consisting essentially of palladium, a bisphosphine ligand and a source of anions, derived from the conjugated base of acids having a pKa of less than 4, in the additional presence of a 1-alkenyl substituted arylgroup containing compound.

    摘要翻译： 一种制备一氧化碳和一种或多种烯键式不饱和非芳族化合物的共聚物的方法，其通过在聚合条件下与单体接触，催化剂体系基本上由钯，双膦配体和阴离子源组成，催化剂体系衍生自 在另外存在含1-烯基取代的含芳基的化合物的情况下，pKa小于4的酸的共轭碱。

    Preparation of copolymers
    5.
    发明授权
    Preparation of copolymers 失效
    共聚物的制备

    公开(公告)号：US5354340A

    公开(公告)日：1994-10-11

    申请号：US150934

    申请日：1993-11-10

    申请人： Peter A. A. Klusener ,  Petrus W. N. M. Van Leeuwen ,  Hans A. Stil

    发明人： Peter A. A. Klusener ,  Petrus W. N. M. Van Leeuwen ,  Hans A. Stil

    IPC分类号： C08G67/00 ,  C08G67/02

    CPC分类号： C08G67/02

    摘要： A process for the preparation of copolymers of carbon monoxide and one or more ethylenically unsaturated compounds by contacting the monomers, under polymerization conditions, with a catalyst system comprising a) a source of cations of one or more metals of Group VIII of the Periodic Table and b) a bidentate ligand, and c) a minor amount of a compound containing a hydride moiety. Copolymers made by this process generally have low molecular weights.

    摘要翻译： 一种制备一氧化碳和一种或多种烯键式不饱和化合物的共聚物的方法，其通过使聚合条件下的单体与催化剂体系接触，所述催化剂体系包括：a）周期表第VIII族的一种或多种金属的阳离子源，以及 b）二齿配体，和c）少量含有氢化物部分的化合物。 通过该方法制备的共聚物通常具有低分子量。

    Catalyst compositions
    8.
    发明授权
    Catalyst compositions 失效
    催化剂组合物

    公开(公告)号：US5266545A

    公开(公告)日：1993-11-30

    申请号：US6577

    申请日：1993-01-21

    申请人： Peter A. A. Klusener ,  Johannes J. M. Snel

    发明人： Peter A. A. Klusener ,  Johannes J. M. Snel

    IPC分类号： B01J31/00

    CPC分类号： B01J31/00

    摘要： A catalyst composition useful in the preparation of a polymer composition includes a Group VIII metal and a phosphorus bidentate ligand of the general formula (R.sub.2)(R.sub.4)P--R.sub.3 --P(R.sub.2)(R.sub.4) wherein R.sub.2 and R.sub.4 are optionally polar substituted alkyl groups, differing from each other in carbon number, and wherein R.sub.3 is a divalent organic bridging group which contains four atoms. Such catalyst compositions are particularly useful for preparing copolymers of carbon monoxide with .alpha.-olefins having at least three carbon atoms.

    摘要翻译： 可用于制备聚合物组合物的催化剂组合物包括通式（R2）（R4）P-R3-P（R2）（R4）的第Ⅷ族金属和磷二齿配体，其中R2和R4任选被极性取代 烷基，碳数不同，其中R3是含有四个原子的二价有机桥连基团。 这种催化剂组合物特别可用于制备一氧化碳与具有至少三个碳原子的α-烯烃的共聚物。

    Catalyst compositions
    10.
    发明授权
    Catalyst compositions 失效

    公开(公告)号：US5216119A

    公开(公告)日：1993-06-01

    申请号：US914235

    申请日：1992-07-13

    申请人： Peter A. A. Klusener ,  Johannes J. M. Snel

    发明人： Peter A. A. Klusener ,  Johannes J. M. Snel

    IPC分类号： C08G67/02

    CPC分类号： C08G67/02

    摘要： A catalyst composition useful in the preparation of a polymer composition includes a Group VIII metal and a phosphorus bidentate ligand of the general formula (R.sub.2)(R.sub.4)P-R.sub.3 -P(R.sub.2)(R.sub.4) wherein R.sub.2 and R.sub.4 are optionally polar substituted alkyl groups, differing from each other in carbon number, and wherein R.sub.3 is a divalent organic bridging group which contains four atoms. Such catalyst compositions are particularly useful for preparing copolymers of carbon monoxide with .alpha.-olefins having at least three carbon atoms.